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In this problem you will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

(a) Prove that, when x1,tanhxx-13x3

(b) Use the result of part (a) to find an expression for the magnetisation of the Ising model, in the mean field approximation, when T is very close to the critical temperature. You should find MTc-T,where(not to be confused with 1/kT) is a critical exponent, analogous to the f defined for a fluid in Problem 5.55. Onsager's exact solution shows that =1/8in two dimensions, while experiments and more sophisticated approximations show that 1/3in three dimensions. The mean field approximation, however, predicts a larger value.

(c) The magnetic susceptibility is defined as (M/B)T. The behaviour of this quantity near the critical point is conventionally written as T-Tc- , where y is another critical exponent. Find the value of in the mean field approximation, and show that it does not depend on whether T is slightly above or slightly below Te. (The exact value of y in two dimensions turns out to be 7/4, while in three dimensions 1.24.)

Short Answer

Expert verified

Hence proved that when x1,tanhxx-13x3

b)=0.5c)=1

Step by step solution

01

Given information

In this problem we will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

02

Explanation

a) The function tanh x has the following definition:

tanhx=e2x-1e2x+1ex1+x+x22+x36+tanhx1+2x+(2x)22+(2x)36-11+2x+12x+(2x)22+(2x)362+2xx+2x22+4x361+x;(1+x)-11-xx+x2+2x33(1-x)=x-x2+x2-x3+2x33=x-x33

(b)This expression will now be used to expand relation 8.50:

role="math" s=tanh(ns)Tc=nk,=1kT,n=TcTTcTs-sTc/T33s=TcTs1-Tc/T23s2TTc=1-Tc/T23s2Tc23T2s2=1-TTcTc23T2s2=1-TTc/3T2Tc2s2=3T2Tc21-TTcs=3T2Tc21-TTc,TTc-=3T2Tc2Tc-TTc,t=T-TcTc=-3t(1+t)2,|t|<<1,(1+t)21+2r-3t(1+2t)-3t=-3T-TcTcs~Tc-T=0.5

We may conclude that the same critical exponent applies to magnetisation because it is proportional to s.

03

Explanation

(c) To calculate susceptibility, we must differentiate the non-approximate formula for sin relation to B, which we shall manually insert:

s=tanh((ns+B))/ddB=(1+ncosh2[(ns+B)]

We can get by setting B = 0 and rearranging terms:

=(1+n)cosh2[ns]=cosh2[ns]-nn=TcTs(3|t|)0.5forTTc-cosh(x)1+x22cosh2TcTs1+Tc/T23|t|221+3Tc2T2|t|1+3Tc2T2|t|-TcT1+3Tc2T2|t|-TcT=3Tc2T2|t|+1-TcT=3Tc2T2|t|-|t|=|t|3Tc2T2-1=|t|3Tc2-T2T2|t|3Tc2-T2T21kBTT2|t|3Tc2-T21kBT|t|3Tc2-T2TTc1kBTc|t|2Tc212kB1|t|TcT-Tc-1=1

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Most popular questions from this chapter

For a two-dimensional Ising model on a square lattice, each dipole (except on the edges) has four "neighbors"-above, below, left, and right. (Diagonal neighbors are normally not included.) What is the total energy (in terms of ) for the particular state of the 44square lattice shown in Figure 8.4?

Figure 8.4. One particular state of an Ising model on a 44square lattice (Problem 8.15).

Consider an Ising model of just two elementary dipoles, whose mutual interaction energy is . Enumerate the states of this system and write down their Boltzmann factors. Calculate the partition function. Find the probabilities of finding the dipoles parallel and antiparallel, and plot these probabilities as a function of kT/. Also calculate and plot the average energy of the system. At what temperatures are you more likely to find both dipoles pointing up than to find one up and one down?

Use a computer to plot s as a function of kT/, as predicted by mean field theory, for a two-dimensional Ising model (with a square lattice).

In this section I've formulated the cluster expansion for a gas with a fixed number of particles, using the "canonical" formalism of Chapter 6. A somewhat cleaner approach, however, is to use the "grand canonical" formalism introduced in Section 7.1, in which we allow the system to exchange particles with a much larger reservoir.

(a) Write down a formula for the grand partition function (Z) of a weakly interacting gas in thermal and diffusive equilibrium with a reservoir at fixed T and碌. Express Z as a sum over all possible particle numbers N, with each term involving the ordinary partition function Z(N).

(b) Use equations 8.6 and 8.20 to express Z(N) as a sum of diagrams, then carry out the sum over N, diagram by diagram. Express the result as a sum of similar diagrams, but with a new rule 1 that associates the expression (>./vQ) J d3ri with each dot, where >. = e13碌,. Now, with the awkward factors of N(N - 1) 路 路 路 taken care of, you should find that the sum of all diagrams organizes itself into exponential form, resulting in the formula

Note that the exponent contains all connected diagrams, including those that can be disconnected by removal of a single line.

(c) Using the properties of the grand partition function (see Problem 7.7), find diagrammatic expressions for the average number of particles and the pressure of this gas.

(d) Keeping only the first diagram in each sum, express N(碌) and P(碌) in terms of an integral of the Mayer /-function. Eliminate 碌 to obtain the same result for the pressure (and the second virial coefficient) as derived in the text.

(e) Repeat part (d) keeping the three-dot diagrams as well, to obtain an expression for the third virial coefficient in terms of an integral of /-functions. You should find that the A-shaped diagram cancels, leaving only the triangle diagram to contribute to C(T).

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