Chapter 9: Q3P (page 469)
What reaction would acetylene likely to undergo if it were kept at for too long?
Short Answer
When acetylene is kept at for too long, it will decompose into carbon (C) and hydrogen (H) elements.
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Chapter 9: Q3P (page 469)
What reaction would acetylene likely to undergo if it were kept at for too long?
When acetylene is kept at for too long, it will decompose into carbon (C) and hydrogen (H) elements.
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Using any necessary inorganic reagents, show how you would convert acetylene and isobutylbromide to
(a)meso-2,7-dimethyloctane-4,5-diol,(CH3)2CHCH2CH(OH)CH(OH)CH2CH(CH3)2 .
(b) (± ) -2,7-dimethyloctane-4,5-diol
Predict the major product(s) of the following reactions:
(a) phenylacetylene + 2 HBr
(b) hex-1-yne + 2 HCl
(c) cyclooctyne + 2 HBr
(d) hex-2-yne + 2 HCl
Disiamylborane adds only once to alkynes by virtue of its two bulky secondary isoamyl groups. Disiamylborane is prepared by the reaction of BH3. THF with an alkene.
(a) Draw the structural formulas of the reagents and the products in the preparation of disiamylborane.
(b) Explain why the reaction in part (a) goes only as far as the dialkylborane. Why is Sia3B not formed?
Question:Predict the products of the reaction of but-1-yne with the following reagents.
(a)1 equivalent of HCl
(b)2 equivalents of HCl
(c)excess H2 , Ni
(d) H2 , Pd /BaSO4, quinolone
(e)1 equivalent of Br2
(f)2 equivalents of Br2
(g)cold, dilute KMnO4
(h)warm, concd.KMnO4 , NaOH
(i)Na, liquid ammonia
(j) NaNH2
(k) H2SO4/HgSO4, H2O
(l) Sia2BH, then , H2O2,OH-
Propose a mechanism for the reaction of pent-1-yne with HBr in the presence of peroxides. Show why anti-Markovnikov orientation results.
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