Chapter 1: PROBLEM 1.33 (page 86)
Question: Draw a line-angle formula for each compound in Problem.
Short Answer
Answer
The Line-angle formulas for the given compounds are:
a.

b.

c.

d.

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Chapter 1: PROBLEM 1.33 (page 86)
Question: Draw a line-angle formula for each compound in Problem.
Answer
The Line-angle formulas for the given compounds are:
a.

b.

c.

d.

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Question: In most amines, the nitrogen atom is sp3 hybridized, with a pyramidal structure and bond angles close to 109o.In urea, both nitrogen atoms are found to be planer, with bond angles close to 120o. Explain this surprising finding. (Hint: consider resonance forms and the overlap needed in them.)

Allene,CH2=C=CH2 , has the structure shown below. Explain how the bonding in allene requires the two groups at its ends to be at right angles to each other.

Allene
In 1934, Edward A. Doisy of Washington University extracted 3000 lb of hog ovaries to isolate a few milligrams of pure estradiol, a potent female hormone. Doisy burned 5.00 mg of this precious sample in oxygen and found that 14.54 mg of CO2 and 3.97 mg of H2O were generated.
(a) Determine the empirical formula of estradiol.
(b) The molecular weight of estradiol was later determined to be 272. Determine the molecular formula of estradiol.
Determine whether the following pairs of structures are different compounds or simply resonance forms of the same compounds.


For each of these ions, draw the important resonance forms and predict which resonance form is likely to be the major contributor.

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