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Figure 7.49 is a potential energy curve for the interaction of two neutral toms. The two-atom system is in a vibrational state indicated by the green horizontal line.

  1. At , what are the approximate values of the kinetic energy K, the potential energy U, and the quantity K + U?
  2. What minimum energy must be supplied to cause these two atoms to separate?
  3. In some cases, when r is large, the interatomic potential energy can be expressed approximately as . For large r, what is the algebraic form of the magnitude of the force the two atoms exert on each other in this case?

Short Answer

Expert verified

a) The approximate values of the kinetic energy K is 1.1 eV, the potential energy U is -1.3 eV, and the quantity K + U is -0.2 eV.

b) The required amount of energy that must be supplied to separate the two atoms is +0.2 eV.

c) The force magnitude that is applied by two atoms on each other in the algebraic form is -6ar7.

Step by step solution

01

Explanation of Potential and kinetic energy of the atom and for two atom system and the magnitude of force applied by the atoms on each other 

The motion of electrons in a particular atom defines the potential and kinetic energy of the atom. And for two atoms, the potential energy depends on the distance between two atoms.

The total energy for the system is given by the sum of the potential energy and the kinetic energy. It is expressed as follows,

E=K+U 鈥(1)

Here, , K is the kinetic energy and U is the potential energy.

F=dUdr 鈥(2)

Here, U is the potential energy and r is interatomic distance.

02

Determination of the approximate values of the kinetic energy K, the potential energy U, and the quantity K + U 

(a)From the given plot, the value of potential energy and the total energy corresponding tor=r1 is as follows,

U=-1.3eV

E=-0.2eV

Substitute all the values in equation (1).

-0.2eV=K+-1.3eVK=1.3eV-0.2eV=1.1eV

Thus, the approximate values of the kinetic energy K is 1.1 eV, the potential energy U is -1.3 eV, and the quantity K + U is -0.2 eV.

03

Determination of the minimum energy required to separate the two atoms

(b)The required factor for determination of the minimum energy required to separate the two atoms is that the value of the interaction energy must be zero.

So, the required amount of energy that must be supplied is +0.2 eV to make the interaction energy zero. It can be expressed as follows,

E=-0.2eV +-0.2eV=0

Thus, the required amount of energy that must be supplied to separate the two atoms is +0.2 eV.
04

Determination of the force magnitude that is applied by two atoms on each other in the algebraic form 

(c)Substitute all the values in equation (2) and solve the equation.

F=ddr-ar6=-6ar7

Thus, theforce magnitude that is applied by two atoms on each other in the algebraic formis -6ar7.

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