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The fundamental commutation relations for angular momentum (Equation 4.99) allow for half-integer (as well as integer) eigenvalues. But for orbital angular momentum only the integer values occur. There must be some extra constraint in the specific formL=r×p that excludes half-integer values. Let be some convenient constant with the dimensions of length (the Bohr radius, say, if we're talking about hydrogen), and define the operators

q1≡12[x+a2/ħpy];p1≡12[px-(ħ/a2)y];q2≡12[x-(a2/ħ)py];p2≡12[px-(ħ/a2)y];

(a) Verify that [q1,q2]=[p1,p2]=0;[q1,p1]=[p2,q2]=iħ. Thus the q's and the p's satisfy the canonical commutation relations for position and momentum, and those of index 1are compatible with those of index 2 .

(b) Show that[q1,q2]=[p1,p2]Lz=ħ2a2(q12-q22)+a22ħ(p12-p22)

(c) Check that , where each is the Hamiltonian for a harmonic oscillator with mass and frequency .

(d) We know that the eigenvalues of the harmonic oscillator Hamiltonian are , where (In the algebraic theory of Section this follows from the form of the Hamiltonian and the canonical commutation relations). Use this to conclude that the eigenvalues of must be integers.

Short Answer

Expert verified

a) The equations are verified.

b) It is proved that.

c) The equationis checked and verified.

d) It is concluded that the eigenvalues of are integers.

Step by step solution

01

Definition of angular momentum

The rotating equivalent of linear momentum is angular momentum. Because it is a conserved quantity—the total angular momentum of a closed system remains constant—it is a significant quantity in physics.

Both the direction and the amplitude of angular momentum are preserved.

02

Verify that [q1,q2]=[p1,p2]=0;[q1,q2]=[q2,p2]=iħ

(a)

Consider that,

q1≡12x+a2/ħpy;q1≡12px-ħ/a2y;p2≡12x-a2/ħpy;q2≡12px+ħ/a2y;

Now, the commutation relation between q1and q2is,

localid="1658311027712" q1,q2=12x+a2ħpy,12x-a2ħpy=12[x,x]+x,-a2ħpy+a2ħpy,a2ħpy=0

Since, x,x=py,py=0

Also, the commutation relation between p1and p2is,

localid="1658311843930" p1,p2=12px-ħa2y,12px+ħħa2y=12[px,px]+12px,ħa2y-12ħa2y,px-12ħa2y,a2ħyAs,px,px=y,y=px,y=0

The commutation relation between q1and p1is,

role="math" localid="1658313061062" q1,p1=12x+a2ħ,12px-ħa2y=12x,px+12a2ħpy,px-12x,ħa2y-12a2ħpy,ħa2=12x,px-12py,y=12iħ--iħ=2iħ2=iħ

And, commutation relation between q2and p2is,

role="math" localid="1658313694232" q2,p2=12x-a2ħpy,12px+ħa2y=12x,px+12x,ħa2y-12a2ħpy,px-12a2ħpy,ħa2y=12x,px-12py,y=2iħ2=iħAs,x,y=py,px=0Butx,px=iħandpy,y=-iħTherefore,theabovefindingsuggeststhatq'sandp'sfollowtheposition-momentumquantumcommutationrelations,qi,pj=iħδij.

03

Show that Lz=ħ2a2(q12-q22)+a22ħ(p12-p22) 

(b)

Evaluate q12-q22and p12-p22to obtain their relation with the z-component of the angular momentum:

q12-q22=12x2+a2ħpy2+a2ħx,py-12x2+a2ħpy2+a2ħx,py=a2ħx,py=2a2ħxpy

Also,

p12-p22=12px2+ħa22y2-ħa2pxy+ypx-px2-ħa22y2-ħa2pxy+ypx=-2ħa2ypx

Now,

ħ2a2q12-q22+a22ħp12-p22=ħ2a22a2ħxpy+a22ħ2ħa2xpx=xpy-ypx=Lz

Thus, the relation with the z component of angular momentum is established.

04

Check that Lz=H1-H2 

(c)

The Hamiltonian for the harmonic oscillator is,

H=p22m+12mӬ2x2Form=ħa2andӬ=1H=12mP2+12mӬ2x2=a22ħp2+ħ2a2x2

And

H1=a22ħp12+ħ2a2q12H2=a22ħp22+ħ2a2q22H1-H2=a22ħp12-p22+ħ2a2q12-q22=Lz

Thus, the relationship is established.

05

The eigenvalues of Lz must be integers

(d)

The values of eigenvalues ofLzare integers. So,

Hψ〉=n-12ħӬ

Then,

H1-H2ψ〉=Lzψ⟩=n1-12-n2-12ħӬψ〉

ForÓ¬=1:

L2ψ〉=n1,n2ħψ⟩

Here n1,n2=0,1,2,3,...

Lzψ〉=mħψ⟩,is an integer since .

Hence, the eigenvalues of Lzmust be integers.

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Most popular questions from this chapter

(a) Work out the Clebsch-Gordan coefficients for the case s1=1/2,s2=anything. Hint: You're looking for the coefficients A and Bin

|sm⟩=A|1212⟩|s2(m-12)⟩+B|12(-12)⟩|s2(m+12)⟩

such that|sm⟩ is an eigenstate of . Use the method of Equations 4.179 through 4.182. If you can't figure out whatSx(2) (for instance) does to|s2m2⟩ , refer back to Equation 4.136 and the line before Equation 4.147. Answer:

;role="math" localid="1658209512756" A=s2+12±m2s2+1;B=±s2+12±m2s2+1

where, the signs are determined bys=s2±1/2 .

(b) Check this general result against three or four entries in Table 4.8.

An electron is in the spin state

χ=A3i4

(a) Determine the normalization constant .

(b) Find the expectation values of Sx,Sy , and Sz.

(c) Find the "uncertainties" ,σSx , σSyandσSz . (Note: These sigmas are standard deviations, not Pauli matrices!)

(d) Confirm that your results are consistent with all three uncertainty principles (Equation 4.100 and its cyclic permutations - only with in place ofL, of course).

(a) Find〈r〉and〈r²〉for an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius.

(b) Find〈x〉and (x2)for an electron in the ground state of hydrogen.

Hint: This requires no new integration—note that r2=x2+y2+z2,and exploit the symmetry of the ground state.

(c) Find〈x²〉in the state n=2,l=1,m=1. Hint: this state is not symmetrical in x, y, z. Usex=rsinθcosπx=rsinθcosϕ

[Attempt this problem only if you are familiar with vector calculus.] Define the (three-dimensional) probability current by generalization of Problem 1.14:

J=ih2m(ψ∇ψ*-ψ*∇ψ)

(a) Show that satisfies the continuity equation ∇.J=-∂∂t|ψ|2which expresses local conservation of probability. It follows (from the divergence theorem) that ∫sJ.da=-ddt∫v|ψ|2d3rwhere Vis a (fixed) volume and is its boundary surface. In words: The flow of probability out through the surface is equal to the decrease in probability of finding the particle in the volume.

(b) FindJfor hydrogen in the staten=2,l=1,m=1 . Answer:

h64ma5re-r/a²õ¾±²Ôθϕ^

(c) If we interpretmJas the flow of mass, the angular momentum is

L=m∫(r×J)d3r

Use this to calculate Lzfor the stateψ211, and comment on the result.

Consider the observablesA=x2andB=Lz .

(a) Construct the uncertainty principle forσAσB

(b) EvaluateσB in the hydrogen stateψn/m .

(c) What can you conclude about<xy>in this state?

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