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The argument given above for why CvTdoes not depend on the details of the energy levels available to the fermions, so it should also apply to the model considered in Problem 7.16: a gas of fermions trapped in such a way that the energy levels are evenly spaced and non-degenerate.

(a) Show that, in this model, the number of possible system states for a given value of q is equal to the number of distinct ways of writing q as a sum of positive integers. (For example, there are three system states for q = 3, corresponding to the sums 3, 2 + 1, and 1 + 1 + 1. Note that 2 + 1 and 1 + 2 are not counted separately.) This combinatorial function is called the number of unrestricted partitions of q, denoted p(q). For example, p(3) = 3.

(b) By enumerating the partitions explicitly, compute p(7) and p(8).

(c) Make a table of p(q) for values of q up to 100, by either looking up the values in a mathematical reference book, or using a software package that can compute them, or writing your own program to compute them. From this table, compute the entropy, temperature, and heat capacity of this system, using the same methods as in Section 3.3. Plot the heat capacity as a function of temperature, and note that it is approximately linear.

(d) Ramanujan and Hardy (two famous mathematicians) have shown that when q is large, the number of unrestricted partitions of q is given approximately by

p(q)e2q343q

Check the accuracy of this formula for q = 10 and for q = 100. Working in this approximation, calculate the entropy, temperature, and heat capacity of this system. Express the heat. capacity as a series in decreasing powers of kT/, assuming that this ratio is large and keeping the two largest terms. Compare to the numerical results you obtained in part (c). Why is the heat capacity of this system independent of N, unlike that of the three dimensional box of fermions discussed in the text?

Short Answer

Expert verified

a, explanation has been given.

b. For q=7,

7,6+1,5+2,5+1+1,4+3,4+2+1,4+1+1+1,3+1+1+1+1,2+1+1+1+1+1,1+1+1+1+1+1+1

For q=8,

8,7+1,6+2,6+1+1,5+3,5+2+1,5+1+1+1,4+4,4+3+1,4+2+1+1,4+1+1+1+1,3+2+1+1+1,3+1+1+1+1+1,2+1+1+1+1+1+1,1+1+1+1+1+1+1+1

c. The plot found is using python plot is approximately linear.

d. p(10)=48p(100)=199280893

S=Klne2q343q

1T=K6q-1q

Cvk2t3-2

Step by step solution

01

Part (a) Step 1: Given information

We have given,

CvT

We have to explain the function p in term of q show it is verity.

02

Simplify

Here the value of q explains the no. of energy levels.

For example as given for q=3, then we can write,

1+1+1

2+1

3

It is explain the how we can distribution the number of q.

03

Part (b) Step 1: Given information

We have to findp(7),p(8)using above rule.

04

Simplify

For q=7, we can write

7,6+1,5+2,5+1+1,4+3,4+2+1,4+1+1+1,3+1+1+1+1,2+1+1+1+1+1,1+1+1+1+1+1+1

For q=8, we can write,

8,7+1,6+2,6+1+1,5+3,5+2+1,5+1+1+1,4+4,4+3+1,4+2+1+1,4+1+1+1+1,3+2+1+1+1,3+1+1+1+1+1,2+1+1+1+1+1+1,1+1+1+1+1+1+1+1

05

part (c) Step 1: Given information,

We have to plot the graph of heat capacity as function of temperature.

06

Simplify

The table for p(q) for the values of q up to 100 is given by using the python code as given below.

For this we can use the python code and we will get the plot as shown in figure.

The out put is following

(1,1,2,3,5,7,11,15,22,30,42,56,77,101,135,176,231,297,385,490,627792,1002,1255,1575,1958,2436,3010,3718,4565,5604,6842,8349,10143,12310,14883,17977,21977,21637,26015,31185,37338,44583,5269823,614154,715220,831820.............15019136,169229875,190569292)

then entropy will found as

S=Kin

then, capacity will be,

CV=UT

Then the code of python to p[lot the curve between the entropy and the temperature is given by,

Then the code of python to p[lot the curve between the entropy and the temperature is given by,

07

Part (d) Step 1: Given information

We have given,

p(q)e2q343q

we have to calculate the heat capacity ,temperature and entropy of the system.

08

Simplify

For q=10, we can write,

p(q)e2q343qp(10)=e2034310p(10)=48

For q=100, we can write,

p(q)e2q343qp(100)=e200343100p(10)=199280893

09

Simplify 

The entropy of the system is given by,

S=K濒苍惟S=Kln(p(q))S=Klne2q343q

Then, the temperature is ,

1T=1Sq1T=Kqlne2q343q1T=K6q-1q

The heat capacity is given by,

Cv=kqtCvk2t3-2

Here, t is given by,

t=kT

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Most popular questions from this chapter

When the attractive forces of the ions in a crystal are taken into account, the allowed electron energies are no longer given by the simple formula 7.36; instead, the allowed energies are grouped into bands, separated by gaps where there are no allowed energies. In a conductor the Fermi energy lies within one of the bands; in this section we have treated the electrons in this band as "free" particles confined to a fixed volume. In an insulator, on the other hand, the Fermi energy lies within a gap, so that at T = 0 the band below the gap is completely occupied while the band above the gap is unoccupied. Because there are no empty states close in energy to those that are occupied, the electrons are "stuck in place" and the material does not conduct electricity. A semiconductor is an insulator in which the gap is narrow enough for a few electrons to jump across it at room temperature. Figure 7 .17 shows the density of states in the vicinity of the Fermi energy for an idealized semiconductor, and defines some terminology and notation to be used in this problem.

(a) As a first approximation, let us model the density of states near the bottom of the conduction band using the same function as for a free Fermi gas, with an appropriate zero-point: g()=g0-c, where go is the same constant as in equation 7.51. Let us also model the density of states near the top

Figure 7.17. The periodic potential of a crystal lattice results in a densityof-states function consisting of "bands" (with many states) and "gaps" (with no states). For an insulator or a semiconductor, the Fermi energy lies in the middle of a gap so that at T = 0, the "valence band" is completely full while the-"conduction band" is completely empty. of the valence band as a mirror image of this function. Explain why, in this approximation, the chemical potential must always lie precisely in the middle of the gap, regardless of temperature.

(b) Normally the width of the gap is much greater than kT. Working in this limit, derive an expression for the number of conduction electrons per unit volume, in terms of the temperature and the width of the gap.

(c) For silicon near room temperature, the gap between the valence and conduction bands is approximately 1.11 eV. Roughly how many conduction electrons are there in a cubic centimeter of silicon at room temperature? How does this compare to the number of conduction electrons in a similar amount of copper?

( d) Explain why a semiconductor conducts electricity much better at higher temperatures. Back up your explanation with some numbers. (Ordinary conductors like copper, on the other hand, conduct better at low temperatures.) (e) Very roughly, how wide would the gap between the valence and conduction bands have to be in order to consider a material an insulator rather than a semiconductor?

Consider any two internal states, s1 and s2, of an atom. Let s2 be the higher-energy state, so that Es2-Es1= for some positive constant. If the atom is currently in state s2, then there is a certain probability per unit time for it to spontaneously decay down to state s1, emitting a photon with energy e. This probability per unit time is called the Einstein A coefficient:

A = probability of spontaneous decay per unit time.

On the other hand, if the atom is currently in state s1 and we shine light on it with frequency f=/h, then there is a chance that it will absorb photon, jumping into state s2. The probability for this to occur is proportional not only to the amount of time elapsed but also to the intensity of the light, or more precisely, the energy density of the light per unit frequency, u(f). (This is the function which, when integrated over any frequency interval, gives the energy per unit volume within that frequency interval. For our atomic transition, all that matters is the value of u(f)atf=/h) The probability of absorbing a photon, per unit time per unit intensity, is called the Einstein B coefficient:

B=probability of absorption per unit timeu(f)

Finally, it is also possible for the atom to make a stimulated transition from s2down to s1, again with a probability that is proportional to the intensity of light at frequency f. (Stimulated emission is the fundamental mechanism of the laser: Light Amplification by Stimulated Emission of Radiation.) Thus we define a third coefficient, B, that is analogous to B:

B'=probability of stimulated emission per unit timeu(f)

As Einstein showed in 1917, knowing any one of these three coefficients is as good as knowing them all.

(a) Imagine a collection of many of these atoms, such that N1 of them are in state s1 and N2 are in state s2. Write down a formula for dN1/dt in terms of A, B, B', N1, N2, and u(f).

(b) Einstein's trick is to imagine that these atoms are bathed in thermal radiation, so that u(f) is the Planck spectral function. At equilibrium, N1and N2 should be constant in time, with their ratio given by a simple Boltzmann factor. Show, then, that the coefficients must be related by

B'=BandAB=8hf3c3

Compute the quantum volume for an N2molecule at room temperature, and argue that a gas of such molecules at atmospheric pressure can be

treated using Boltzmann statistics. At about what temperature would quantum statistics become relevant for this system (keeping the density constant and pretending that the gas does not liquefy)?

Each atom in a chunk of copper contributes one conduction electron. Look up the density and atomic mass of copper, and calculate the Fermi energy, the Fermi temperature, the degeneracy pressure, and the contribution of the degeneracy pressure to the bulk modulus. Is room temperature sufficiently low to treat this system as a degenerate electron gas?

At the surface of the sun, the temperature is approximately 5800 K.

(a) How much energy is contained in the electromagnetic radiation filling a cubic meter of space at the sun's surface?

(b) Sketch the spectrum of this radiation as a function of photon energy. Mark the region of the spectrum that corresponds to visible wavelengths, between 400 nm and 700 nm.

(c) What fraction of the energy is in the visible portion of the spectrum? (Hint: Do the integral numerically.)

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