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Suppose you have 10 atoms of weberium: 4 with energy 0 eV, 3 with energy 1 eV, 2 with energy 4 eV, and 1 with energy 6 eV.

(a) Compute the average energy of all your atoms, by adding up all their energies and dividing by 10.

(b) Compute the probability that one of your atoms chosen at random would have energy E, for each of the four values of E that occur.

(c) Compute the average energy again, using the formulaE¯=∑sE(s)P(s)

Short Answer

Expert verified

Therefore,

The average energy is E¯=1.7eV

The probability is P(0eV)=410P(1eV)=310P(4eV)=210P(6eV)=110

The average energy using formula isE¯=1.7eV

Step by step solution

01

Given information

10 atoms of weberium: 4 with energy 0 eV, 3 with energy 1 eV, 2 with energy 4 eV, and 1 with energy 6 eV.

02

Explanation

(a) Assume we have ten weberium atoms, four of which have an energy of E1 = 0 eV, three of which have an energy of E2 =1 eV, two of which have an energy of E3 4 eV, and one of which has an energy of E4 = 6 eV; the average energy is given by:

E¯=∑NEN∑N

Where ENis the energy level that occupied by N atoms

Substitute the values,

E¯=4(0eV)+3(1.0eV)+2(4eV)+1(6eV)10=1.7eVE¯=1.7eV

(b) Each energy's probability is equal to the number of atoms with that energy divided by the total number of atoms, so:

P(0eV)=410P(1eV)=310P(4eV)=210P(6eV)=110

03

Explanation

The average energy is:

E¯=∑E(s)P(s)

The average energy of the system is:

E¯=E1P(0eV)+E2P(1eV)+E3P(4eV)+E4P(6eV)

Substitute from part (b):

E¯=(0eV)(0.4)+(1eV)(0.3)+(4eV)(0.2)+(6eV)(0.1)E¯=1.7eV

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Most popular questions from this chapter

Consider a classical "degree of freedom" that is linear rather than quadratic E=cqfor some constant c. (As example would be the kinetic energy of a highly relativistic particle in one dimension, written in terms of its momentum.) Repeat derivation of the equipartition theorem for this system, and show that the average energy isrole="math" localid="1646903677918" E-=kT.

Carefully plot the Maxwell speed distribution for nitrogen molecules at T=300K and atT=600K. Plot both graphs on the same axes, and label the axes with numbers.

The most common measure of the fluctuations of a set of numbers away from the average is the standard deviation, defined as follows.

(a) For each atom in the five-atom toy model of Figure 6.5, compute the deviation of the energy from the average energy, that is, Ei-E¯,fori=1to5. Call these deviations ΔEi.

(b) Compute the average of the squares of the five deviations, that is, ΔEi2¯. Then compute the square root of this quantity, which is the root-mean- square (rms) deviation, or standard deviation. Call this number σE. Does σEgive a reasonable measure of how far the individual values tend to stray from the average?

(c) Prove in general that

σE2=E2¯-(E¯)2

that is, the standard deviation squared is the average of the squares minus the square of the average. This formula usually gives the easier way of computing a standard deviation.

(d) Check the preceding formula for the five-atom toy model of Figure 6.5.

Use the Maxwell distribution to calculate the average value of v2for the molecules of an ideal gas. Check that your answer agrees with equation 6.41.

This problem concerns a collection of N identical harmonic oscillators (perhaps an Einstein solid or the internal vibrations of gas molecules) at temperature T. As in Section 2.2, the allowed energies of each oscillator are 0, hf, 2hf, and so on. (

a) Prove by long division that

11-x=1+x+x2+x3+⋯

For what values of x does this series have a finite sum?

(b) Evaluate the partition function for a single harmonic oscillator. Use the result of part (a) to simplify your answer as much as possible.

(c) Use formula 6.25 to find an expression for the average energy of a single oscillator at temperature T. Simplify your answer as much as possible.

(d) What is the total energy of the system of N oscillators at temperature T? Your result should agree with what you found in Problem 3.25.

(e) If you haven't already done so in Problem 3.25, compute the heat capacity of this system and check t hat it has the expected limits as T→0 and T→∞.

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