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Chapter 21: 11P (page 817)

What reagents are needed to convert each compound into butanal(CH3CH2CH2CHO)?

a.

b.

c.

d.

Short Answer

Expert verified

a.

b.

c.

d.

Step by step solution

01

Reagents

Reagents are used to synthesize different products. Reactions such as hydroboration-oxidation, ozonolysis are used to convert alkenes into aldehydes.

02

Formation of the product

a. The reaction of methyl butyrate with DIBAL-H followed by water gives butyraldehyde.

The reaction is shown below.

Synthesis in a

b. The reaction of butan-1-ol with PCC gives butyraldehyde.

The reaction is shown below.

Synthesis in b

c. But-1-yne undergoes hydroboration-oxidation in the presence of hydrogen peroxide to form butyraldehyde.

The reaction is shown below.

Synthesis in c

d. (E)-Oct-4-ene undergoes ozonolysis to form butyraldehyde.

The reaction is shown below.

Synthesis in d

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Most popular questions from this chapter

Design a stepwise synthesis to convert cyclopentanone and 4-bromobutanal to hydroxy aldehyde A.

Draw a stepwise mechanism for each reaction.

a.

b.

An unknown compound C of molecular formula C6H12O3 exhibits a strong absorption in its IR spectrum at 1718 cm-1 and the given 1H NMR spectrum. What is the structure of C?

Which compound in each pair forms the higher percentage of gem-diol at equilibrium?

a.

or

b.

or

Draw a stepwise mechanism for the following reaction
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