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The solubility of CuBr is \(2 \times 10^{-4} \mathrm{~mol} \mathrm{~L}^{-1}\) at \(25^{\circ} \mathrm{C}\). The Ksp value for CuBr is a. \(4 \times 10^{-6}\) b. \(4 \times 10^{-16}\) c. \(4 \times 10^{-11}\) d. \(4 \times 10^{-8}\)

Short Answer

Expert verified
The Ksp value for CuBr is d. \(4 \times 10^{-8}\).

Step by step solution

01

Understand the Problem

We need to find the solubility product constant (Ksp) for CuBr given its solubility in water at 25掳C. Solubility is given as \(2 \times 10^{-4} \text{ mol L}^{-1}\).
02

Write the Dissociation Equation

Write the dissociation equation for CuBr in water: \[ \text{CuBr (s)} \rightleftharpoons \text{Cu}^+ (aq) + \text{Br}^- (aq) \] This shows that for each mole of CuBr that dissolves, 1 mole of Cu\(^+\) ions and 1 mole of Br\(^-\) ions are produced.
03

Calculate the Concentrations

Since 1 mole of CuBr produces 1 mole of Cu\(^+\) and 1 mole of Br\(^-\), the concentration of each ion in a saturated solution is the same as the solubility: \[ [\text{Cu}^+] = [\text{Br}^-] = 2 \times 10^{-4} \text{ mol L}^{-1} \]
04

Write the Expression for Ksp

The expression for the solubility product constant (Ksp) is written as the product of the concentrations of the ions: \[ K_{sp} = [\text{Cu}^+][\text{Br}^-] \]
05

Substitute the Values

Substitute the concentrations into the Ksp expression: \[ K_{sp} = (2 \times 10^{-4})(2 \times 10^{-4}) \]
06

Perform the Calculation

Calculate the value: \[ K_{sp} = 4 \times 10^{-8} \] This matches option d.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Dissociation Equation
To understand the concept of dissociation, consider a compound like CuBr being added to water. CuBr is an ionic compound, which means it consists of both copper ions (Cu鈦) and bromide ions (Br鈦). When CuBr is placed into water, it dissociates or separates into these ions. This can be described with the dissociation equation: \[ \text{CuBr (s)} \rightleftharpoons \text{Cu}^+ (aq) + \text{Br}^- (aq) \] This is a straightforward process where one molecule of CuBr dissociates to give one copper ion and one bromide ion. It's important to note that this process is at equilibrium, indicated by the double arrows, meaning the solid compound and the ions are in a constant state of dissolve and formation. Understanding these equations is crucial as they lay the groundwork for further calculations.
Ion Concentration
Ion concentration is a key factor when dealing with solutions. When CuBr dissociates in water, each molecule releases one Cu鈦 ion and one Br鈦 ion. Given the solubility of CuBr is \(2 \times 10^{-4} \text{ mol L}^{-1}\), the concentration of each type of ion in the solution can also be directly determined. - For copper ions, the concentration is \([\text{Cu}^+] = 2 \times 10^{-4} \text{ mol L}^{-1}\).- Similarly, for bromide ions, the concentration is \([\text{Br}^-] = 2 \times 10^{-4} \text{ mol L}^{-1}\). Since the process is a simple 1:1 dissociation, the ion concentrations match the initial solubility of CuBr in the solution. Keeping track of these concentrations is vital when proceeding to calculate the Ksp.
Ksp Calculation
The solubility product constant, or Ksp, is a crucial value that helps us understand the extent to which a compound can dissolve in water. It is calculated as the product of the molar concentrations of the ions in the solution, each raised to the power of their stoichiometric coefficients in the dissociation equation. For CuBr, the expression for Ksp is: \[ K_{sp} = [\text{Cu}^+][\text{Br}^-] \] This is because each ion appears just once in the dissociation equation. By substituting the known concentrations, \([\text{Cu}^+] = 2 \times 10^{-4} \text{ mol L}^{-1}\) and \([\text{Br}^-] = 2 \times 10^{-4} \text{ mol L}^{-1}\), into the Ksp expression, you perform the calculation: \[ K_{sp} = (2 \times 10^{-4})(2 \times 10^{-4}) = 4 \times 10^{-8} \] This calculated Ksp value determines the point of equilibrium between the solid and its ions in the solution.
Solubility
Solubility is a measure of how much solute can dissolve in a solvent to form a saturated solution at a given temperature. Here, the solubility of CuBr in water was given as \(2 \times 10^{-4} \text{ mol L}^{-1}\) at 25掳C. This number represents the maximum concentration of the compound that can dissolve to form a stable solution. Understanding solubility is important for determining how much of a compound can realistically dissolve, which directly impacts the ion concentrations in the solution. It also provides insight into the behavior of compounds in various conditions, influencing reactions and formulations in chemistry. With this understanding, scientists and students alike can predict the outcomes of mixing different substances and the potential reactions and precipitates that may form.

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Most popular questions from this chapter

(A): The equilibrium constant is fixed and a characteristic for any given chemical reaction at a specified temperature. (R): The composition of the final equilibrium mixture at a particular temperature depends upon the starting amount of reactants.

If at a temperature the value of \(K_{C}\) for the reaction \(\mathrm{N}_{2}+3 \mathrm{H}_{2} \rightleftharpoons 2 \mathrm{NH}_{3}\) is \(1.49 \times 10^{-5} \mathrm{~mol}^{-2}\) lit \(^{2} .\) What will be the value of \(\mathrm{K}_{\mathrm{C}}\), for \(1 / 2 \mathrm{~N}_{2}+3 / 2 \mathrm{H}_{2} \rightleftharpoons 2 \mathrm{NH}_{3} ?\) a. \(1.49 \times 10^{-5}\) lit/mole b. \(3.86 \times 10^{-3}\) lit \(\mathrm{mol}^{-1}\) c. \(3.86 \times 10^{-3} \mathrm{lit}^{2} \mathrm{~mol}^{-2}\) d. \(1 / \sqrt{\left(1.49 \times 10^{-5}\right)} \mathrm{lit}^{-2} \mathrm{~mol}^{2}\)

The oxidation of sulphur dioxide by oxygen to sulphur trioxide has been implicated as an important step in the formation of acid rain: \(2 \mathrm{SO}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{SO}_{3}(\mathrm{~g})\) If the equilibrium partial pressures of \(\mathrm{SO}_{2}, \mathrm{O}_{2}\) and \(\mathrm{SO}_{3}\) are \(0.564 \mathrm{~atm}, 0.102 \mathrm{~atm}\), and \(0.333 \mathrm{~atm}\) respec- tively at \(1000 \mathrm{~K}\), what is the \(\mathrm{Kp}\) at that temperature? a. \(2.24\) b. \(4.68\) c. \(3.42\) d. \(13.42\)

What is the molar solubility of \(\mathrm{Cu}(\mathrm{OH})_{2}\) in \(1.0\) M \(\mathrm{NH}_{3}\) if the deep blue complex ion \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}^{2+}\) forms? The Ksp for \(\mathrm{Cu}(\mathrm{OH})_{2}\) is \(1.6 \times 10^{-19}\) and the \(\mathrm{K}_{\mathrm{r}}\) for \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}^{2+}\) is \(1.1 \times 10^{13}\) a. \(7.1 \times 10^{-4} \mathrm{M}\) b. \(7.6 \times 10^{-3} \mathrm{M}\) c. \(6.7 \times 10^{-3} \mathrm{M}\) d. \(5.6 \times 10^{-3} \mathrm{M}\)

Potassium chromate is slowly added to a solution containing \(0.20 \mathrm{M} \mathrm{AgNO}_{3}\) and \(0.20 \mathrm{M} \mathrm{Ba}\left(\mathrm{NO}_{3}\right)_{2}\) Describe what happens if the Ksp for \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) is \(1.1 \times 10^{-12}\) and the \(\mathrm{Ksp}\) of \(\mathrm{BaCrO}_{4}\) is \(1.2 \times 10^{-10}\) a. The \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) precipitates first out of solution and then \(\mathrm{BaCrO}_{4}\) precipitates. b. The \(\mathrm{BaCrO}_{4}\) precipitates first out of solution. c. Both \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) and \(\mathrm{BaCrO}_{4}\) precipitate simultaneously out of solution. d. Neither \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) nor \(\mathrm{BaCrO}_{4}\) precipitates out of solution.

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