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Careful measurements show that the specific heat of the solid phase depends on temperature (Fig. P17.117). How will the actual time needed for this cryoprotectant to come to equilibrium with the cold plate compare with the time predicted by using the values in the table? Assume that all values other than the specific heat (solid) are correct. The actual time (a) will be shorter; (b) will be longer; (c) will be the same; (d) depends on the density of the cryoprotectant.

Short Answer

Expert verified

Therefore, the correct option is (a): The actual time will be shorter.

Step by step solution

01

Write the given data from the question.

The specific heat of the solid phase depends on temperature.

02

Determine the formula to calculate the specific heat.

The relationship between the mass, temperature, and heat is given as follows.

\(Q = mc\Delta T\) …… (i)

Here,\(Q\)is the heat transfer,\(m\)is the mass,\(c\)is the specific heat and\(\Delta T\)is the change in the temperature between room temperature and freezing point of the cryoprotectant.

03

Determine the actual time needed for this cryoprotectant to come to equilibrium with the cold plate compare with the time predicted by using the values in the table.

Derive the expression for the specific heat from the equation (i).

\(c = \frac{Q}{{m\Delta T}}\) …… (ii).

Let's assume the mass and change in the temperature is constant. Therefore, the specific heat depends on the generated heat.

Since the value of the specific heat is less then the average specific heat (from the table: \(2 \times {10^3}\;{{\rm{J}} \mathord{\left/{\vphantom {{\rm{J}} {{\rm{kg}} \cdot {\rm{K}}}}} \right.\\} {{\rm{kg}} \cdot {\rm{K}}}}\)). The less amount of the heat is required to for cryoprotectant to come to equilibrium with the cold plate. Therefore, the time required for cryoprotectant to come to equilibrium with the cold plate will be shorter.

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