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As an explicit example of the method developed inProblem 7.15, consider an electron at rest in a uniform magnetic fieldB=B2Kfor which the Hamiltonian is (Equation 4.158):

H=-B (4.158).

H0=eBzmSz (7.57).

The eigenspinors localid="1656062306189" xaandxbandthecorrespondingenergies,EaandEb, are given in Equation 4.161. Now we turn on a perturbation, in the form of a uniform field in the x direction:

{x+,withenergyE+=-纬叠0/2x-,withenergyE-=-纬叠0/2 (4.161).

H'=ebxmSx (7.58).

(a) Find the matrix elements of H鈥, and confirm that they have the structure of Equation 7.55. What is h?

(b) Using your result inProblem 7.15(b), find the new ground state energy, in second-order perturbation theory.

(c) Using your result inProblem 7.15(c), find the variation principle bound on the ground state energy.

Short Answer

Expert verified

(a)<xaH'xb>=eBx2m(01)(0110)(10)=eBx2m(01)(10)=eBx2m.soh=eBx2m.(b)EgsEa-h2(Eb-Ea)=-e2m(Bz+Bx22Bz).(c)Egs=12(eBx2m)2+4(eBx2m)2=e2mBz2+Bx2.

Step by step solution

01

(a)Finding the matrix elements of H'

For the electron, =-e/m,soE=eBz.(Eq. 4.161).

For consistency with Problem 7.15, Eb>Ea,

soXB=x+=10,xa=x-=01,Eb=E+=eBz2m,Ea=E-=-eBz2m.x+,withenergyE+=-B0/2x-,withenergyE+=+B0/2(4.161)xaH'xa=eBxm01011001=eBx2m0110.xbH'xb=eBx2m10011010=0;xbH'xa=eBx2m10011001=eBx2m10011010.xaH'xb=eBx2m01011010=eBx2m0101=eBx2m.soh=eBx2m.andtheconditionsofProblem7.15aremet.

02

(b)Finding the new ground state energy

From Problem 7.15(b),

EgsE4-h2Eb-Ea=-eBz2m-(eBz/2m)2(eBz/m)=-e2mBz+Bx22Bz.

03

(c)Finding the variation principle bound

From Problem 7.15(c),

Egs=12Ea+Eb-Eb-Ea2+4h2,(itsactuallytheexactgroundstate).Egs=12eB2m2+4eB22m2=别魔2mBz2+Bx2.whichwasobviousfromthestart,sincethesquarerootissimplythemagnitudeofthetotalfield).

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Most popular questions from this chapter

Use the WKB approximation to find the allowed energies of the harmonic oscillator.

Use the WKB approximation to find the allowed energies (En)of an infinite square well with a 鈥渟helf,鈥 of heightV0, extending half-way across

role="math" localid="1658403794484" V(x)={v0,(0<x<a/2)0,(a/2<x<a),(otherwise)

Express your answer in terms ofrole="math" localid="1658403507865" V0andEn0(苍蟺魔)2/2ma2(the nth allowed energy for the infinite square well with no shelf). Assume that, but do not assume that E10>V0. Compare your result with what we got in Section 7.1.2, using first-order perturbation theory. Note that they are in agreement if eitherV0is very small (the perturbation theory regime) or n is very large (the WKB鈥攕emi-classical鈥攔egime).

Consider the case of a symmetrical double well, such as the one pictured in Figure. We are interested in Figure 8.13bound states with E<V(0) .
(a) Write down the WKB wave functions in regions (i) x>x2 , (ii) x1<x<x2 , and (iii) 0<x<x1. Impose the appropriate connection formulas at and (this has already been done, in Equation 8.46, for x2 ; you will have to work out x1 for yourself), to show that


(x)={DPxexp-1hx2xpx'dx'2DPxsin1hx2xpx'dx'+4DPx2cos1hvx1pxdx+sine1hvx1pxdx

FIGURE 8.13: Symmetrical double well; Problem 8.15.
Where

1hx1x2p(x)dx .

(b) Because v(x) is symmetric, we need only consider even (+)and odd (-)wave functions. In the former case (0)=0 , and in the latter case =(0)=0 . Show that this leads to the following quantization condition:

tan=2ef.

Where

f1h-x1x1p(x)dx

Equation 8.59determines the (approximate) allowed energies (note that Ecomes into 1 and x2, so and are both functions of E ).

(c) We are particularly interested in a high and/or broad central barrier, in which case is large, and eis huge. Equation 8.59 then tells us thatA must be very close to a half-integer multiple of . With this in mind, write localid="1658823154085" (=n+1/2)+o . where localid="1658823172105" ||<<1, and show that the quantization condition becomes

localid="1658823190448" =(n+12)m12e-f.

(d) Suppose each well is a parabola: 16

localid="1658823244259" v(x)={12m2x+a2,ifx<012m2x-a2,ifx<0 .

Sketch this potential, find (Equation 8.58 ), and show that

localid="1658823297094" En=(n+12)hmh2e-f

Comment: If the central barrier were impenetrable localid="1658823318311" (f) , we would simply have two detached harmonic oscillators, and the energies, localid="1658823339386" En=(n+1/2)h , would be doubly degenerate, since the particle could be in the left well or in the right one. When the barrier becomes finite (putting the two wells into "communication"), the degeneracy is lifted. The even (localid="1658823360600" n+) states have slightly lower energy, and the odd ones n. have slightly higher energy.
(e) Suppose the particle starts out in the right well-or, more precisely, in a state of the form

localid="1658823391675" (x,0)=12(n++n)

which, assuming the phases are picked in the "natural" way, will be concentrated in the right well. Show that it oscillates back and forth between the wells, with a period

localid="1658823416179" =22e.

(f) Calculate , for the specific potential in part (d), and show that for , localid="1658823448873" V(0).>>E,~ma2/h.

Use the WKB approximation in the form

r1r2p(r)dr=(n-1/2)蟺丑

to estimate the bound state energies for hydrogen. Don't forget the centrifugal term in the effective potential (Equation ). The following integral may help:

ab1x(x-a)(b-x)dx=2(b-a)2.

Note that you recover the Bohr levels whenn/andn1/2

Use the WKB approximation to find the allowed energies of the general power-law potential:

V(x)=|x|vwhere v is a positive number. Check your result for the case v=2 .

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