Chapter 14: Q53P (page 670)
Match each of the 1HNMR spectra with one of the following compounds:






a.

b.

c.

Short Answer
a.

b.

c.

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Chapter 14: Q53P (page 670)
Match each of the 1HNMR spectra with one of the following compounds:






a.

b.

c.

a.

b.

c.

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Describe the 1H NMR spectrum you would expect for each of the following compounds, indicating the relative positions of the signals:



Identify each of the following compounds from its molecular formula and its NMR spectrum:
a.

b.

c.

d.

Which underlined proton (or sets of protons) has the greater chemical shift (that is, the higher frequency signal)?

Identify each of the following compounds from the 1H NMR data and molecular formula:
a.C4H8Br2: a 6H singlet at 1.97 ppm
a 2H singlet at 3.89 ppm
b. C8H9Br: a 3H doublet at 2.01 ppm
a 1H quartet at 5.14 ppm
a 5H broad singlet at 7.35 ppm
c. C5H10O2: a 3H triplet at 1.15 ppm
a 3H triplet at 1.25 ppm
a 2H quartet at 2.33 ppm
a 2H quartet at 4.13 ppm
[18]-Annulene shows two signals in its 1 H NMR spectrum: one at 9.25 ppm and the other to the right of the TMS signal at -2.88 ppm. What hydrogens are responsible for each of the signals?
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