/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 42 The solubility of \(\mathrm{MX}_... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

The solubility of \(\mathrm{MX}_{2}\) type electrolyte is \(0.5 \times 10^{-4}\) mol \(L^{-1}\). The value of \(K\) sp of the electrolyte is a. \(1.35 \times 10^{-13}\) b. \(25 \times 10^{-10}\) c. \(5 \times 10^{-13}\) d. \(5 \times 10^{-18}\)

Short Answer

Expert verified
The value of \( K_{sp} \) is \( 5 \times 10^{-13} \), which is option c.

Step by step solution

01

Write Down the Solubility Product Expression

For an electrolyte MXâ‚‚, it dissociates in water as \( \mathrm{MX}_{2} \rightarrow \mathrm{M}^{2+} + 2\mathrm{X}^{-} \). The solubility product \( K_{sp} \) is given by the expression \( K_{sp} = [\mathrm{M}^{2+}][\mathrm{X}^{-}]^2 \).
02

Define the Concentrations in Terms of Solubility

If the solubility of MXâ‚‚ is \( 0.5 \times 10^{-4} \) mol/L, then the concentration of \( \mathrm{M}^{2+} \) is \( 0.5 \times 10^{-4} \) mol/L as well. The concentration of \( \mathrm{X}^{-} \) is \( 2 \times 0.5 \times 10^{-4} = 1 \times 10^{-4} \) mol/L.
03

Substitute Concentrations into the Solubility Product Expression

Substitute the concentrations from Step 2 into \( K_{sp} = [\mathrm{M}^{2+}][\mathrm{X}^{-}]^2 \). We have: \[ K_{sp} = (0.5 \times 10^{-4}) \times (1 \times 10^{-4})^2 \]
04

Calculate the Solubility Product

Perform the calculations: \[ \begin{align*}K_{sp} &= 0.5 \times 10^{-4} \times (1 \times 10^{-4})^2 \&= 0.5 \times 10^{-4} \times 1 \times 10^{-8} \&= 0.5 \times 10^{-12} \&= 5 \times 10^{-13}\end{align*} \]
05

Compare with Available Options

From the calculated value \( K_{sp} = 5 \times 10^{-13} \), compare with the provided options. The correct answer corresponds to option c.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electrolyte Solubility
Electrolyte solubility refers to the ability of an electrolyte to dissolve in a solvent, usually water, to form a solution. Electrolytes are compounds that can break down into ions when dissolved in water. In the context of this exercise, we're dealing with a type of electrolyte called MXâ‚‚. Here, the solubility is given as the amount of electrolyte that can dissolve in a liter of water until the solution becomes saturated.
It's important to understand that solubility is influenced by factors like temperature and pressure.
For the given electrolyte,
  • MXâ‚‚ dissolves in water at a solubility of
    \(0.5 \times 10^{-4}\) mol/L.
  • This means only a very small amount of MXâ‚‚ can be dissolved before the solution becomes saturated.
Understanding solubility helps in determining how much of the electrolyte can be used in reactions and conditions required to reach saturation.
Dissociation in Water
When MXâ‚‚ is dissolved in water, it dissociates into its ionic components. This process is key to understanding what electrolytes do in aqueous solutions. Dissociation refers to the breaking apart of a compound into ions. For MXâ‚‚, the dissociation in water can be represented as:
\[ \text{MX}_{2} \rightarrow \text{M}^{2+} + 2\text{X}^{-} \]
This equation shows that one mole of MXâ‚‚ produces:
  • One mole of \(\text{M}^{2+}\) ions
  • Two moles of \(\text{X}^{-}\) ions
Dissociation in water is vital for the calculation of concentrations of ions that affect properties like electrical conductivity and reactivity.
This process helps us understand how solutions form and is essential for tasks such as predicting the behavior of other chemicals in solution.
Concentration Calculations
Once we know how a substance dissociates, we can calculate concentrations of individual ions. These calculations are useful in various chemical applications. In the provided exercise, we performed concentration calculations based on the dissociation of electrolyte MXâ‚‚.
With a solubility of \(0.5 \times 10^{-4}\) mol/L:
  • The concentration of \(\text{M}^{2+}\) ions is \(0.5 \times 10^{-4}\) mol/L.
  • The concentration of \(\text{X}^{-}\) ions is \(2 \times 0.5 \times 10^{-4} = 1 \times 10^{-4}\) mol/L.
These concentrations are then used to calculate the solubility product, or \(K_{sp}\), which determines how saturated a solution can become. Proper concentration calculations ensure accurate predictions and outcomes in chemical processes, essential for various scientific and industrial applications.
Chemical Equilibrium
Chemical equilibrium is a state where the rates of the forward and reverse reactions are equal. In a dissolved MXâ‚‚ solution, chemical equilibrium involves the balance of ion production and recombination.
When MXâ‚‚ dissolves in water, initially, lots of ions form quickly. Over time, as the solution reaches saturation, recombination into the original compound balance out the dissociation into ions. This dynamic state is known as equilibrium.
For the case of MXâ‚‚, the solubility product constant \(K_{sp}\) represents this balance, calculated as:
  • \(K_{sp} = [\text{M}^{2+}][\text{X}^{-}]^{2}\)
  • Reflects the maximum product of concentrations of ions that can coexist in equilibrium in the solution.
Understanding equilibrium concepts is crucial in chemistry because it allows you to predict how much of a substance can dissolve and the conditions under which reactions will occur in a stable manner.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Consider the following reversible reaction: \(\mathrm{CO}(\mathrm{g})+2 \mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}(\mathrm{g})\) \(\Delta \mathrm{H}=-92.5 \mathrm{~kJ}\)Which factor(s) will increase the yield of methanol at equilibrium? a. Addition of inert gas at constant volume b. Increased pressure on the system c. Increased temperature d. Increased partial pressure of hydrogen

For the reaction $$ \mathrm{CO}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \leftrightarrow \mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2}(\mathrm{~g}) $$ at a given temperature, the equilibrium amount of \(\mathrm{CO}_{2}(\mathrm{~g})\) can be increased by a. adding a suitable catalyst b. adding an inert gas c. decreasing the volume of the container d. increasing the amount of \(\mathrm{CO}(\mathrm{g})\)

\((\mathbf{A}): 0.33 \mathrm{M}\) solution of \(\mathrm{KCN}\) is more basic than \(0.33 \mathrm{M}\) solution of \(\mathrm{KF}\). (R): \(0.33 \mathrm{M}\) solution of \(\mathrm{KCN}\) is more basic than \(0.33 \mathrm{M}\) solution of \(\mathrm{CH}_{3} \mathrm{COOK}\).

\((\mathbf{A}):\) When \(0.1 \mathrm{M}\) diprotic weak acid \(\mathrm{H}, \mathrm{X}\) dissociates with its dissociation constants \(\mathrm{K}_{\mathrm{a}}=10^{-4}\) and \(\mathrm{K}_{\mathrm{a} 2}\) \(=10^{-12}\), then \(\left[\mathrm{X}^{-2}\right]\) is almost equal to \(10^{-12} \mathrm{M}\) \((\mathbf{R}):\) Since \(K_{a 2}<<\mathbb{K}_{a 1}\) for \(0.1 \mathrm{M}\) so \(\mathrm{H}_{2} \mathrm{X}\) so \(\left[\mathrm{X}^{-2}\right]\) is negligible w.r.t. \(\left[\mathrm{HX}^{-}\right]\). Hence \(\left[\dot{\mathrm{X}}^{-2}\right] \approx \mathrm{K}_{\mathrm{a} 2}\)

Match the following: Column I Column II A. \(0.5 \mathrm{M} \mathrm{NO}_{3}+0.1 \mathrm{M} \quad\) (p) 7 \(\mathrm{NH}_{4} \mathrm{OH}\) B. \(0.1 \mathrm{M} \mathrm{KCl}+0.1 \mathrm{M} \quad\) (q) greater then 7 \(\mathrm{KNO}_{3}\) C. \(0.2 \mathrm{M} \mathrm{NaOH}+0.5 \mathrm{M}(\mathrm{r})\) between 1 to 7 \(\mathrm{HCOOH}\) D. \(0.1 \mathrm{NH}_{4} \mathrm{Cl}+0.1 \mathrm{M}(\mathrm{s}) 0.7\) \(\mathrm{KOH}\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.