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What is the pH of 0.070 M dimethylamine?

Short Answer

Expert verified

Answer

The value of pHis obtained as: 11.81

Step by step solution

01

Define Gaseous State

In water, strong acids totally dissociate. Their conjugate bases aren't very strong. In water, weak acids only partly dissociate. Their conjugate foundations are solid.

The equilibrium in any acid-base reaction favours the reaction that sends the proton to the stronger base.

02

Construction of ICE table

It is given that:

0.070M(CH3)2NH

Appendix C: Kb=5.910-4

To begin, create the balanced equation for (CH3)2NHdissociation in water.

localid="1662033204023" (CH3)2NH+H2(CH3)2NH2++OH

Then, to get the equation for Kb, build the ICE table.

localid="1662033218654" [(CH3)2NH]+H2OC[(CH3)2NH2+]+[OH-]I0.070M00C-x+x+xE0.070M-x+x+xKa=[OH-][(CH3)2NH2+][CH32NH]Ka=x20.070-x

03

Evaluate the value of 


It is known that:

x=[CH32NH2+]=[OH-]

The Kbof(CH3)2NH2is quite tiny since it is a weak base. Assume that x has no influence on the denominator's 0.070MM. Then, to solve for x, insert the Kb.

Kb=x20.070.........................(1)x2=(Kb)(0.070)...................(2)x=(Kb)(0.070).................(3)=(5.910-4)(0.070).......(4)x=6.4310-4M.................(5)

We know that x=OH-. Using the Kwof water, solve for [H3O+].

Kw=[H3O+][OH-]............(6)[H3O+]=[Kw][OH-].....................(7)=1.010-146.4310-3..............(8)[H3O+]=1.5610-12M............(9)

Now, solving to evaluate the value of pHas:

pH=-log[H3O+]....................(10)=-log(1.5610-12)...........(11)pH=11.81...............................(12)

Therefore, the value of pHis: 11.81

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Most popular questions from this chapter

Human urine has a normal pH of 6.2. If a person eliminates an average of 1250mL of urine per day, how manyH+ions are eliminated per week?

Question: Which of the following are Arrhenius bases?

(a)H3AsO4

(b)Ba(OH)2

(c)HClO

(d)KOH

Question: Write the Ka expression for each of the following in water:

(a)H2PO4-

(b)H3PO2

(c)HSO4-

Hemoglobin (Hb) transports oxygen in the blood:

HbH+(aq) +O2(aq) +H2O(l)nHbO2(aq) +H3O+(aq)

In blood,H3O+is held nearly constant at4脳10- 8M.

(a) How does the equilibrium position change in the lungs?

(b) How does it change in O2-de铿乧ient cells?

(c) Excessive vomiting may lead to metabolic alkalosis, in which [H3O+] in blood decreases. How does this condition affect the ability of Hb to transportO2?

(d) Diabetes mellitus may lead to metabolic acidosis, in which [H3O+] in blood increases. How does this condition affect the ability of Hb to transportO2?

The antimalarial properties of quinine (C20H24N2O2) saved thousands of lives during construction of the Panama Canal. This substance is a classic example of the medicinal wealth of tropical forests. Both N atoms are basic, but the N (coloured) of the 3amine group is far more basic (pKb =5.1) than the N within the aromatic ring system (pKb =9.7).

(a) A saturated solution of quinine in water is only1.610-3M. What is the pH of this solution?

(b) Show that the aromatic N contributes negligibly to the pH of the solution.

(c) Because of its low solubility, quinine is given as the salt quinine hydrochloride(C20H24N2O2HCl),which is 120times more soluble than quinine. What is the pH ofM quinine hydrochloride?

(d) An antimalarial concentration in water is 15% quinine hydrochloride by mass (d 1.0g/mL). What is the pH?

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