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Chapter 22: Q5Pb (page 1155)

Predict the major products of the following reactions.

b)

Short Answer

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b)

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01

Alkylation of enolate ions

Lithium diisopropyl amide (LDA) is used for the alkylation of enolate ions as it is a strong base and transforms the ketone to an enolate.

02

Predicting the major products of the reaction

(b) The reaction of the given compound with LDA and CH3CH2Br is 2-ethyloctahydronaphthalen-1(2H)-one. The reaction is given below:

Product of reaction (b)

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Most popular questions from this chapter

Show how octane-2,7-dione might cyclize to a cycloheptenone. Explain why ring closure to the cycloheptenone is not favored.

Which compounds will give positive iodoform tests?

  1. 1-phenyl ethanol
  2. pentan-2-ol
  3. pentan-2-one
  4. pentan-3-one
  5. acetone
  6. isopropyl alcohol

Question:Show how you would use an aldol, Claisen, or another type of condensation to make each compound

d.

Show how you would use an aldol, Claisen, or another type of condensation to make each compound.

The following compound results from base-catalyzed aldol cyclization of a 2-substituted cyclohexanone.

  1. Show the diketone that would cyclize to give this product.
  2. Propose a mechanism for the cyclization
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