Chapter 15: Problem 45
Why must fiber materials that are melt-spun and then drawn be thermoplastic? Cite two reasons.
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Chapter 15: Problem 45
Why must fiber materials that are melt-spun and then drawn be thermoplastic? Cite two reasons.
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Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted. (b) For each of these tests, cite the experimental parameter of interest and how it is determined.
Would you expect the tensile strength of polychlorotrifluoroethylene to be greater than, the same as, or less than that of a polytetrafluoroethylene specimen having the same molecular weight and degree of crystallinity? Why?
Nylon 6,6 may be formed by means of a condensation polymerization reaction in which hexamethylene diamine \(\left[\mathrm{NH}_{2}-\left(\mathrm{CH}_{2}\right)_{6}-\right.\) \(\mathrm{NH}_{2}\) ] and adipic acid react with one another with the formation of water as a by-product. What masses of hexamethylene diamine and adipic acid are necessary to yield \(37.5 \mathrm{~kg}\) of completely linear nylon 6,6 ? (Note: the chemical equation for this reaction is the answer to Concept Check 15.12.)
Make two schematic plots of the logarithm of relaxation modulus versus temperature for an amorphous polymer (curve \(C\) in Figure 15.8). (a) On one of these plots demonstrate how the behavior changes with increasing molecular weight. (b) On the other plot, indicate the change in behavior with increasing crosslinking.
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