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In this problem you will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

(a) Prove that, when x1,tanhxx-13x3

(b) Use the result of part (a) to find an expression for the magnetisation of the Ising model, in the mean field approximation, when T is very close to the critical temperature. You should find MTc-T,where(not to be confused with 1/kT) is a critical exponent, analogous to the f defined for a fluid in Problem 5.55. Onsager's exact solution shows that =1/8in two dimensions, while experiments and more sophisticated approximations show that 1/3in three dimensions. The mean field approximation, however, predicts a larger value.

(c) The magnetic susceptibility is defined as (M/B)T. The behaviour of this quantity near the critical point is conventionally written as T-Tc- , where y is another critical exponent. Find the value of in the mean field approximation, and show that it does not depend on whether T is slightly above or slightly below Te. (The exact value of y in two dimensions turns out to be 7/4, while in three dimensions 1.24.)

Short Answer

Expert verified

Hence proved that when x1,tanhxx-13x3

b)=0.5c)=1

Step by step solution

01

Given information

In this problem we will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

02

Explanation

a) The function tanh x has the following definition:

tanhx=e2x-1e2x+1ex1+x+x22+x36+tanhx1+2x+(2x)22+(2x)36-11+2x+12x+(2x)22+(2x)362+2xx+2x22+4x361+x;(1+x)-11-xx+x2+2x33(1-x)=x-x2+x2-x3+2x33=x-x33

(b)This expression will now be used to expand relation 8.50:

role="math" s=tanh(ns)Tc=nk,=1kT,n=TcTTcTs-sTc/T33s=TcTs1-Tc/T23s2TTc=1-Tc/T23s2Tc23T2s2=1-TTcTc23T2s2=1-TTc/3T2Tc2s2=3T2Tc21-TTcs=3T2Tc21-TTc,TTc-=3T2Tc2Tc-TTc,t=T-TcTc=-3t(1+t)2,|t|<<1,(1+t)21+2r-3t(1+2t)-3t=-3T-TcTcs~Tc-T=0.5

We may conclude that the same critical exponent applies to magnetisation because it is proportional to s.

03

Explanation

(c) To calculate susceptibility, we must differentiate the non-approximate formula for sin relation to B, which we shall manually insert:

s=tanh((ns+B))/ddB=(1+ncosh2[(ns+B)]

We can get by setting B = 0 and rearranging terms:

=(1+n)cosh2[ns]=cosh2[ns]-nn=TcTs(3|t|)0.5forTTc-cosh(x)1+x22cosh2TcTs1+Tc/T23|t|221+3Tc2T2|t|1+3Tc2T2|t|-TcT1+3Tc2T2|t|-TcT=3Tc2T2|t|+1-TcT=3Tc2T2|t|-|t|=|t|3Tc2T2-1=|t|3Tc2-T2T2|t|3Tc2-T2T21kBTT2|t|3Tc2-T21kBT|t|3Tc2-T2TTc1kBTc|t|2Tc212kB1|t|TcT-Tc-1=1

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Most popular questions from this chapter

At T = 0, equation 8.50 says that s=1. Work out the first temperature-dependent correction to this value, in the limit n1. Compare to the low-temperature behaviour of a real ferromagnet, treated in Problem 7.64.

Starting from the partition function, calculate the average energy of the one-dimensional Ising model, to verify equation 8.44. Sketch the average energy as a function of temperature.

Modify the ising program to simulate a one-dimensional Ising model.

(a) For a lattice size of 100, observe the sequence of states generated at various temperatures and discuss the results. According to the exact solution (for an infinite lattice), we expect this system to magnetise only as the temperature goes to zero; is the behaviour of your program consistent with this prediction? How does the typical cluster size depend on temperature?

(b) Modify your program to compute the average energy as in Problem 8.27. Plot the energy and heat capacity vs. temperature and compare to the exact result for an infinite lattice.

(c) Modify your program to compute the magnetisation as in Problem 8.28. Determine the most likely magnetisation for various temperatures and sketch a graph of this quantity. Discuss.

Consider a gas of "hard spheres," which do not interact at all unless their separation distance is less than r0, in which case their interaction energy is infinite. Sketch the Mayer f-function for this gas, and compute the second virial coefficient. Discuss the result briefly.

The Ising model can be used to simulate other systems besides ferromagnets; examples include anti ferromagnets, binary alloys, and even fluids. The Ising model of a fluid is called a lattice gas. We imagine that space is divided into a lattice of sites, each of which can be either occupied by a gas molecule or unoccupied. The system has no kinetic energy, and the only potential energy comes from interactions of molecules on adjacent sites. Specifically, there is a contribution of -u0to the energy for each pair of neighbouring sites that are both occupied.

(a) Write down a formula for the grand partition function for this system, as a function of u0, T, and p.

(b) Rearrange your formula to show that it is identical, up to a multiplicative factor that does not depend on the state of the system, to the ordinary partition function for an Ising ferromagnet in the presence of an external magnetic field B, provided that you make the replacements u04and 2BB-8. (Note that is the chemical potential of the gas while uB is the magnetic moment of a dipole in the magnet.)

(c) Discuss the implications. Which states of the magnet correspond to low density states of the lattice gas? Which states of the magnet correspond to high-density states in which the gas has condensed into a liquid? What shape does this model predict for the liquid-gas phase boundary in the P-T plane?

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