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Poly(3-hydroxybutyrate) (PHB), a semicrystallinepolymer that is fully biodegradable and biocompatible,is obtained from renewable resources. From a sustainabilityperspective, PHB offers many attractive propertiesthough it is more expensive to produce than standardplastics. The accompanying data on melting point(掳C) for each of 12 specimens of the polymer using adifferential scanning calorimeter appeared in the article鈥淭he Melting Behaviour of Poly(3-Hydroxybutyrate)by DSC. Reproducibility Study鈥 (Polymer Testing,2013: 215鈥220).

180.5 181.7 180.9 181.6 182.6 181.6

181.3 182.1 182.1 180.3 181.7 180.5

Compute the following:

  1. The sample range
  2. The sample variance \({{\bf{s}}^{\bf{2}}}\)from the definition (Hint:First subtract 180 from each observation.
  3. The sample standard deviation
  4. \({{\bf{s}}^{\bf{2}}}\)using the shortcut method

Short Answer

Expert verified

a. The sample range is 2.3掳C.

b. The sample variance is 0.5245掳C square.

c. The sample standard deviation is 0.7242掳C.

d. The sample variance is 0.5245掳C square.

Step by step solution

01

Given information

The data on melting point (掳C) for each of 12 specimens of the polymer using a differential scanning calorimeter.

The size of the sample is 12.

02

Compute the sample range

a.

The range is the difference between the largest and the smallest sample value.

The sample range is computed as,

\(\begin{array}{c}Range = 182.6 - 180.3\\ = 2.3\end{array}\)

Therefore, the sample range for the provided data is 2.3掳C.

03

Compute the sample variance

b.

Let x represents the sample values for melting point.

The sample variance is given as,

\(\begin{array}{c}{s^2} &=& \frac{{\sum {{{\left( {{x_i} - \bar x} \right)}^2}} }}{{n - 1}}\\ &=& \frac{{{S_{xx}}}}{{n - 1}}\end{array}\)

The sample mean is computed as,

\(\begin{array}{c}\bar x &=& \frac{{\sum {{x_i}} }}{n}\\ &=& \frac{{180.5 + 181.7 + 180.9 + ... + 180.5}}{{12}}\\ &=& 181.40833\\ \approx 181.41\end{array}\)

Thus, the sample mean is 181.41掳C.

The calculations that are required to compute the sample variance is as follows,


\({x_i}\)

\(\left( {{x_i} - \bar x} \right)\)

\({\left( {{x_i} - \bar x} \right)^2}\)

1

180.5

-0.91

0.8281

2

181.7

0.29

0.0841

3

180.9

-0.51

0.2601

4

181.6

0.19

0.0361

5

182.6

1.19

1.4161

6

181.6

0.19

0.0361

7

181.3

-0.11

0.0121

8

182.1

0.69

0.4761

9

182.1

0.69

0.4761

10

180.3

-1.11

1.2321

11

181.7

0.29

0.0841

12

180.5

-0.91

0.8281

Total



5.7692

Substituting the values, the sample variance is given as,

\(\begin{array}{c}{s^2} &=& \frac{{\sum {{{\left( {{x_i} - \bar x} \right)}^2}} }}{{n - 1}}\\ &=& \frac{{5.7692}}{{12 - 1}}\\ &=& \frac{{5.7692}}{{11}}\\ &=& 0.5245\end{array}\)

Thus, the sample variance for the provided data is 0.5245掳C square.

04

Compute the sample standard deviation

c.

Referring to the sample variance computed in part b,

The sample variance is 0.5245.

The sample standard deviation is given as,

\(\begin{array}{c}s &=& \sqrt {{s^2}} \\ &=& \sqrt {0.5245} \\ &=& 0.7242\end{array}\)

Therefore, the sample standard deviation for the provided data is 0.72442掳C.

05

Compute the sample variance using the shortcut method

d.

Let x represents the sample values.

The sample variance is given as,

\(\begin{array}{c}{s^2} &=& \frac{{\sum {{{\left( {{x_i} - \bar x} \right)}^2}} }}{{n - 1}}\\ &=& \frac{{{S_{xx}}}}{{n - 1}}\\ &=& \frac{{\sum {x_i^2} - n{{\left( {\bar x} \right)}^2}}}{{n - 1}}\end{array}\)

The sample mean is computed as,

\(\begin{array}{c}\bar x &=& \frac{{\sum {{x_i}} }}{n}\\ &=& \frac{{180.5 + 181.7 + 180.9 + ... + 180.5}}{{12}}\\ &=& 181.40833\\ \approx 181.41\end{array}\)

Thus, the sample mean is 181.41.

The calculations that are required to compute the sample variance is as follows,


\({x_i}\)

\(x_i^2\)

1

180.5

32580.25

2

181.7

33014.89

3

180.9

32724.81

4

181.6

32978.56

5

182.6

33342.76

6

181.6

32978.56

7

181.3

32869.69

8

182.1

33160.41

9

182.1

33160.41

10

180.3

32508.09

11

181.7

33014.89

12

180.5

32580.25

Total

2176.9

394913.6

Substituting the values, the sample variance is given as,

\(\begin{array}{c}{s^2} &=& \frac{{\sum {x_i^2} - \frac{{{{\left( {\sum {{x_i}} } \right)}^2}}}{n}}}{{n - 1}}\\ &=& \frac{{394913.6 - \frac{{{{\left( {2176.9} \right)}^2}}}{{12}}}}{{12 - 1}}\\ &=& 0.5245\end{array}\)

Thus, the sample variance for the provided data is 0.5245掳C square.

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