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Derivation of equation(940): Our model for calculatingEis equation (9-26), whose denominator is the total number of particlesNand whose numerator is the total energy of the system, which we here callUtotal. State with the denominator:

N=0N(E)(E)dE

Insert the quantum gas density of states and an expression for the distribution. usingto distinguish the Bose-Einstein from the Fermi-Dirac. Then change variables:E=y2, and factorBe+r2/kUTout of the denominator. In the integrand will be a factor

(11Bey2/kBT)1

Using,(l)11 a sum of two integrals results, each of Gaussian form. The integral thus becomes two terms in powers of1/B. Repeat the process. but instead find an expression forUtotalin terms of1/B, using

U|ntal=0EN(E)D(E)dE

Divide your expression forUtotalby that forN. both in terms of1/B. Now1/Bcan safely be eliminated by using the lowest-order expression forNin terms of1/B.

Short Answer

Expert verified

The expression for average energy is 32kBT[1233(2s+1)(12mkBT)32(NV)+].

Step by step solution

01

Step 1:The total number of particles, total energy and average energy. 

The expression of total number of particles is given by,

N=0N(E)D(E)dE

The expression of total energy is given by,

Utotal=0EN(E)D(E)dE

The expression for average energy is given by,

E=UtotalN

02

Find total number of particles.

The total number of particles is N.

The total energy of system is UtotalCalculation:

The expression of total number of particles is given by,

N=0N(E)D(E)dE=0[(2s+1)m32V232E12][1BeEkBT1]dE=(2s+1)m32V2320E12BeEk2T1dE

LetE=y2 thendE=2ydy,

Substitute2ydyfordEandy2for Ein equation (1).

dN=(2s+1)m32V2320(y2)12BeEkBT1(2ydy)=2(2s+1)m32V2320y2BeEkBT1dy=2(2s+1)m32V2320y2Bey2kBT(1ey2kBT)dy=2(2s+1)m32V232[0y2Bey2kBTy2ey2kBTey2kBTdy]

Further simplify the above,

N=2(2s+1)m32V232[14B(kBT)314B2(kBT2)3]=(2s+1)VB(mkBT22)32[112B2]

03

Find total energy. 

The expression of total energy is given by,

Utotal=0EN(E)D(E)dE=0E[(2s+1)m32V232E12][1BeEkBT1]dE=(2s+1)m32V2320E32BeEkBT1dE

Let E=y2thendE=2ydy,

Substitute 2ydyfordE and y2forE in equation (2).

Utotal=(2s+1)m32V2320(y2)32BeEkBT1(2ydy)=2(2s+1)m32V2320y4BeEkBT1dy=2(2s+1)m32V2320y4Bey2kBT(1ey2kBT)dy=2(2s+1)m32V232[0y4Bey2k2y4ey2kBTey2kBTdy]

Further simplify the above,

Utotal=2(2s+1)m32V232[38B(kBT)538B2(kBT2)5]=3(2s+1)VkBT2B(mkBT22)32[114B2]

04

Find the average energy.

The expression for average energy is calculated as,

E=UtotalN=3(2s+1)VkBT2B(mkBT22)32[114B2](2s+1)VB(mkBT22)32[112B2]32kBT[114B2+]32kBT[1142{1(2s+1)(22mkBT)32(NV)}+]

Further simplify the above,

E32kBT[122332(2)32(2s+1)(1mkBT)32(NV)+]32kBT[1233(2s+1)(12mkBT)32(NV)+]

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Most popular questions from this chapter

In Exercise 35, a simple two-state system is studied. Assume that the particles are distinguishable. Determine the molar specific heat Cvof this material and plot it versus T. Explain qualitatively why it should behave as it does.

Example 9.4 investigated one criterion for quantum indistinguishability with reference to atmospheric nitrogen. Here we investigate the other, (a) Calculate the avenge separation between nitrogen molecules in the air. Assume a temperature of 300K a pressure of1atmand air that is 80% nitrogen. (b) Calculate the wave length of a typical nitrogen molecule in the air. (c) How does your result relate to Example 9.4?

Suppose we have a system of identical particles moving in just one dimension and for which the energy quantization relationship isE=bn2/3, wherebis a constant andan integer quantum number. Discuss whether the density of states should be independent ofE, an increasing function ofE, or a decreasing function ofE.

Copper has a density of8.9103kg/m3, and no photoelectrons are ejected from it if the wavelength of the incident light is greater than8.9103kg/m3(in the ultraviolet range). How deep is the well in which its conduction electrons--one per atom-are bound?

You have six shelves, one above the other and all above the floor, and six volumes of an encyclopedia, A, B, C, D, E and F.

(a) list all the ways you can arrange the volumes with five on the floor and one on the sixth/top shelf. One way might be(ABCDE_,_,_,_,_F).

(b) List all the ways you can arrange them with four on the floor and two on the third shelf.

(c) Show that there are many more ways, relative to pans (a) and (b), to arrange the six volumes with two on the floor and two each on the first and second shelves. (There are several ways to answer

this, but even listing them all won't take forever it's fewer than.)

(d) Suddenly, a fantastic change! All six volumes are volume X-it's impossible to tell them apart. For each of the three distributions described in parts (a), (b), and (c), how many different (distinguishable) ways are there now?

(e) If the energy you expend to lift a volume from the floor is proportional to a shelf's height, how do the total energies of distributions (a), (b), and (c) compare?

(I) Use these ideas to argue that the relative probabilities of occupying the lowest energy states should be higher for hosons than for classically distinguishable particles.

(g) Combine these ideas with a famous principle to argue that the relative probabilities of occupying the lowest states should he lower for fermions than for classically distinguishable particles.

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