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Balancing a chemical reaction. Consider the chemical reaction

aNO2+bH2OcHNO2+dHNO3,

where a, b, c, and d are unknown positive integers. The reaction must be balanced; that is, the number of atoms of each element must be the same before and after the reaction. For example, because the number of oxygen atoms must remain the same,

2a+b=2c+3d.

While there are many possible values for a,b,c and d that balance the reaction, it is customary to use the smallest possible positive integers. Balance this reaction.

Short Answer

Expert verified

The smallest possible positive integers are.a=2,b=c=d=1,

Step by step solution

01

Write the elements in terms of positive integers.

The elements in terms of integers are:

Oxygen:

2a+b=2ca+3d2a+b-2c-3d=0......1

Nitrogen:

a=c+da-c-d=0......2

Hydrogen:

2b=c+d2b-c-d=0......3

02

Consider the equations.

Re-write the equations in terms of a matrix.

2a+b-2c-3d=0a-c-d=02b-c-d=0

Represent the above system of equations in terms of the matrix form,

21-2-3010-1-1002-1-10

03

Solve the matrix.

Consider the matrix.

21-2-3010-1-1002-1-10

Using row Echelon form to reduce the matrix.

21-2-3002-1-1000-14140=100-20010-10001-10

Consider the equations,

a-2d=0........1b-c=0........2c-d=0.........3

Computing the equations (1), (2) and (3), we get the values as,a=2,b=c=d=1 .

04

Final answer

a=2,b=c=d=1are the smallest possible values.

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Most popular questions from this chapter

In Exercises19through 24 , find the matrix Bof the linear transformation T(x鈬赌)=Ax鈬赌 with respect to the basis I=(v1鈬赌,v2鈬赌). For practice, solve each problem in three ways: (a) Use the formula B=S-1AS , (b) use a commutative diagram (as in Examples 3 and 4), and (c) construct 鈥渃olumn by column.鈥

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