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Draw Newman projections of the following molecules viewed from the direction of the arrows.

(a)

(b)

(c)

Short Answer

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(a)

(b)

(c)

Step by step solution

01

Newman projection

Newman projections are often used in drawing conformations. In Newman projection, one is viewing the bond end on along the axis of connection. The front carbon is represented by the intersection of bonds from it, while the rear carbon appears as a circle.

02

 Drawing Newman projections

(a)

While looking from the direction of arrow, it can be seen that the front carbon has a methyl group pointing straight up, a chlorine atom pointing down and to the left, and also a hydrogen atom pointing down and to the right. The back carbon has an ethyl group pointing straight down, a bromine atom pointing up and to the left, and also a hydrogen atom pointing up and to the right.

(b)

While looking from the direction of arrow, it can be seen that the front carbon has a hydrogen atom pointing straight up, a bromine atom pointing down and to the left, and also a methyl group pointing down and to the right. The back carbon has an ethyl group pointing straight down, a chlorine atom pointing up and to the left, and also a hydrogen atom pointing up and to the right.

(c)

While looking from the direction of arrow, it can be seen that the front carbon has an ethyl group pointing straight up, a hydrogen atom pointing down and to the left, and also a bromine atom pointing down and to the right. The back carbon has an ethyl group pointing straight down, a hydrogen atom pointing up and to the left, and also a methyl group pointing up and to the right.

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Most popular questions from this chapter

Using what you know about the conformational energetics of substituted cyclohexanes, predict which of the two 9-methyldecalinisomers is more stable. Explain your reasoning.

Question: This is a Newman projection of a substituted cyclohexane.

(a) Draw the equivalent chair form

(b)Draw the equivalent structure using wedge and dash notation on a cyclohexane hexagon.

(c) Give the IUPAC name.

(a) Draw the two chair conformations of cis-1,3-dimethylcyclohexane, and label all the positions as axial or equatorial.

(b) Label the higher-energy conformation and the lower-energy conformation.

(c) The energy difference in these two conformations has been measured to be about23 k´³â€‰(5.4 k³¦²¹±ô)per mole. How much of this energy difference is due to the torsional energy of gauche relationships?

(d) How much energy is due to the additional steric strain of the1,3-diaxial interaction?

Question: The most stable form of 1,2,3,4,5,6-Cyclohexanehexolcontains a six-membered ring in the chair conformation with all the substituents equatorial. Draw this most stable conformation of cyclohexanehexol

Use a Newman projection about the indicated bond to draw the most stable conformer for each compound.

(a)3-³¾±ð³Ù³ó²â±ô±è±ð²Ô³Ù²¹²Ô±ð â¶Ä‰a²ú´Ç³Ü³Ù â¶Ä‰t³ó±ð C2−°ä3 â¶Ä‰b´Ç²Ô»å

(b)3,3-»å¾±³¾±ð³Ù³ó²â±ô³ó±ð³æ²¹²Ô±ð â¶Ä‰a²ú´Ç³Ü³Ù â¶Ä‰t³ó±ð C3−°ä4 â¶Ä‰b´Ç²Ô»å

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