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Consider the case of a symmetrical double well, such as the one pictured in Figure. We are interested in Figure 8.13bound states with E<V(0) .
(a) Write down the WKB wave functions in regions (i) x>x2 , (ii) x1<x<x2 , and (iii) 0<x<x1. Impose the appropriate connection formulas at and (this has already been done, in Equation 8.46, for x2 ; you will have to work out x1 for yourself), to show that


(x)={DPxexp-1hx2xpx'dx'2DPxsin1hx2xpx'dx'+4DPx2cos1hvx1pxdx+sine1hvx1pxdx

FIGURE 8.13: Symmetrical double well; Problem 8.15.
Where

1hx1x2p(x)dx .

(b) Because v(x) is symmetric, we need only consider even (+)and odd (-)wave functions. In the former case (0)=0 , and in the latter case =(0)=0 . Show that this leads to the following quantization condition:

tan=2ef.

Where

f1h-x1x1p(x)dx

Equation 8.59determines the (approximate) allowed energies (note that Ecomes into 1 and x2, so and are both functions of E ).

(c) We are particularly interested in a high and/or broad central barrier, in which case is large, and eis huge. Equation 8.59 then tells us thatA must be very close to a half-integer multiple of . With this in mind, write localid="1658823154085" (=n+1/2)+o . where localid="1658823172105" ||<<1, and show that the quantization condition becomes

localid="1658823190448" =(n+12)m12e-f.

(d) Suppose each well is a parabola: 16

localid="1658823244259" v(x)={12m2x+a2,ifx<012m2x-a2,ifx<0 .

Sketch this potential, find (Equation 8.58 ), and show that

localid="1658823297094" En=(n+12)hmh2e-f

Comment: If the central barrier were impenetrable localid="1658823318311" (f) , we would simply have two detached harmonic oscillators, and the energies, localid="1658823339386" En=(n+1/2)h , would be doubly degenerate, since the particle could be in the left well or in the right one. When the barrier becomes finite (putting the two wells into "communication"), the degeneracy is lifted. The even (localid="1658823360600" n+) states have slightly lower energy, and the odd ones n. have slightly higher energy.
(e) Suppose the particle starts out in the right well-or, more precisely, in a state of the form

localid="1658823391675" (x,0)=12(n++n)

which, assuming the phases are picked in the "natural" way, will be concentrated in the right well. Show that it oscillates back and forth between the wells, with a period

localid="1658823416179" =22e.

(f) Calculate , for the specific potential in part (d), and show that for , localid="1658823448873" V(0).>>E,~ma2/h.

Short Answer

Expert verified

Therefore,

(a) WKBxDpxexp1hx2xpx'dxDpxsin1hx2xpx'dx+4Dpx2cosePx'dx+sine-1hxx1pxdx'
(b) =1/-x1xp(x')dx.

(c)n+12+12e- .
(d) En+=n+12+2e-.
(e) =22e.

(f) ~ma2 is showed.

Step by step solution

01

(a) By using wave function. 

Write down the WKB wave functions in regions (i) x >x2, (ii) x1>x>x2and (iii) <x<x1. Impose the appropriate connection formulas at x1and x2, to show that

WKBxDpxexp1hx2xpx'dxDpxsin1hx2xpx'dx+4Dpx2cosePx'dx+sine-1hxx1pxdx'

The WKB wave function takes the form,

WKBxDpxexp1hx2xpx'dxDpxsin1hx2xpx'dx+4

To do the same thing for the turning point , we will follow the same procedure. But first let's rewrite localid="1658393003007" WKB. (ii) in such a form that help us effectively join it with WKB. (iii) atX1. Using the definition of Equating 9.59, we rewrite the WKB wave function in region (ii) as

WKBx2Dpxsin-1hx1xpx'dx'+4

The next step then is to patch the WKB solutions (in regions (ii) and (iii)) at. Let us shift the axes over so that the turning pointoccurs at, then we have

WKBx-2Dpxsin1hx2xpx'dx--4,x>01pxFe1nx0Px'dx+Ge-1hxx1pxdx'X<0 鈥︹︹︹︹ ()

The turning pointsx1has a downward slope, so the patching wave function, in this case, assumes the form

px=aAi-ax+bBi-ax鈥︹︹︹︹︹︹︹ ( 2)

Where a=2mV0/h21/3, and also, the momentum, in this case, takes the following form:

px=ha3/2x

.

02

In particular, for x<0.

For,

x0px'dx'a3/2x0-x'dx'=23-ax3/2

And therefore the WKB wave function (Equation (1)) can be written as

WKBx1ha3/4-x1/4Fe23-ax3/2+Ge-23(-ax)3/2

Meanwhile, using the large- z asymptotic form of the Airy function for large positive z (remember thatz=-ax), the patching wave function (Equation (2)), for x<0, becomes

px1-ax1/4a2e-23-ax3/2+be23-ax3/2

Comparing the WKB and patching wave functions in the region where x<0 , we find

a=2aGand b=aF 鈥︹︹︹︹︹︹(3 )

03

In particular, for x>0.

For x>0 , we have

0xP'xdx'a3/20xx0xP'xdx=23ax3/2

and therefore the WKB wave function (Equation ()) can be written asWKBX-2Da3/4x1/4sin23ax3/2--4WKBX-2Da3/4x1/4cos23ax3/2+4-

Let 2/3ax3/2+/4, then using elementary trigonometry,

WKBX2Da3/4x1/4coscos+sinsin

Meanwhile, using the large-z asymptotic form of the Airy function for large negative z (remember that z=-ax ), the patching wave function (Equation (2)) x>0 , for becomes

localid="1658823967085" px1ax1/4asin+bcos

(In terms of). Comparing the WKB and patching wave functions in the region where x>0, we find

a=2DasinAnd b=2Dhacos

Or, putting in Equation (3) for and :

G=DsinAnd F=2Dcos

These are the connection formulas, joining the WKB solutions at either side of the turning point . Expressing everything in terms of the one normalization constant D , and shifting the turning point back from the origin to an arbitrary point x1, we show that the WKB wave function in the three regions (i), (ii) and (iii) is

localid="1658824119486" WKBxDpxexp-1hx2xpxdx'2Dpxsin1hxx2px'dx+4DpxI2cose1rxx1px'dx+sine1rxx1px'dx' 鈥︹赌︹赌︹赌︹赌(4)

Where,

=1/x1x2pxdx

04

(b) Odd wave function with quantization condition.

Let's start by the easy case; the oddwave functions. It requires0=0.


(iii) (Equation (4)), we have

localid="1658402848392" sine-1r0x1pxdx'=-2cos1r0x1px'dx

(AssumingD0), which leads to

tan=-2e1r0x1px'dx

tan=-2e1r0x1px'dx

Where the second equality is valid by the virtue of symmetry of v(x) (remember that ) Ipxi=2mIE-vxI. Introducing whose definition is given by Equation 9.61, we can write

tan=-2e

Consider the case of even (+) wave functions. This requires0=0. The derivative ofWKB(region (iii) in Equation (4)) is

WKBx=-12IpxIdIPxIdxWKBx+DIpxI2cose1rxx1px;dx-1hIpxI+sine1rxx1pxdx1hIpxI................. ( X)

At X=0 , the first term vanishes by the fact that

dIPxIdxx-0=ddx2mVx-EX-OdIPxIdxx-0=mV'02mV0-E=0

(Indeed V(0)=0since V(x) since is symmetric). Thus WKB0=0 (Equation ( 5)) leads to

-2cose/2+sine-/2=0

tan=2e (Or)

Putting the results together, we see that the requirements0=0and0=0leads to the following quantization condition:

=1/h-xx1px'dx 鈥︹︹︹︹︹︹︹ ()

Where,

=1/-x1x1px'dx'.

05

(c) Using quantization condition.

The quantization condition (equation (6)), with=n+1/2+owhereo<<1, becomes

tann+1/2+tano1-tann+1/2tano=2e

Dividing the numerator and denominator of the fraction on the lefttann+1/2by and realizing thatan(n+$$1/2), the equation reduces to

-1tano1o=2e (or) o=12e-

Expressing the result in terms ofyields the following form of quantization condition:

n+12+12e- 鈥︹︹︹︹︹︹ (7 )

06

(d) Sketch the graph by using V(x).

Figure shows the sketch of the potential V (X) . Since the right-side parabola (for X>0 ) is symmetric about X=A and the integration limits X1and X2are equidistant from a , then we can write

=2hax2pxdx

Where the turning pointX2satisfies,

E=Vx2=12m2x2-a2鈥︹︹︹︹.. (8 )

In this case,

px=2mE-1/2M2x-a2px=mx2-a2-x-a2

Thus,

=2mhax2x2-a=x-a2dx

By using the substitution, u=x-a , this integral simply appears to be the area of a quarter circle with radius x2-a, which is trivial to calculate:

=2mh0x2-ax2-a2-u2du=m2hx2-a2=hE

(Equation ( 8)), and the quantization condition (Equation (7 )) yields

n+1212e-=hEN

(Or)

En=n+12h+h2e- 鈥︹赌︹赌︹赌︹赌.(9)

To sketch a symmetric double parabola V(x).

07

(e) Sketch the graph.

Suppose the particle starts out in the right well that is a state of the form

=x,0=12n++N-

It is also useful to define the state in which the particle resides in the left well;

=12N+-N-

At arbitrary time, the state of the particle (tacking on the phases in the natural way) evolves to

x,t=12n+e-iEn+tir+n-e-iEn-tirx,t=12e-En+tirn++n-e-ist

Where we define localid="1658464326203" En--EN+IIt follows that

Ix,tI2=12n+2+n-2+n+n-eist+e-ist

We used the fact and are real functions (see Equation (4 )). Since eist+e-ist/2=cost(Euler's formula), we can write

Ix,tI2=12n+2+n-2+2n+n-cos未迟

Here we notice something remarkable. Att =0

滨蠄x,02=12n++n-2滨蠄x,02=r2

The particle starts out at the right well (as expected).localid="1658467491416" Att=/

localid="1658467501051" x,/2=12n+-n-2x,/2=2

The particle hops into the left well. Atlocalid="1658467510407" t=2/, the particle jumps back again into the right well, and we see the particle keeps oscillating back and forth between the wells, with a period

localid="1658467528233" t=2=2En--EN+=22e

To sketch for localid="1658467548354" e+and localid="1658467540229" e- (for x<0 ).

To sketch for e+ and e-(for ).

To sketch the probability density att =0

08

(f) To evaluate the integral of.

The specific potential in part (d) is symmetric, and so we need to deal only with the right parabola well then we double the answer. In this case (for x>0),

Ipx=2mIE-12m蝇2x-a2IpxI=m蝇x1-a2-x-a2

Where the turning pointsx1satisfies,

E=12m2x1-a2

Thus,

=2mh0x1a-x2-a-x12dx

This integral can be done using the change of variables,a-x=a-x1cosh. It follows (check the answer yourself!)

=mahy2yy2-1-Iny+y2-1

Where yaIa-x1>1.

For V(0)>>E, that is a2>>x1-a2, or y2>>1,

localid="1658824827027" ~ma2hy2y2-2In2y~ma2

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Most popular questions from this chapter

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