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Chapter 21: Q36P-b (page 1129)

Show how you would accomplish the following synthetic transformations. You may use any necessary reagents.(b)ethylbenzoate鈫�N-ethylbenzamide

Short Answer

Expert verified

Synthetic transformation for ethyl benzoate to N-ethylbenzamide is shown as,

Step by step solution

01

Step-by-Step SolutionStep 1: Use of heating in this reaction

In this reaction heating condition are require for fast reaction and formation of amide product, If we do not provide the heat for this reaction then formation of amide product is very slow and also reaction rate are slow.

02

Synthesis of N-ethylbenzamide from ethylbenzoate

When ethylbenzoate react with ethyl amine followed by heating then there is a formation of N-ethylbenzamide as a final product, In this reaction ethyl amine acts as a nucleophile and it attack on the carbonyl carbon of ethylbenzoateand there is a formation of N-ethylbenzamide and ethyl alcohol as a by product.

This reaction is favored at a high temperature.

Formation of N-ethylbenzamide

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Most popular questions from this chapter

Show how you would accomplish the following syntheses using amides as intermediates.

You may use any necessary reagents.

(a)benzoicacid鈫�benzyldimethylamine

Name the following carboxylic acid derivatives, giving both a common name and an IUPAC name where possible.

a.

b.

c.

d.

e.

f.

g.

h.

i.

j.

k.

l.

m.

n.

o.

p.

q.

r.

Show how you would accomplish the following synthetic transformations. You may use any necessary reagents.(a)N-ethylbenzamide鈫�benzylethylamine

Show how you would use appropriate acyl chlorides and amines to synthesize the following amides.

(a)N,N-dimethylacetamide

(b)acetanilide(PhNHCOCH3)

(c)cyclohexanecarboxamide

(d)

When ethyl 4-hydroxybutyrate is heated in the presence of a trace of a basic catalyst (sodium acetate), one of the products is a lactone. Propose a mechanism for the formation of this lactone.
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