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Use the Maxwell distribution to calculate the average value of v2for the molecules of an ideal gas. Check that your answer agrees with equation 6.41.

Short Answer

Expert verified

The required average value is 3kTmand it matches with the given equation.

Step by step solution

01

Step1. Given information

The Maxwell speed distribution function is give by

Dv=m2Ï€kT324Ï€v2e-mv22kT................................(1)

02

Step 2. Calculation

The formula to calculate the average of v2is given by

v2=∫0∞v2Dvdv....................(2)

Substitute the distribution function from equation (1) into equation (2) to calculate the required average value.

v2=∫0∞v2m2πkT324πv2e-mv22kTdv=4πm2πkT32∫0∞v4e-mv22kTdv................(3)

Substitute xfor m2kTvinto equation (3) and evaluate the required value.

role="math" localid="1647007293675" v2=4πm2πkT322kTm52∫0∞x4e-x2dx=4πm2πkT322kTm523π8=3kTm

The rms speed is defined as

vrms=v2...................(4)

Substitute 3kTmfor v2into equation (4) to obtain the rms speed.

vrms=3kTm

Thus, the above equation exactly matches with equation 6.41.

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Most popular questions from this chapter

Consider a hypothetical atom that has just two states: a ground state with energy zero and an excited state with energy 2 eV. Draw a graph of the partition function for this system as a function of temperature, and evaluate the partition function numerically at T = 300 K, 3000 K, 30,000 K, and 300,000 K.

Use a computer to sum the exact rotational partition function numerically, and plot the result as a function ofkT∈. Keep enough terms in the sum to be confident that the series has converged. Show that the approximation in equation 6.31 is a bit low, and estimate by how much. Explain the discrepancy

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For a diatomic gas near room temperature, the internal partition function is simply the rotational partition function computed in section 6.2, multiplied by the degeneracy Zeof the electronic ground state.

(a) Show that the entropy in this case is

S=NkInVZeZrotNvQ+72.

Calculate the entropy of a mole of oxygen at room temperature and atmospheric pressure, and compare to the measured value in the table at the back of this book.

(b) Calculate the chemical potential of oxygen in earth's atmosphere near sea level, at room temperature. Express the answer in electron-volts

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