Chapter 13: Q 16. (page 514)
Question: How do the IR spectra of the isomers cyclopentane and pent-1-ene differ?
Short Answer
Answer
IR spectra of 1-pentene will have an additional peak at .
1-pentene will show IR absorptions at .
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Chapter 13: Q 16. (page 514)
Question: How do the IR spectra of the isomers cyclopentane and pent-1-ene differ?
Answer
IR spectra of 1-pentene will have an additional peak at .
1-pentene will show IR absorptions at .
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Question: What are the major IR absorptions in the functional group region for oleic acid, a common unsaturated fatty acid (Section 10.6A)?
Question: A chiral hydrocarbon X exhibits a molecular ion at 82 in its massspectrum. The IR spectrum of X shows peaks at 3300, 3000–2850, and 2250 cm-1. Propose a structure for X.
Question:Suppose you have two bottles, labeled ketone A and ketone B. You know that one bottle contains and one contains but you do not know which ketone is in which bottle. Ketone A gives a fragment at m/z= 99 and ketone B givesa fragment at m/z= 113. What are the likely structures of ketones A and B from these fragmentation data?
Question: How do the three isomers of molecular formula (A, B, and C) differ in their IR spectra?

Question: The base peak in the mass spectrum of 2,2,4-trimethylpentane occurs at m/z = 57. What ion is responsible for this peak and why is this ion the most abundant fragment?
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