/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q12P Question: Draw a graph, similar ... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Question: Draw a graph, similar to Figure 3-9, of the torsional strain of 2-methylpropane as it rotates about the bond between and . Show the dihedral angle and draw a Newman projection for each staggered and eclipsed conformation.

Short Answer

Expert verified

Newman projections are often used in drawing conformations. In Newman projection, one is viewing the C-C bond end on along the axis of connection. The front carbon is represented by the intersection of bonds from it, while the rear carbon appears as a circle.

Step by step solution

01

Step-by-Step solutionStep 1: Newman projection

Newman projections are often used in drawing conformations. In Newman projection, one is viewing the C-C bond end on along the axis of connection. The front carbon is represented by the intersection of bonds from it, while the rear carbon appears as a circle.

02

Staggered and eclipsed conformation

Dihedral angle(θ) gives the identity of any conformation. It may be defined as the angle between C-Hbonds on the front carbon atom and C-H the bonds on the back carbon atom in the Newman projection. Eclipsed conformation has a dihedral angle,θ = 00 and the staggered conformation has a dihedral angle, θ = 600

03

Torsional strain

The potential energy of a molecule increases when it rotates toward an eclipsed conformation, and also there is a resistance to the rotation. The resistance to twisting (torsion) is known as torsional strain.

04

Graph showing torsional strainOF  2-methylpropane as it rotates about the bond between C1 and c2 .

eclipsed staggered eclipsed

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.