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Suppose two spin -1/2particles are known to be in the singlet configuration (Equation Let Sa(1)be the component of the spin angular momentum of particle number 1 in the direction defined by the unit vectora^ Similarly, letSb(2) be the component of 2鈥檚 angular momentum in the directionb^ Show that

Sa(1)Sb(2)=-24肠辞蝉胃

where is the angle between a^ andb^

Short Answer

Expert verified

It is proved that Sa(1)Sb(2)=-24肠辞蝉胃.

Step by step solution

01

Expression for the Singlet, Triplet and Pauli spin operators

The singlet state of two spin-12particles is defined as follows:

|00>12(-)

The triplet state of two spin role="math" localid="1658204414547" -12 particles is defined as follows:

|11||101/2(|+|)|1-1|

The action of Pauli spin operators on the quantum states is defined as follows:

Sz|=2|Sz|=-/2|Sx|=/2|Sx|=/2|

The previous spin states are orthonrmalized.

That is :

0011=001-1=1-111=0

And

0000=1111=1-11-1=1

02

Determination of the angle between  a^ and  b^

Assume, without loss of generality, that the component of the angular momentum vector of particle numberl,Sa1, is directed in the z direction while the component of the angular momentum vector of particle number2,Sb2, is located in the zx -plane with an anglebetween the two normalized operators' vectors,a^andb^, respectively.

Sa1=Sz1andSb2=cos胃厂z2+sin胃厂x2

Calculate the expectation value ofSa1Sb2in the singlet state of the two spin--12particles,00>.

role="math" localid="1658206640658" Sa1Sb2=00Sa1Sb200=1200Sz1cos胃厂z2+sin胃厂x2-=1200Sz1cos胃厂z2+sin胃厂x2-1200Sz1cos胃厂z2+sin胃厂x2=1200Sz1cos胃厂z2+sin胃厂x2+1200Sz1cos胃厂z2+sin胃厂x2

Simplify the above expression.

1200Sz1cos胃厂z2+sin胃厂x2-1200Sz1cos胃厂z2+sin胃厂x2=1200Sz1cos胃厂z2+1200Sz1sin胃厂x2-1200Sz1cos胃厂z2-1200Sz1sin胃厂x2=cos200h2h2+sin200h2h2-cos200h2h2-sin200h2h2=cos2.h200-++sin2.h200+

Further evaluate the above expression.

-24肠辞蝉胃0012-+24蝉颈苍胃0012-=-24肠辞蝉胃0000+-242蝉颈苍胃0011+242蝉颈苍胃001-1=-24肠辞蝉胃+0+0=-24肠辞蝉胃

The expectation value of the product of the operators Sa(1) and Sb(2)Sa(1)Sb(2) in the singlet state, |00, of the two spin- -12particles is: -24肠辞蝉胃.

Thus,role="math" localid="1658204824299" Sa(1)Sb(2)=-24肠辞蝉胃whereis the angle betweena^andb^is 0.

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Most popular questions from this chapter

The fundamental commutation relations for angular momentum (Equation 4.99) allow for half-integer (as well as integer) eigenvalues. But for orbital angular momentum only the integer values occur. There must be some extra constraint in the specific formL=rp that excludes half-integer values. Let be some convenient constant with the dimensions of length (the Bohr radius, say, if we're talking about hydrogen), and define the operators

q112[x+a2/py];p112[px-(/a2)y];q212[x-(a2/)py];p212[px-(/a2)y];

(a) Verify that [q1,q2]=[p1,p2]=0;[q1,p1]=[p2,q2]=i. Thus the q's and the p's satisfy the canonical commutation relations for position and momentum, and those of index 1are compatible with those of index 2 .

(b) Show that[q1,q2]=[p1,p2]Lz=2a2(q12-q22)+a22(p12-p22)

(c) Check that , where each is the Hamiltonian for a harmonic oscillator with mass and frequency .

(d) We know that the eigenvalues of the harmonic oscillator Hamiltonian are , where (In the algebraic theory of Section this follows from the form of the Hamiltonian and the canonical commutation relations). Use this to conclude that the eigenvalues of must be integers.

(a) Prove the three-dimensional virial theorem

2T=rV

(for stationary states). Hint: Refer to problem 3.31,

(b) Apply the virial theorem to the case of hydrogen, and show that

T=-En;V=2En

(c) Apply the virial theorem to the three-dimensional harmonic oscillator and show that in this case

T=V=En/2

Work out the normalization factor for the spherical harmonics, as follows. From Section 4.1.2we know that

Ylm=BlmeimPlmcos

the problem is to determine the factor (which I quoted, but did not derive, in Equation 4.32). Use Equations 4.120, 4.121, and 4.130to obtain a recursion

relation giving Blm+1 in terms of Blm. Solve it by induction on to get Blm up to an overall constant Cl, .Finally, use the result of Problem 4.22 to fix the constant. You may find the following formula for the derivative of an associated Legendre function useful:

1-x2dPlmdx=1-x2Plm+1-mxPlm [4.199]

Deduce the condition for minimum uncertainty inSx andSy(that is, equality in the expression role="math" localid="1658378301742" SxSy(/2)|<Sz>|, for a particle of spin 1/2 in the generic state (Equation 4.139). Answer: With no loss of generality we can pick to be real; then the condition for minimum uncertainty is that bis either pure real or else pure imaginary.

(a) Find鈱﹔鈱猘nd鈱﹔虏鈱猣or an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius.

(b) Find鈱﹛鈱猘nd (x2)for an electron in the ground state of hydrogen.

Hint: This requires no new integration鈥攏ote that r2=x2+y2+z2,and exploit the symmetry of the ground state.

(c) Find鈱﹛虏鈱猧n the state n=2,l=1,m=1. Hint: this state is not symmetrical in x, y, z. Usex=rsincosx=rsincos

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