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Consider a free Fermi gas in two dimensions, confined to a square area A=L2•

(a) Find the Fermi energy (in terms of Nand A), and show that the average energy of the particles is ∈F2.

(b) Derive a formula for the density of states. You should find that it is a constant, independent of ∈.

(c) Explain how the chemical potential of this system should behave as a function of temperature, both when role="math" localid="1650186338941" kT≪∈Fand when Tis much higher.

(d) Because g∈is a constant for this system, it is possible to carry out the integral 7.53 for the number of particles analytically. Do so, and solve for μas a function of N. Show that the resulting formula has the expected qualitative behavior.

(e) Show that in the high-temperature limit, kT≫∈F, the chemical potential of this system is the same as that of an ordinary ideal gas.

Short Answer

Expert verified

(a) Fermi energy is, 12N∈Fand the average energy relation is given below.

(b) Density of states is, g∈=N∈F

(c) As the density state is constant, so the behavior of chemical properties is the same as the Fermi-Dirac distribution i.e. it will decrease continuously.

(d) Value of μis, μ=kTlne∈FkT-1

(e) Since, μ=-kTlnAN×2lQ2. Therefore, we can say that the chemical potential of this system is the same as that of an ordinary ideal gas.

Step by step solution

01

Part(a) Step 1: Given information

We have been given that,

A=L2

02

Part (a) Step 2: Simplify

In two dimensional case,

N=2∫0nmax∫0π/2ndndθ=π2nmax2

We know that,

∈F=h2nmax28mL2=h28mA×2Nπ∈F=h24Ï€³¾´¡N

Now, we can find the total energy U,

U=2∫0nmax∫0Ï€2ndndθ=Ï€2nmax2U=∫0∈F∈π8mAh2∈8mAh212∈d∈U=∫0∈F∈4Ï€³¾´¡h2d∈U=∫0∈F∈N∈Fd∈U=12N∈F

So, we can easily get average energy of the particles is UN=∈F2

03

Part (b) Step 1: Given information

We need to find out the density of states.

04

Part (b) Step 2: Simplify

From part (a),

Density of states is,

g∈=N∈F

That is independent of∈

05

Part (c) Step 1: Given information

We need to find out behavior of chemical properties

06

Part (c) Step 2: Simplify

Since the density of state is constant, the behavior of the chemical potential is the same as that of the Fermi-Dirac distribution. As we know that Fermi-Dirac distribution has some symmetrical property but when the energy difference from μis higher than the chemical potential, it gets broken because the occupancy is zero when ∈<0. So, the electrons with energy less than the Fermi energy are excited to a higher level than the Fermi energy with broken symmetry, which means that the number of electron loss with energy ∈<∈Fis lower than the number of electron gain with energy ∈>∈F.

To be sensible with the difference in no. of electrons, chemical potential should move i.e. Fermi-Dirac distribution has to move totally. As the number of electrons with energy ∈>∈Fis larger than ∈<∈F, so Fermi-Dirac distribution has to move on the left side with fixed ∈F, which means that the chemical potential decreases. When the temperature slightly grows up, then the difference in the number of electrons also grows up. So, the chemical potential will decrease continuously and at some point, it will have a negative value.

07

Part (d) Step 1: Given information

We need to find out value ofμ

08

Part (d) Step 2: Simplify

Since g(∈)is a constant, we can analytically integrate the equation,

N=∫0∞g∈1e∈-μkT+1d∈=N∈F∫0∞e-∈-μkT1+e-∈-μkTd∈=N∈F-kTln1+e-∈-μkT∈=0∈=∞=N∈FkTln1+eμkT

From this,

μ=kTln∈FkT-1=∈FwherekT≪∈FkTln∈FkTwherekT≫∈F

The second case is approximately and it will be negative value.

09

Part(e) Step 1: Given information

We need to find out that the chemical properties of this system is the same as that of an ordinary ideal gas

10

Part (e) Step 2: Simplify 

From the answer of part (d),

μ=kTln∈FkT=kTlnAN×4Ï€³¾°ì°Õh2=-kTlnAN×2lQ2

It seems to be the same form with the equation of chemical potential of an ordinary ideal gas.

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Most popular questions from this chapter

Problem 7.69. If you have a computer system that can do numerical integrals, it's not particularly difficult to evaluate μforT>Tc.

(a) As usual when solving a problem on a computer, it's best to start by putting everything in terms of dimensionless variables. So define t=T/Tc,c=μ/kTc,andx=ϵ/kTc. Express the integral that defines , equation 7.22, in terms of these variables. You should obtain the equation

2.315=∫0∞xdxe(x-c)/t-1

(b) According to Figure

the correct value of cwhen T=2Tcis approximately -0.8. Plug in these values and check that the equation above is approximately satisfied.

(c) Now vary μ, holding Tfixed, to find the precise value of μfor T=2Tc. Repeat for values of T/Tcranging from 1.2up to 3.0, in increments of 0.2. Plot a graph of μas a function of temperature.

Consider an isolated system of Nidentical fermions, inside a container where the allowed energy levels are nondegenerate and evenly spaced.* For instance, the fermions could be trapped in a one-dimensional harmonic oscillator potential. For simplicity, neglect the fact that fermions can have multiple spin orientations (or assume that they are all forced to have the same spin orientation). Then each energy level is either occupied or unoccupied, and any allowed system state can be represented by a column of dots, with a filled dot representing an occupied level and a hollow dot representing an unoccupied level. The lowest-energy system state has all levels below a certain point occupied, and all levels above that point unoccupied. Let ηbe the spacing between energy levels, and let be the number of energy units (each of size 11) in excess of the ground-state energy. Assume thatq<N. Figure 7 .8 shows all system states up to q=3.

(a) Draw dot diagrams, as in the figure, for all allowed system states with q=4,q=5,andq=6. (b) According to the fundamental assumption, all allowed system states with a given value of q are equally probable. Compute the probability of each energy level being occupied, for q=6. Draw a graph of this probability as a function of the energy of the level. ( c) In the thermodynamic limit where qis large, the probability of a level being occupied should be given by the Fermi-Dirac distribution. Even though 6 is not a large number, estimate the values of μand T that you would have to plug into the Fermi-Dirac distribution to best fit the graph you drew in part (b).

A representation of the system states of a fermionic sytern with evenly spaced, nondegen erate energy levels. A filled dot rep- resents an occupied single-particle state, while a hollow dot represents an unoccupied single-particle state . {d) Calculate the entropy of this system for each value of q from 0to6, and draw a graph of entropy vs. energy. Make a rough estimate of the slope of this graph near q=6, to obtain another estimate of the temperature of this system at that point. Check that it is in rough agreement with your answer to part ( c).

Repeat the previous problem, taking into account the two independent spin states of the electron. Now the system has two "occupied" states, one with the electron in each spin configuration. However, the chemical potential of the electron gas is also slightly different. Show that the ratio of probabilities is the same as before: The spin degeneracy cancels out of the Saha equation.

Suppose that the concentration of infrared-absorbing gases in earth's atmosphere were to double, effectively creating a second "blanket" to warm the surface. Estimate the equilibrium surface temperature of the earth that would result from this catastrophe. (Hint: First show that the lower atmospheric blanket is warmer than the upper one by a factor of 21/4. The surface is warmer than the lower blanket by a smaller factor.)

Consider a degenerate electron gas in which essentially all of the electrons are highly relativistic ϵ≫mc2so that their energies are ϵ=pc(where p is the magnitude of the momentum vector).

(a) Modify the derivation given above to show that for a relativistic electron gas at zero temperature, the chemical potential (or Fermi energy) is given by =

μ=hc(3N/8πV)1/3

(b) Find a formula for the total energy of this system in terms of N and μ.

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