Chapter 31: Q26P. (page 1258)
Locate the isoprene units in each compound.
(a)
(b)

(c)

(d)

(e)
(f)

(g)

(h)

Short Answer
(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

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Chapter 31: Q26P. (page 1258)
Locate the isoprene units in each compound.
(a)
(b)

(c)

(d)

(e)
(f)

(g)

(h)

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

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A difficult problem in the synthesis of PGFis the introduction of the OH group at C15 in the desired configuration.
A well known synthesis of PGFinvolves reaction of A with (a metal hydride reagent similar in reactivity to, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.
Suggest a reagent to convert A to the single stereoisomer X.

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