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Describe the chemistry that occurs in each of the following regions in Figure 7-2:

  1. before the equivalence point;
  2. (ii) at the equivalence point; and
  3. (iii) past the equivalence point.

Write the equation to find[Ag+]in each region.


Short Answer

Expert verified

The equation to findAg+isCtitrant=ntitrant-nanalyteVtotalAg+=nAg+-n1-VAg++V1-

Step by step solution

01

Define The formula to be used for solution

Solve for l-

role="math" localid="1654772439398" Canalyte=nanalyte-ntitrantVtotall-=n1--nAg+V1-+VAg+

02

calculate the solubility

Here for Ag+can be calculated using the solubility product formula:

role="math" localid="1654772931130" Ksp=Ag+l-Ag+=Kl-

(ii) at the equivalence point and by letting l-be equal to Ag+

Ag+l-=KspAg+Ag+=KspAg+2=KspAg+=Ksp

The number of moles of titrant (Ag+)is greater than the number of moles of analyte (l-).

Ctitrant=ntitrant-nanalyteVtotalAg+=nAg+-n1-VAg++V1-

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