Chapter 21: 14P (page 817)
Draw the products of each reaction. Include all stereoisomers formed
a.

b.

Short Answer
a.

b.

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Chapter 21: 14P (page 817)
Draw the products of each reaction. Include all stereoisomers formed
a.

b.

a.

b.

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What hydrolysis products are formed when the following compound is treated with aqueous acid?

What products are formed when each acetal is hydrolyzed with aqueous acid?
a.

b.

a. How many stereogenic centers are present in -D-galactose?
b. Label the hemiacetal carbon in -D-galactose.
c. Draw the structure of -D-galactose.
d. Draw the structure of the polyhydroxy aldehyde that cyclizes to - and
-D-galactose.
e. From what you learned in Section 21.16B, what product (s) is (are) formed
when -D-galactose is treated with CH3OH and an acid catalyst?

Identify the acetal in oleandrin, and draw the products formed by acid-catalysed hydrolysis of the acetal.

¶Ù°ù²¹·É t³ó±ð p°ù´Ç»å³Ü³¦³Ù f´Ç°ù³¾±ð»å w³ó±ð²Ô C±á3CH2CH2CH2NH2reacts with each carbonyl compound in the presence of mild acid.
a.

b.

c.

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