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Chapter 31: Question 31.5 (page 1237)

Unlike many fats and oils, the cocoa butter used to make chocolate is remarkably uniform in composition. All triacylglycerols contain oleic acid esterified to the °2OH group of glycerol, and either palmitic acid or stearic acid esterified to the°1 OH groups. Draw the structures of two possible triacylglycerols that compose cocoa butter.

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01

Cocoa butter

Cocoa butter constitutes an eatable fat acquired from cocoa bean. Several substances like chocolate, ointments, and pharmaceuticals can be created from cocoa butter.

Because of its texture and fragrance, it is also used in several products like soaps and lotions.

02

Triacylglycerols

Triacylglycerols, also known as triglycerides are classed into simple and mixed triacylglycerols. Simple triacylglycerols possess three similar fatty acid chains, whereas complex triacylglycerols possess two or several fatty acids.

03

Structures of triacylglycerols that comprise cocoa butter

The condensed formula of oleic acid is CH3CH27CH=CHCH27COOH. It is an unsaturated fatty acid containing 18 carbon atoms with one double bond.

The condensed formula of palmitic acid is CH3CH214COOH. It is a saturated fatty acid comprising 16 carbon atoms with no double bond. Both the unsaturated and saturated fatty acid undergo an esterification reaction with glycerol.

The structures of the two glycerols can be given as:

Structure of the first possible triacylglycerol that composes cocoa butter

Structure of the second possible triacylglycerol that composes cocoa butter

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