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Home owners and builders discuss thermal conductivities in terms of the value (Rfor resistance) of a material, defined as the thickness divided by the thermal conductivity:

R≡Δxkt

(a) Calculate the Rvalue of a 1/8-inch(3.2mm) piece of plate glass, and then of a 1mmlayer of still air. Express both answers in SI units.

(b) In the United States, Rvalues of building materials are normally given in English units,∘F⋅ft2⋅hr/Btu. A Btu, or British thermal unit, is the energy needed to raise the temperature of a pound of water 1∘F. Work out the conversion factor between the SI and English units for values. Convert your answers from part (a) to English units.

(c) Prove that for a compound layer of two different materials sandwiched together (such as air and glass, or brick and wood), the effective total Rvalue is the sum of the individual Rvalues.

(d) Calculate the effective Rvalue of a single piece of plate glass with a 1.0mmlayer of still air on each side. (The effective thickness of the air layer will depend on how much wind is blowing; 1mmis of the right order of magnitude under most conditions.) Using this effective Rvalue, make a revised estimate of the heat loss through a 1−m2single-pane window when the temperature in the room is 20∘Chigher than the outdoor temperature.

Short Answer

Expert verified

From the following

a. The value of Rboth glass and air has been found.

Rair=0.0385J−1⋅s⋅m2⋅K

Rglass=0.004J−1⋅s⋅m2⋅K

b. By conversion of units

1∘F⋅ft2⋅hr⋅Btu−1=0.176∘K⋅m2⋅s⋅J

Rair=0.2187∘F⋅ft2⋅hr⋅Btu−1

Rglass=0.0227∘F⋅ft2⋅hr⋅Btu−1

c. The effective value of R

Rc=R1+R2

d. Therefore using the effectiveRvalue we get,

Rc=0.081J−1⋅s⋅m2⋅K

QΔt=246.91watts

Step by step solution

01

Thermal conductivity (part a)

In the construction industry, thermal conductivity is frequently expressed in terms of the Rvalue, which is defined as:

R=Δxkt

Since Rdepends on the inverse of the thermal conductivity and directly on the thickness of the insulating material, a larger Rmeans a better insulator.

For the 1mmlayer of still air with kt=0.026J⋅s−1⋅m−1⋅K−1, we have:

Rair=Δxkt=0.0010.026=0.0385J−1⋅s⋅m2⋅K

Given that kt=0.8J⋅s−1⋅m−1⋅K−1for glass, the Rvalue of a 3.2mmthick sheet of glass is:

Rglass=Δxkt=0.00320.8=0.004J−1⋅s⋅m2⋅K

Thus if there is a 1mmlayer of still air next to a window, it actually provides more insulation than the window glass itself.

02

Conversion of Units (part b)

In the US, the units of Rare F⋅ft2⋅hr⋅Btu−1where a British thermal unit Btuis the amount of energy necessary to elevate one pound of water by 1∘F. To convert to SI units of R, we need to convert 1Btuto Joules. One Fahrenheit degree is59of a Kelvin, there are 453.592grams per pound, and 4.186joules are required to raise 1a gram of water by 1∘K. Therefore:

1Btu=59∘K×(4.186)J×(453.592)g=1054.85J

One foot is 0.3048mand 1hour is 3600seconds, so

1∘F×ft2×hr×Btu−1=59∘K⋅(0.3048)2m2×(3600)s×(1054.85)−1J−1

1∘F⋅ft2⋅hr⋅Btu−1=0.176∘K⋅m2⋅s⋅J

The previous Rvalues in English units are therefore:

Rair=10.176×0.0385=0.2187∘F⋅ft2⋅hr⋅Btu−1

Rglass=10.176×0.004=0.0227∘F⋅ft2⋅hr⋅Btu−1

03

Pictorial Representation

The Rvalues of a compound layer of two different materials are the sum of the individual Rvalues. This can be seen as follows. Assume we have a composite layer made up of two components.: material 1and material 2. The temperature on the exposed side of the material 2is T2and on the material 1side is T1. At the place where the two materials meet, the temperature isTa.


04

At a steady flow rate of flow of heat 

The rate of heat flow across the two layers must be the same in the steady-state (otherwise, heat would build up elsewhere), and employing QΔt=−kt1AΔTΔx1, so from the material 1we have:

Let be Equation (1)

QΔt=−kt1AΔTΔx1=−kt1ATa−T1Δx1

and for material 2, we have equation (2):

QΔt=−kt2AΔTΔx2=−kt2AT2−TaΔx2

by equating equation (1) and equation (2), we have equation (3):

kt2T2−TaΔx2=kt1Ta−T1Δx1

where A(area) is dropping out since in both layers the area is the same. we have equation (4):

R1=Δx1kt1R2=Δx2kt2

substitute from (4) into (3), we get equation (5),

T2−TaR2=Ta−T1R1

The overall rate of heat transfer across the compound layer must now be the same as well.. If we define Rcit to be the effective Rvalue of the compound layer, then:

T2−TaR2=Ta−T1R1=T2−T1Rc

so we have two equations, let's be equation (6).

T2−TaR2=Ta−T1R1Ta−T1R1=T2−T1Rc

05

Solving Ta to find Rc

now we need to solve these two equations for Rc. From the first equation, we can solve for Ta:

T2−TaR2=Ta−T1R1→R1T2−R1Ta=R2Ta−R2T1

R1T2+R2T1=R2Ta+R1Ta→R1T2+R2T1=TaR2+R1

Ta=R1T2+R2T1R2+R1

Substituting into the second equation in (6) we can solve for Rc:

Ta−T1R1=T2−T1Rc→1R1Ta−T1R1=T2−T1Rc

1R1R1T2+R2T1R2+R1−T1R1=T2−T1Rc

R1T2+R2T1R1R2+R1−R2+R1T1R2+R1R1=T2−T1Rc

R1T2+R2T1−R2T1−R1T1R1R2+R1=T2−T1Rc

R1T2−T1R1R2+R1=T2−T1Rc

Rc=R1+R2

06

To find the effective R value

Using this compound Rvalue, we can estimate the rate of heat loss from a 1m2single-pane window of thickness 3.2mm, but with a 1mmlayer of still air on each side. The effective Rvalue of this system is:

localid="1650266582013" Rc=Rglass+2×Rair

using the results from step 1,

localid="1650266585531" Rair=0.0385J−1⋅s⋅m2⋅K

localid="1650266588974" Rglass=0.004J−1⋅s⋅m2⋅K

so, the effective localid="1650266593411" Rvalue of this system is, therefore:

localid="1650266597424" Rc=0.004+2×0.0385=0.081J−1⋅s⋅m2⋅K

When the temperature difference is localid="1650266601163" ΔT=20∘K, the rate of heat is:

QΔt=−ktAΔTΔx

with, localid="1650266605707" Rc=Δxktso:

localid="1650266613094" QΔt=−AΔTRc

substitute,

localid="1650266651710" QΔt=−1×200.081=246.91localid="1650266657465" watts

This compares with the heat loss through the glass on its own localid="1650266667372" AΔTRglass=5000localid="1650266673006" watts. Thus the air layer provides most of the insulation.

Therefore, it is concluded that,

localid="1650266679151" Rair=0.0385J−1⋅s⋅m2⋅K

localid="1650266683604" Rglass=0.004J−1⋅s⋅m2⋅K

localid="1650266688380" 1∘F⋅ft2⋅hr⋅Btu−1=0.176∘K⋅m2⋅s⋅J,

localid="1650266693304" Rair=0.2187∘F⋅ft2⋅hr⋅Btu−1

localid="1650266702329" Rglass=0.0227∘F⋅ft2⋅hr⋅Btu−1

localid="1650266707608" Rc=R1+R2

localid="1650266713776" Rc=0.081J−1⋅s⋅m2⋅K,QΔt=246.91watts

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Most popular questions from this chapter

An ideal diatomic gas, in a cylinder with a movable piston, undergoes the rectangular cyclic process shown in the given figure.

Assume that the temperature is always such that rotational degrees of freedom are active, but vibrational modes are "frozen out." Also assume that the only type of work done on the gas is quasistatic compression-expansion work.

(a) For each of the four steps A through D, compute the work done on the gas, the heat added to the gas, and the change in the energy content of the gas. Express all answers in terms of P1,P2,V1,andV2. (Hint: Compute ΔUbefore Q, using the ideal gas law and the equipartition theorem.)

(b) Describe in words what is physically being done during each of the four steps; for example, during step A, heat is added to the gas (from an external flame or something) while the piston is held fixed.

(c) Compute the net work done on the gas, the net heat added to the gas, and the net change in the energy of the gas during the entire cycle. Are the results as you expected? Explain briefly.

Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial

expansion,

PV−nRT(1+B(T)(V/n)+C(T)(V/n)2+⋯)

where the functions B(T), C(T), and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient B(T)is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen (N2):

T(K)
B(cm3/mol)
100–160
200–35
300–4.2
4009.0
50016.9
60021.3
  1. For each temperature in the table, compute the second term in the virial equation, B(T)/(V/n), for nitrogen at atmospheric pressure. Discuss the validity of the ideal gas law under these conditions.
  2. Think about the forces between molecules, and explain why we might expect B(T)to be negative at low temperatures but positive at high temperatures.
  3. Any proposed relation between P, V, andT, like the ideal gas law or the virial equation, is called an equation of state. Another famous equation of state, which is qualitatively accurate even for dense fluids, is the van der Waals equation,
    (P+an2V2)(V−nb)=nRT
    where a and b are constants that depend on the type of gas. Calculate the second and third virial coefficients (Band C) for a gas obeying the van der Waals equation, in terms of aand b. (Hint: The binomial expansion says that (1+x)p≈1+px+12p(p−1)x2, provided that |px|≪1. Apply this approximation to the quantity [1−(nb/V)]−1.)
  4. Plot a graph of the van der Waals prediction for B(T), choosing aand bso as to approximately match the data given above for nitrogen. Discuss the accuracy of the van der Waals equation over this range of conditions. (The van der Waals equation is discussed much further in Section 5.3.)

Calculate the rms speed of a nitrogen molecule at room temperature.

The Rankine temperature scale(abbreviated °R) uses the same scale size degrees as Fahrenheit, but measured up from absolute zero like Kelvin(so Rankine is to Fahrenheit as Kelvin is to Celsius). Find the conversion formula between Rankine and Fahrenheit and also between Rankine and Kelvin. What is the room temperature on the Rankine scale?

Suppose you open a bottle of perfume at one end of a room. Very roughly, how much time would pass before a person at the other end of the room could smell the perfume, if diffusion were the only transport mechanism? Do you think diffusion is the dominant transport mechanism in this situation?

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