Chapter 15: Problem 9
(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted. (b) For each of these tests, cite the experimental parameter of interest and how it is determined.
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Chapter 15: Problem 9
(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted. (b) For each of these tests, cite the experimental parameter of interest and how it is determined.
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For each of the following pairs of polymers, (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature nd then cite reason(s) for your choice; and 3) if it is not possible to decide, then state why. (a) Isotactic polystyrene that has a density of \(1.12 \mathrm{~g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(150,000 \mathrm{~g} / \mathrm{mol}\); syndiotactic polystyrene that has a density of \(1.10 \mathrm{~g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(125,000 \mathrm{~g} / \mathrm{mol}\) (b) Linear polyethylene that has a degree of polymerization of 5000 ; linear and isotactic polypropylene that has a degree of polymerization of 6500 (c) Branched and isotactic polystyrene that has a degree of polymerization of 4000 ; linear and isotactic polypropylene that has a degree of polymerization of 7500
List two important characteristics for polymers that are to be used in fiber applications.
What is the distinction between dye and pigment colorants?
For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to $$ \sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right) $$ where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a timeindependent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation \(15.10\) was suddenly pulled in tension to a measured strain of \(0.6\); the stress necessary to maintain this constant strain was measured as a function of time. Determine \(E_{r}(10)\) for this material if the initial stress level was \(2.76\) MPa (400 psi), which dropped to \(1.72 \mathrm{MPa}\) (250 psi) after \(60 \mathrm{~s}\).
Normal butane and isobutane have boiling temperatures of \(-0.5\) and \(-12.3^{\circ} \mathrm{C}\) (31.1 and \(\left.9.9^{\circ} \mathrm{F}\right)\), respectively. Briefly explain this behavior on the basis of their molecular structures, as presented in Section 14.2.
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