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If I=0, then j=s,mj=ms, and the "good" states are the same (nms)for weak and strong fields. DetermineEz1(from Equation) and the fine structure energies (Equation 6.67), and write down the general result for the I=O Zeeman Effect - regardless of the strength of the field. Show that the strong field formula (Equation 6.82) reproduces this result, provided that we interpret the indeterminate term in square brackets as.

Short Answer

Expert verified

The EZ1=e2mBext2msħand the fine structure energies is

E=-13.6eVn21+α2n2n-34+2msBexteħ2m

Step by step solution

01

Definition of Zeeman Effect.

In the presence of a static magnetic field, the Zeeman Effect causes a spectral line to break into numerous components.

02

Step2: Structural isomers of carboxylic acids.

Use the equation 6.72,

Ez1=e2mBext.L+2S=e2mBext2msħ

Fine structure energy (with j=1/2),

Enj=-13.6eVn21+α2n2n-34Etot=-13.6eVn21+α2n2n-34+2mSBext±ðħ2m

Fine structure term is proportional to α2;

Efs1=-13.6eVn4α2n-34=13.6eVn3α234n-1

{Same as equation } with the term in square brackets set equal to 1.

Efs1=13.6eVn3α234n-II+1-mImsII+1/2I+1

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Most popular questions from this chapter

Problem 6.6 Let the two "good" unperturbed states be

ψ±0=α±ψa0+β±ψb0

whereα±andβ±are determined (up to normalization) by Equation 6.22(orEquation6.24). Show explicitly that

(a)are orthogonal;role="math" localid="1655966589608" (⟨ψ+0∣ψ-0⟩=0);

(b) ⟨ψ+0|H'|ψ-0⟩=0;

(c)⟨ψ±0|H'|ψ±0⟩=E±1,withE±1given by Equation 6.27.

Consider the (eight) n=2states, |2ljmj⟩. Find the energy of each state, under weak-field Zeeman splitting, and construct a diagram like Figure 6.11 to show how the energies evolve asBext increases. Label each line clearly, and indicate its slope.

Suppose we put a delta-function bump in the center of the infinite square well:

H'=αδ(x-a/2)

whereais a constant.

(a) Find the first-order correction to the allowed energies. Explain why the energies are not perturbed for evenn.

(b) Find the first three nonzero terms in the expansion (Equation 6.13) of the correction to the ground state,Ψ11.

Calculate the wavelength, in centimeters, of the photon emitted under a hyperfine transition in the ground state (n=1) of deuterium. Deuterium is "heavy" hydrogen, with an extra neutron in the nucleus; the proton and neutron bind together to form a deuteron, with spin 1 and magnetic moment

μdl=gde2mdSd

he deuteron g-factor is 1.71.

Prove Kramers' relation:

sn2⟨rs⟩-(2s+1)a⟨rs-1⟩+s4[(2l+1)2-s2]a2⟨rs-2⟩=0

Which relates the expectation values of rto three different powers (s,s-1,ands-2),for an electron in the state ψn/mof hydrogen. Hint: Rewrite the radial equation (Equation) in the form

u''=[l(l+1)r2-2ar+1n2a2]u

And use it to expressrole="math" localid="1658192415441" ∫(ursu'')drin terms of (rs),(rs-1)and(rs-2). Then use integration by parts to reduce the second derivative. Show that ∫(ursu'')dr=-(s/2)(rs-1)and∫(u'rsu')dr=-[2/s+1]∫(u''rs+1u')dr. Take it from there.

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