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Based on the diagrams in Exercise 12.83, which of the reactions has the fastest rate? Which has the slowest rate?

Short Answer

Expert verified

Reactions (a) and (b) have the same rate.

Step by step solution

01

Definition of Catalyst, Activation Energy

Catalyst are substances which increases the rate of the reaction without getting used up by themselves while decreasing the activation energy of the reaction. Activation energy is the energy difference between the initial reagents and the transition state(it is the state where the energy is maximum on the reaction coordinate diagram).

02

Determination of Fastest and Slowest Rate 

  • Catalyst increases the rate of reaction.
  • Catalyst accelerates the rate of a reaction by decreasing the activation energy.
  • Catalysts may provide different reaction mechanisms involving extra steps in the reaction and lower the activation energy simultaneously increasing the reaction rate.
  • Catalyst is regenerated during the reaction.

As both reactions (a) and (b) have same activation energy, these two reactions have same rate. Thus, reactions both (a) and (b) have the same rate.

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Most popular questions from this chapter

Use the provided initial rate data to derive the rate law for the reaction whose equation is: \({\bf{OC}}{{\bf{l}}^ - }\)(aq) + \({{\bf{I}}^ - }\)(aq) ⟶OI−(aq) +\({\bf{C}}{{\bf{l}}^ - }\)(aq)

Trial

(\({\bf{OC}}{{\bf{l}}^ - }\)) (mol/L)

(\({{\bf{I}}^ - }\)) (mol/L)

Initial Rate (mol/L/s)

1.

0.0040

0.0020

0.00184

2.

0.0020

0.0040

0.00092

3.

0.0020

0.0020

0.00046

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(a) What is the rate constant for the decomposition of fluorine-18?

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