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Chapter 1: 51P (page 89)

For each of the following compounds,

1. Give the hybridization and approximate bond angles around each atom except hydrogen.

2. Draw a three-dimensional diagram, including any lone pairs of electrons.

(a) H3O+

(b) OH-

(c)CH2CHCN

(d)N(CH3)3

(e) CH3NH3+

(f) CH3COOH

(g) CH2CHNH

(h) CH3OH

(i) CH2O

Short Answer

Expert verified
  1. The hybridization and bond angles around each atom accepts hydrogens.They are shown as below:


(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

2. A three dimensional diagram is given there as well.

Step by step solution

01

Hybridisation, bond angles   and diagram of compounds  

Generally, atoms with sp3 hybridization have the bond angle of 110o and atoms with sp2 hybridization having bond angle of 120o. For structure determination if we consider lone pair of electrons then there should be different shape. But for geometry consideration the structure without lone pair should be determined in the following compounds.

(a)

Hybridization of (a)

(b)

Hybridization of (b)

(c)

Hybridization of (c)

(d)

(e)

Hybridization of e

(f)

(g)

(h)

(I)

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In the following sets of resonance forms, label the major and minor contributors and state which structures would be of equal energy. Add any missing resonance forms.

There is a small portion of the periodic table that you must know to do organic chemistry. Construct this part from memory, using the following steps.

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(a) Compute an empirical formula for compound X.

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(c) Many possible structures have this molecular formula. Draw complete structural formulas for four of them.
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