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Chapter 4: Q27P (page 159)

Convert the Fischer projection to a perspective formula.

Short Answer

Expert verified

Perspective formulae are chemical compounds that have their components orientated in three dimensions. The Fischer projection is the one where all the molecules of a compound are seen on a two-dimensional sheet.

Step by step solution

01

Definition of Perspective Formulae

Perspective formulae are chemical compounds that have their components orientated in three dimensions. The Fischer projection is the one where all the molecules of a compound are seen on a two-dimensional sheet.

02

Steps to draw the Perspective formula.

  • First, draw the bonds around the asymmetrical center first keeping in mind that the solid and hatched wedges must be contiguous.


  • On the hatched wedge, place the group with the lowest priority. Any residual bond should be assigned to the group with the greatest priority.


  • Draw an arrow clockwisefrom the group with the highest priority to the next accessible bond, and place the group with the second-highest priority on that bond so that we get the R enantiomer.Therefore, the perspective formula is


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Most popular questions from this chapter

Question:Are the following pairs identical, enantiomers, diastereomers, or constitutional isomers?

Draw skeletal structures for the compounds in Problem 3, including any cis-trans isomers.

Draw four compounds with molecular formula C5H10that have carbon-carbon double bonds but do not have cis-trans isomers.

Stereoisomers with two asymmetric centres are called ___ if the configuration of both asymmetric centers in one stereoisomer is the opposite of the configuration of the asymmetric centers in the other stereoisomer.

b. Stereoisomers with two asymmetric centers are called ___ if the configuration of both asymmetric centers in one stereoisomer is the same as the configuration of the asymmetric centers in the other stereoisomer.

c. Stereoisomers with two asymmetric centers are called ___ if one of the asymmetric centers has the same configuration in both stereoisomers and the other asymmetric center has the opposite configuration in the two stereoisomers.

Which of the following has an asymmetric center?

CHBr2Cl BHFCl CH3CHCl2 CHFBrCl BeHCl
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