Chapter 30: Question 30.20 (page 1217)
Draw a stepwise mechanism for Step [2] in Figure 30.7 using the Lewis acid catalyst.
Short Answer
Answer
Mechanism of the reaction
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Chapter 30: Question 30.20 (page 1217)
Draw a stepwise mechanism for Step [2] in Figure 30.7 using the Lewis acid catalyst.
Answer
Mechanism of the reaction
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Draw a stepwise mechanism for the anionic polymerization of styrene to form polystyrene using BuLi as an initiator. Use CO2 as the electrophile that terminates the chain mechanism.
Compound A is a novel poly(ester amide) copolymer that can be used as a bioabsorbable coating for the controlled release of drugs. A is a copolymer of four monomers, two of which are amino acids or amino acid derivatives. The body’s enzymes recognize the naturally occurring amino acids in the polymer backbone, allowing for the controlled enzymatic breakdown of the polymer and steady release of an encapsulated drug. Identify the four monomers used to synthesize A; then use Figure 29.2 to name the two amino acids.
Poly(ester amide) A
Draw the structure of the three monomers used to prepare polybutyrateadipate terephthalate (PBAT), a biodegradable copolymer sold under the trade name of Ecoflex. Because PBAT has properties similar to low-density polyethylene, it can be used in biodegradable food packaging and plastic bags.
PBAT
Explain why acrylonitrile () undergoes cationic polymerization more slowly than but-3-enenitrile () .
Thermosetting resins similar to Bakelite (Section 30.7) have also been prepared from renewable feedstocks. One method uses cardinol, the major constituent of the liquid obtained from roasted cashew nutshells. What polymer is obtained when cardinol is treated with formaldehyde () in the presence of a proton source?

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