Chapter 22: Q26P (page 1059)
Which of the following amino acid side chains can form an imine with a substrate?

Short Answer
The answer is

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Chapter 22: Q26P (page 1059)
Which of the following amino acid side chains can form an imine with a substrate?

The answer is

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Which compound has the greatest rate of hydrolysis at pH=3.5:benzamide, o-carboxybenzamide, o-formylbenzamide, or o-hydroxybenzamide?
In glycolysis, why must glucose-6-phosphate isomerizes to fructose- 6- phosphate before the cleavage reaction with aldose occurs?
a. Explain why the alkyl halide shown here reacts much more rapidly with guanine than does a primary alkyl halide (such as pentyl chloride).

b. The alkyl halide can react with two guanines, each in a different DNA chain, thereby cross-linking the chains. Propose a mechanism for the cross-linking reaction.
Which of the following two compounds eliminates HBr more rapidly in a basic solution?

3-Amino-2-oxindole catalyzes the decarboxylation of -keto acids.
a. Propose a mechanism for the catalyzed reaction.
b. Would 3-aminoindole be equally effective as a catalyst?

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