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Consider a mass separator that applies a magnetic field perpendicular to the velocity of ions and separates the ions based on the radius of curvature of their paths in the field. Construct a problem in which you calculate the magnetic field strength needed to separate two ions that differ in mass, but not charge, and have the same initial velocity. Among the things to consider are the types of ions, the velocities they can be given before entering the magnetic field, and a reasonable value for the radius of curvature of the paths they follow. In addition, calculate the separation distance between the ions at the point where they are detected.

Short Answer

Expert verified
  1. The magnetic field strength is \({\rm{0}}{\rm{.4}}\;{\rm{T}}\).
  2. The curvature radius is\({\rm{0}}{\rm{.37}}\;{\rm{m}}\).
  3. The mass is\({\rm{5}}{\rm{.92}} \times {\rm{1}}{{\rm{0}}^{{\rm{ - 27}}}}\;{\rm{kg}}\).
  4. The separation distance is \({\rm{0}}{\rm{.2}}\;{\rm{m}}\).

Step by step solution

01

Define Magnetic field

Magnetic field lines are never crossed. The strength of the field is determined by the density of the field lines.

02

Constructing a problem

In a mass spectrometer, single-charged chloride\({\rm{Cl - }}\)and oxide \({\rm{O - }}\)ions are separated. The mass ratio of these ions is\({\rm{27}}\)to\({\rm{59}}\), with oxide having a mass of\({\rm{2}}{\rm{.7 \times 1}}{{\rm{0}}^{{\rm{ - 27}}}}{\rm{kg}}\)Both ions travel at a speed of\({\rm{4}} \times {\rm{1}}{{\rm{0}}^{\rm{6}}}\;{{\rm{m}} \mathord{\left/

{\vphantom {{\rm{m}} {\rm{s}}}} \right.

\kern-\nulldelimiterspace} {\rm{s}}}\).

(a) Determine the magnetic field strength required to keep\({\rm{O - }}\)in a circular path with a radius of\({\rm{0}}{\rm{.17}}\)m.

(b) What is the curvature radius that\({\rm{Cl - }}\)follows?

(c) Calculate the mass of\({\rm{Cl - }}\)using the findings from (a) and (b).

(d) If the ions are identified after crossing a semicircle, what is the separation distance between them?

03

Solution- Evaluating the magnetic field strength

(a)

Solving for\({\rm{B}}\)by using the equation,

\(\begin{aligned}{c}{\rm{r}} &= \frac{{{\rm{mv}}}}{{{\rm{qB}}}}\\{\rm{B}} &= \frac{{{\rm{mv}}}}{{{\rm{qr}}}}\\{\rm{B}} &= \frac{{\left( {{\rm{2}}{\rm{.7}} \times {\rm{1}}{{\rm{0}}^{{\rm{ - 27}}}}\;{\rm{kg}}} \right) \times \left( {{\rm{4}} \times {\rm{1}}{{\rm{0}}^{\rm{6}}}\;{m \mathord{\left/

{\vphantom {m s}} \right.

\kern-\nulldelimiterspace} s}} \right)}}{{\left( {{\rm{1}}{\rm{.6}} \times {\rm{1}}{{\rm{0}}^{{\rm{ - 19}}}}\;{\rm{C}}} \right) \times \left( {{\rm{0}}{\rm{.17}}\;{\rm{m}}} \right)}}\\{\rm{B}} &= {\rm{0}}{\rm{.4}}\;{\rm{T}}\end{aligned}\)

Therefore, the magnetic field strength is \({\rm{0}}{\rm{.4}}\;{\rm{T}}\).

04

Solution- Evaluating the curvature radius

(b)

Since the radius is directly proportional to mass, the radius of curvature is obtained by considering the ratio of ions masses.

\(\begin{aligned}{l}\frac{{{{\rm{r}}_{{\rm{O - }}}}}}{{{{\rm{r}}_{{\rm{Cl - }}}}}} &= \frac{{{{\rm{m}}_{{\rm{O - }}}}}}{{{{\rm{m}}_{{\rm{Cl - }}}}}}\\\frac{{{\rm{0}}{\rm{.17}}\;{\rm{m}}}}{{{{\rm{r}}_{{\rm{Cl - }}}}}} &= \frac{{{\rm{27}}}}{{{\rm{59}}}}\\{{\rm{r}}_{{\rm{Cl - }}}} &= {\rm{0}}{\rm{.17}}\;{\rm{m}} \times \left( {\frac{{{\rm{59}}}}{{{\rm{27}}}}} \right)\\{{\rm{r}}_{{\rm{Cl - }}}} &= {\rm{0}}{\rm{.37}}\;{\rm{m}}\end{aligned}\)

Therefore, the curvature radius is \({\rm{0}}{\rm{.37}}\;{\rm{m}}\).

05

Solution- Evaluating the mass

(c)

Solving for\({{\rm{m}}_{{\rm{Cl - }}}}\)and filling in the numbers using the findings from (a) and (b) provides

\(\begin{aligned}{c}{{\rm{r}}_{{\rm{Cl - }}}} &= \frac{{{{\rm{m}}_{{\rm{Cl - }}}}{\rm{v}}}}{{{\rm{qB}}}}\\{{\rm{m}}_{{\rm{Cl - }}}} &= \frac{{{{\rm{r}}_{{\rm{Cl - }}}}{\rm{qB}}}}{{\rm{v}}}\\ &= \frac{{\left( {{\rm{0}}{\rm{.37}}\;{\rm{m}}} \right) \times \left( {{\rm{1}}{\rm{.6 \times 1}}{{\rm{0}}^{{\rm{ - 19}}}}\;{\rm{C}}} \right) \times \left( {{\rm{0}}{\rm{.4}}\;{\rm{T}}} \right)}}{{{\rm{4}} \times {\rm{1}}{{\rm{0}}^{\rm{6}}}\;{m \mathord{\left/

{\vphantom {m s}} \right.

\kern-\nulldelimiterspace} s}}}\\ &= {\rm{5}}{\rm{.92}} \times {\rm{1}}{{\rm{0}}^{{\rm{ - 27}}}}\;{\rm{kg}}\end{aligned}\)

Therefore, the mass is \({\rm{5}}{\rm{.92}} \times {\rm{1}}{{\rm{0}}^{{\rm{ - 27}}}}\;{\rm{kg}}\).

06

Solution- Evaluating the separation distance

(d)

When the ions are discovered, the separation distance\({\rm{d}}\)between them is just the difference in their radii.

\(\begin{aligned}{c}{\rm{d}} &= {{\rm{r}}_{{\rm{Cl - }}}} - {{\rm{r}}_{{\rm{O - }}}}\\ &= {\rm{0}}{\rm{.37}}\;{\rm{m}} - {\rm{0}}{\rm{.17}}\;{\rm{m}}\\ &= {\rm{0}}{\rm{.2}}\;{\rm{m}}\end{aligned}\)

Therefore, the separation distance is\({\rm{0}}{\rm{.2}}\;{\rm{m}}\).

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