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Keeping only the first two diagrams in equation 8.23, and approximating NN-1N-2..... expand the exponential in a power series through the third power. Multiply each term out, and show that all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.

Short Answer

Expert verified

By doing the expansion, the symmetry factors come out naturally fromZc.

Step by step solution

01

Given Information 

We need to find all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.

02

Simplify

Lets first write out the expression 8.23in mathematical form (without diagrams):

Zc=exp12NN1V2d3r1d3r2f12+12NN1N2V3d3r1d3r2d3r3f12f23

Now we can do the approximation NN-1N-2.. Then we need to expand 's Zcexp function to the third power:

Zcexp12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23exp1++122+163+Zc=1+12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23+18N4V4d3r1d3r2d3r3d3r4f12f34+18N6V6d3r1d3r2d3r3d3r4d3r5d3r6f12f23f45f56+14N5V5d3r1d3r2d3r3d3r4d3r5f12f14f45+

To examine those integrals we have to add one more degree of integrals comming from the 3of the. This would give:

Zc=1+12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23+18N4V4d3r1d3r2d3r3d3r4f12f34+18N6V6d3r1d3r2d3r3d3r4d3r5d3r6f12f23f45f56+14N5V5d3r1d3r2d3r3d3r4d3r5f12f34f45+148N6V6d3r1d3r2d3V3d3r4d3r5d3r6f12f34f56+116N7V7d3r1d3r2d3r3d3r4d3r5d3r6d3r7f12f34f56f67+148N9V9d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8d3r9f12f23f45f56f78f89

We can see that in front of every integral asymmetry factor arises, we can check that on the example of this last integral:

+148N9V9d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8d3r9f12f23f45f56f78f89

If we draw it's diagram and look for dots that can change the place we get exactly 48permutations:

03

Explanation 

Another example can be integral:

116N8V8d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8f12f34f45f67f78

We can see that counting permutations, which is counting the dots with the same role in the integral and possible place where they can be interchanged, is exactly what we get from Taylor's expansion of $Z,c$.By doing the expansion, the symmetry factors come out naturally.

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Most popular questions from this chapter

In this problem you will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

(a) Prove that, when x1,tanhxx-13x3

(b) Use the result of part (a) to find an expression for the magnetisation of the Ising model, in the mean field approximation, when T is very close to the critical temperature. You should find MTc-T,where(not to be confused with 1/kT) is a critical exponent, analogous to the f defined for a fluid in Problem 5.55. Onsager's exact solution shows that =1/8in two dimensions, while experiments and more sophisticated approximations show that 1/3in three dimensions. The mean field approximation, however, predicts a larger value.

(c) The magnetic susceptibility is defined as (M/B)T. The behaviour of this quantity near the critical point is conventionally written as T-Tc- , where y is another critical exponent. Find the value of in the mean field approximation, and show that it does not depend on whether T is slightly above or slightly below Te. (The exact value of y in two dimensions turns out to be 7/4, while in three dimensions 1.24.)

For each of the diagrams shown in equation 8.20, write down the corresponding formula in terms of f-functions, and explain why the symmetry factor gives the correct overall coefficient.

Use the cluster expansion to write the total energy of a monatomic nonideal gas in terms of a sum of diagrams. Keeping only the first diagram, show that the energy is approximatelyU32NkT+N2V20r2u(r)e-u(r)drUse a computer to evaluate this integral numerically, as a function of T, for the Lennard-Jones potential. Plot the temperature-dependent part of the correction term, and explain the shape of the graph physically. Discuss the correction to the heat capacity at constant volume, and compute this correction numerically for argon at room temperature and atmospheric pressure.

Draw all the diagrams, connected or disconnected, representing terms in the configuration integral with four factors of fij. You should find 11 diagrams in total, of which five are connected.

Draw all the connected diagrams containing four dots. There are six diagrams in total; be careful to avoid drawing two diagrams that look superficially different but are actually the same. Which of the diagrams would remain connected if any single dot were removed?

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