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Chapter 29: Q9P (page 1159)

Draw the products of each reaction.

(a)

(b)

(c)

(d)

Short Answer

Expert verified

Answer

(a)

(b)

(c)

(d)

Step by step solution

01

SN2 reaction

Substitution nucleophilic biomolecular reaction is a one-step reaction and doesn鈥檛 involve any intermediate.It is a type of reaction where one side the bond breaks and formation takes place on the other side.

02

Reaction

(a) When bromoacetic acid reacts with excess NH3,its ammonium salt

Formation of ammonium salt

(b) When diethyl acetamidomalonate is treated with (CH3)2 CHCl and undergoes heat and hydrolysis, valine is formed.

Formation of valine

(c) When 2-methyl butanol is treated with NH4Cl, NaCN and undergoes hydrolysis isoleucine is formed.

Formation of isoleucine

(d) When diethyl acetamidomalonate is treated with NaOEt, BrCH2CO2Et and undergoes hydrolysis and heat,2-aminobutanedioic acids are formed.

Formation of 2-aminobutanedioic acid

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Most popular questions from this chapter

What伪-halo carbonyl compoundis needed to synthesize each amino acid?

(a) Glycine

(b) Isoleucine

(c) Phenylalanine

a. Draw the structure of the tripeptide A-A-A, and label the two ionizable functional groups.

b. What is the predominant form of A-A-A at pH=1?

c. The values for the two ionizable functional groups (3.39 and 8.03) differ considerably from the values of alanine (2.35 and 9.87;see table 29.1). Account for the observed differences.

Draw the amino acids and peptide fragments formed when the decapeptide A-P-F-L-K-W-S-G-R-G is treated with each reagent or enzyme: (a) chymotrypsin; (b) trypsin; (c) carboxypeptidase; (d) C6H5N=C=S

Question: Draw the other three stereoisomers of L-isoleucine, and label the stereogenic centers as R or S.

Devise a synthesis of the following dipeptide from amino acid starting materials.
See all solutions

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