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Question: In Problem 4.43you calculated the expectation value ofrsin the state321. Check your answer for the special cases s = 0(trivial), s = -1(Equation 6.55), s = -2(Equation 6.56), and s = -3(Equation 6.64). Comment on the case s = -7.

Short Answer

Expert verified

for:s=0:1s=-1:19as=-2:1135a2s=-3:1405a3

s = -7 Or smaller that the result will be undefined due to

negative numbers! = Undefined quantity

Step by step solution

01

Given information:

Equation 6.55, 6.56, 6.64 are

1r=1n2a1r2=1(l+1/2)n3a21r3=1l(l+1/2)l+1n3a3

Problem 4.43-(a) Construct the spatial wave function for hydrogen in the state n = 3 , l=2 . m = 1 Express your answer as a function of r,,, and a (the Bohr radius) only - no other variables, (p,z etc.) or ,functions, ( y , v etc.), or constants, (A,c0etc.), or derivatives, allowed ( is okay, and e, and 2 , etc.).

(b) Check that this wave function is properly normalized, by carrying out the appropriate integrals over r,,and .

(c) Find the expectation value of rsin this state. For what range of s (positive and negative) is the result finite?

02

Step 2:Check for trivial or non-trivial solution

For n = 3,l = 2,m = 1

Then:

- For s = 0:

1=6!6!1鈥︹赌︹赌.摆罢谤颈惫颈补濒闭

- For s = -1

1r=5!6!3a2-1=1623a=133a=1n2a

- For s = -2:

1r2=4!6!3a22=13023a2=2135a2=12+1233a2=11+12n3a2

03

solve further

-For s = -3

1r3=3!6!3a2-3=1120827a3=122+122+133a3=1ll+12l+1n3a3

- For s = -7

1r7=-1!6!3a2-7-1!

undentified

Then for s = -7 or smaller that the result will be undefined due to

negative numbers! = Undefined quantity

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Most popular questions from this chapter

Question: Sometimes it is possible to solve Equation 6.10 directly, without having to expand in terms of the unperturbed wave functions (Equation 6.11). Here are two particularly nice examples.

(a) Stark effect in the ground state of hydrogen.

(i) Find the first-order correction to the ground state of hydrogen in the presence of a uniform external electric fieldEext (the Stark effect-see Problem 6.36). Hint: Try a solution of the form

(A+Br+Cr2)e-r/acos

your problem is to find the constants , and C that solve Equation 6.10.

(ii) Use Equation to determine the second-order correction to the ground state energy (the first-order correction is zero, as you found in Problem 6.36(a)). Answer:-m(3a2eEext/2)2 .

(b) If the proton had an electric dipole moment p the potential energy of the electron in hydrogen would be perturbed in the amount

H'=-epcos4o0r2

(i) Solve Equation 6.10 for the first-order correction to the ground state wave function.

(ii) Show that the total electric dipole moment of the atom is (surprisingly) zero, to this order.

(iii) Use Equation 6.14 to determine the second-order correction to the ground state energy. What is the first-order correction?

The Feynman-Hellmann theorem (Problem 6.32) can be used to determine the expectation values of1/rand1/r2for hydrogen.23The effective Hamiltonian for the radial wave functions is (Equation4.53)

22md2dr2+22ml(l+1)r2-e2401r

And the eigenvalues (expressed in terms ofl)24are (Equation 4.70)

En=-me432202h2jmax+l+12

(a) Use =ein the Feynman-Hellmann theorem to obtain 1/r. Check your result against Equation 6.55.

(b) Use =lto obtain 1/r2. Check your answer with Equation6.56.

Suppose we put a delta-function bump in the center of the infinite square well:

H'=伪未(x-a/2)

whereais a constant.

(a) Find the first-order correction to the allowed energies. Explain why the energies are not perturbed for evenn.

(b) Find the first three nonzero terms in the expansion (Equation 6.13) of the correction to the ground state,11.

Work out the matrix elements of HZ'andHfs'construct the W matrix given in the text, for n = 2.

Estimate the correction to the ground state energy of hydrogen due to the finite size of the nucleus. Treat the proton as a uniformly charged spherical shell of radius b, so the potential energy of an electron inside the shell is constant:-e2/(4蟺系0b);this isn't very realistic, but it is the simplest model, and it will give us the right order of magnitude. Expand your result in powers of the small parameter, (b / a) whereis the Bohr radius, and keep only the leading term, so your final answer takes the form 螖贰E=A(b/a)n. Your business is to determine the constant Aand the power n. Finally, put in b10-15m(roughly the radius of the proton) and work out the actual number. How does it compare with fine structure and hyperfine structure?

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