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Question: Give both IUPAC names and common names for the following compounds.

(a) phCH2COOH

(b) phCO2Na

(c) (CH3)2 CHCHCICOOH

(d) HOOC (CH2)4CO2H

(e) (CH3)2 CHCH2COOK

(f) CH3 CH(NH2) COOH

(g)

(h)

(i)

Short Answer

Expert verified

Answer

  1. The IUPAC name is 2-phenylethanoic acid, and the common name is .
  2. The IUPAC name is sodium benzoate and there is no common name.
  3. The IUPAC name is 2-chloro-3-methylbutanoic acid, and the common name is .
  4. The IUPAC name is Hexandioic acid, and the common name is adipic acid.
  5. The IUPAC name is Potassium 3-methylbutanoate, and the common name is .
  6. The IUPAC name is 2-aminopropanoic acid, and the common name is.
  7. The IUPAC name is 2-chlorobenzoic acid, and the common name is o-chlorobenzoic acid.
  8. The IUPAC name is calcium ethanedioate, and the common name is calcium oxalate.
  9. The IUPAC name is 3-methoxybenzene-1,2-dicarboxylic acid, and the common name is 3-methoxyphthalic acid.

Step by step solution

01

IUPAC and common names

The IUPAC names of the compounds are written by identifying the substituents attached to the carbon chain or cyclic ring.If a carbon chain contains carboxylic acid, the suffix used in the end is ‘–oic acid’.

02

The IUPAC and common name of  phCH2COOH

  1. The given compound is phCH2COOH. The phenyl group is attached at the second position as numbering starts from the COOH group. The parent chain contains two carbon α, so ‘ethan’ is used. The IUPAC name is 2-phenylethanoic acid.
  2. The common name for this compound is because the phenyl group is present at carbon and acetic acid is for CH2COOH group where Ph replaces one hydrogen.
03

The IUPAC and common name of PhCO2Na 

b. The given compound is PhCO2Na , here, sodium is a cation and PhCOO-is a benzoate. So, first cation name is written and then anion. Thus, the IUPAC name is sodium benzoate, and there is no common name.

04

The IUPAC and common name of  (CH3)2 CHCHCICOOH 

C. The given compound is(CH3)2 CHCHCICOOH . At the 2nd position, the chloro group is attached, and at the 3rd position, the methyl group is attached. The longest carbon chain consists of 4 carbon, so ‘butan’ is used. The IUPAC name is 2-chloro-3-methylbutanoic acid. The common name is α-cloroβ-Methylbutyricacidbecause at position, chloro group, and at position, a methyl group is attached.

05

The IUPAC and common name of HOOC (CH2)4 CO2H

d. The given compound is HOOC (CH2)4CO2H. There are two –COOH groups in a compound, so ‘-dioic acid’ is used and is a 6-carbon chain, so ‘Hexan’ is used. Thus, the IUPAC name is Hexandioic acid, and the common name is adipic acid.

06

The IUPAC and common name of (CH3)2 CHCH2COOK

e. The given compound is(CH3)2 CHCH2COOK . Here, potassium (K+) is a cation and (CH3)2 CHCH2COO- is 3-methylbutanoate. For naming the compound, the cation is written first and then anion. Thus, the IUPAC name is Potassium 3-methylbutanoate. The common name is β-methylbutanoate, here methyl group is present atβposition.

07

The IUPAC and common name of CH3 CH(NH2) COOH

f. The given compound isCH3 CH(NH2) COOH. Here, the amino group is attached at the 2nd position and is a 3-carbon chain, so ‘propan’ is used, and –COOH group means ‘-oic acid.’ Thus, the IUPAC name is 2-aminopropanoic acid. The common name is , where an amino group is present atα position.

08

 Step 8: The IUPAC and common name of (g) compound

g. In a given compound, at the 1st position, a –COOH group is attached, and at the 2nd position, the chloro group is attached. Thus, the IUPAC name is 2-chlorobenzoic acid. The common name is o-chlorobenzoic acid because the two groups –Cl and –COOH are present at the ortho position.

09

The IUPAC and common name of (h) compound

h. In a given compound, calcium is a cation and (C00-)2is ethanedioate anion. For naming the compound, the first cation is written and then anion. The IUPAC name is calcium ethanedioate, and the common name is calcium oxalate.

10

The IUPAC and common name of (i) compound

I. In a given compound, at the 1st and 2nd position of the benzene ring, two carboxylic groups (-COOH) are attached, so ‘-di’ is used, and at the 3rd position, methoxy group (OCH3) is attached. Thus, the IUPAC name is 3-methoxybenzene-1,2-dicarboxylic acid, and the common name is 3-methoxyphthalic acid.

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