Chapter 15: Problem 44
Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
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Chapter 15: Problem 44
Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
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Ten kilograms of polybutadiene is vulcanized with \(4.8 \mathrm{~kg}\) sulfur. What fraction of the possible crosslink sites is bonded to sulfur crosslinks, assuming that, on the average, \(4.5\) sulfur atoms participate in each crosslink?
In your own words, briefly describe the phenomenon of viscoelasticity.
List two important characteristics for polymers that are to be used in fiber applications.
For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to $$ \sigma(t)=\sigma(0) \exp \left(-\frac{t}{\tau}\right) $$ where \(\sigma(t)\) and \(\sigma(0)\) represent the timedependent and initial (i.e., time \(=0\) ) stresses, respectively, and \(t\) and \(\tau\) denote elapsed time and the relaxation time; \(\tau\) is a timeindependent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation \(15.10\) was suddenly pulled in tension to a measured strain of \(0.6\); the stress necessary to maintain this constant strain was measured as a function of time. Determine \(E_{r}(10)\) for this material if the initial stress level was \(2.76\) MPa (400 psi), which dropped to \(1.72 \mathrm{MPa}\) (250 psi) after \(60 \mathrm{~s}\).
For thermoplastic polymers, cite five factors that favor brittle fracture.
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