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Chapter 1: 18P (page 76)

Predict the hybridization, geometry, and bond angles for the carbon and nitrogen atoms in acetonitrilesCH3-C鈮�N

Short Answer

Expert verified

Answer

Hybridization

2

sp

3

sp2

4

sp3

Step by step solution

01

Hybridization and bond angles

Bond angle and geometry are prominent factors that affect hybridization.The angle formed between three atoms across at least two bonds is called the bond angle.It changes with the respective bond pair electron and lone pair electron.

Hybridization is calculated as follows:

Hybridization =Number of蟽 bond+Number of lone pair

02

Prediction of the hybridization, geometry, and bond angles

SN

Elements

Calculation

hybridization

geometry

bond angle

1

C

Hybrid

4+0=4

sp3

tetrahedral

109.280

2

C

Hybrid

2+0=2

sp

linear

1800

3

N

Hybrid

1+1=2

sp

linear

1800

Prediction of hybridization

Prediction of bond angle

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Most popular questions from this chapter

Question: Draw one valid Lewis structure for each compound. Assume the atoms are arranged as drawn

a,

b.

c.

d.

In 1934, Edward A. Doisy of Washington University extracted 3000 lb of hog ovaries to isolate a few milligrams of pure estradiol, a potent female hormone. Doisy burned 5.00 mg of this precious sample in oxygen and found that 14.54 mg of CO2 and 3.97 mg of H2O were generated.

(a) Determine the empirical formula of estradiol.

(b) The molecular weight of estradiol was later determined to be 272. Determine the molecular formula of estradiol.

Draw the important resonance forms of the following cations and anions:

(1) Draw a Lewis structure for each compound.

(2) Label the hybridization, geometry, and bond angles around each atom other than hydrogen.

(3) Draw a three- dimensional representation (using wedges and dashed lines) of the structure.

(a)CO2

(b)CH3OCH3

(c)(CH3)3O+

(d)CH3COOH

(e)CH3CCH

(f)CH3CHNCH3

(g)H2CCO

Allene, CH2=C=CH2, has the structure shown below. Explain how the bonding in allene requires the two=CH2 groups at its ends to be at right angles to each other.

Allene
See all solutions

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