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Ethyl alcohol has a boiling point of78.0°°ä, a freezing point of−114°°ä, a heat of vaporization of879 k´³/°ì²µ, a heat of fusion of109 k´³/°ì²µ, and a specific heat of2.43 k´³/°ì²µK. How much energy must be removed from0.510 k²µof ethyl alcohol that is initially a gas at78.0 °°äso that it becomes a solid at−114 °°ä?

Short Answer

Expert verified

The amount of energy removed from ethyl alcohol is742 â¶Ä‰k´³.

Step by step solution

01

The given data

i) Boiling point of ethyl alcohol is78.0 0C.

ii) Freezing point of ethyl alcohol is−114 0C

iii) Latent heat of vaporization of ethyl alcohol (Lv)is879 k´³/°ì²µ

iv) Mass of ethyl alcohol is0.510 k²µ

v) Heat of fusion is109 k´³/°ì²µ

vi) Specific heat Is 2.43 k´³/°ì²µK

02

Understanding the concept of specific heat

A substance's specific heat capacity is the amount of energy required to raise its temperature by one degree Celsius. The values of latent heat of vaporization, freezing point, boiling point, and also the mass of the ethyl alcohol are given. Using these values and the equation for specific heat capacity and latent heat, we can calculate the amount of heat removed from ethyl alcohol by using the equations.

Formula:

The heat energy required by a body, Q=mcΔT …(¾±)

Where,m = mass

c= specific heat capacity

ΔT= change in temperature

Q= required heat energy

The heat energy released or absorbed by the body,Q=mL …(¾±¾±)

Where,

L= specific latent heat of vaporization

03

Calculation of amount of energy

The phase change occurs at780C.To find the heat required for this phase change, we can use the formula (ii) as given:

Q1=879 k´³kg×0.510 k²µ=448.29 k´³

To cool the liquid to−1140Cthe heat energy required for this phase can be given using the formula of equation (i) as given:

Q2=2.43kJkg.K×0.510 k²µÃ—192‿é=237.95kJ

Finally, to accomplish the phase change at,−1140C we use the formula of equation (ii), which is given as:

Q3=109kJkg×0.510 k²µ=55.59kJ

Therefore, the total amount of heat to be removed from ethyl alcohol is given as:

Qtotal=448.29 k´³+237.95 k´³+55.59 k´³=741.9 k´³â‰ˆ742 k´³

Hence, the amount of heat to be removed is742 k´³

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