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What is the pH of a solution that has an \(\mathrm{H}^{+}\) concentration (a) \(1.75 \times 10^{-6} \mathrm{mol} / \mathrm{L}\) of (b) \(6.50 \times 10^{-10} \mathrm{mol} / \mathrm{L}\) (c) \(1.0 \times\) \(10^{-4} \mathrm{mol} / \mathrm{L} ;(\mathrm{d}) 1.50 \times 10^{-5} \mathrm{mol} / \mathrm{L} ?\)

Short Answer

Expert verified
(a) pH ≈ 5.76, (b) pH ≈ 9.19, (c) pH = 4.00, (d) pH ≈ 4.82.

Step by step solution

01

Understanding pH

The pH of a solution is defined as the negative logarithm (base 10) of the hydrogen ion concentration. Mathematically, it is expressed as: \[ \text{pH} = -\log[\mathrm{H}^+] \] This formula will be used for each part of the question to find the pH value of the solution.
02

Calculate pH for (a)

For the given hydrogen ion concentration, \( [\mathrm{H}^+] = 1.75 \times 10^{-6} \) mol/L, substitute the value into the pH formula:\[ \text{pH} = -\log(1.75 \times 10^{-6}) \approx 5.76 \]
03

Calculate pH for (b)

Given \([\mathrm{H}^+] = 6.50 \times 10^{-10}\) mol/L, substitute into the pH formula:\[ \text{pH} = -\log(6.50 \times 10^{-10}) \approx 9.19 \]
04

Calculate pH for (c)

For \([\mathrm{H}^+] = 1.0 \times 10^{-4} \) mol/L:\[ \text{pH} = -\log(1.0 \times 10^{-4}) = 4.00 \] since \(\log(1.0) = 0\) and \(\log(10^{-4}) = -4\).
05

Calculate pH for (d)

Given \([\mathrm{H}^+] = 1.50 \times 10^{-5}\) mol/L, calculate the pH:\[ \text{pH} = -\log(1.50 \times 10^{-5}) \approx 4.82 \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydrogen Ion Concentration
The hydrogen ion concentration \( [\mathrm{H}^+] \) is a measure of the number of hydrogen ions present in a solution, generally expressed in moles per liter (mol/L).This concentration is a direct indicator of the solution's acidity. A higher concentration of hydrogen ions means the solution is more acidic, while lower concentrations denote a more basic solution. The concentration numbers are often very small decimals in scientific notation because the amount of hydrogen ions in solutions can be quite tiny.Understanding these values and how they relate to pH can help determine the overall character of a solution. Remember:
  • High \( [\mathrm{H}^+] \) = acidic solution.
  • Low \( [\mathrm{H}^+] \) = basic or alkaline solution.
Having a clear idea of what \( [\mathrm{H}^+] \) means is crucial before diving into calculations like pH.
Logarithmic Scale
The pH scale is logarithmic, meaning it uses powers of ten. This is crucial because it allows us to represent very large or very small quantities more manageably. Think of the magnitude of earthquakes; similarly, pH scales convey large variations in ion concentration concisely. This means each whole number step in the pH scale corresponds to a tenfold change in hydrogen ion concentration. For example:
  • A pH of 3 signifies ten times the concentration of hydrogen ions than a pH of 4.
  • Conversely, a pH of 7 is a much more neutral range, closely aligned with the water baseline.
Being comfortable with this exponential concept will help make pH calculations intuitive and clarify why the pH scale runs from 0-14.
Acid-Base Equilibrium
Acid-base equilibrium involves a balance between acids and bases in a solution, represented by the concentrations of hydrogen ions \( [\mathrm{H}^+] \) and hydroxide ions \( [\mathrm{OH}^-] \).In pure water, these are balanced, which is why pure water has a neutral pH of 7. An imbalance in this equilibrium can tilt a solution to be either more acidic or more basic.Important points include:
  • Acids increase \( [\mathrm{H}^+] \) in a solution.
  • Bases decrease \( [\mathrm{H}^+] \), often by increasing \( [\mathrm{OH}^-] \).
Understanding acid-base equilibrium is fundamental for predicting how changes in concentration impact pH levels and whether solutions might buffer against change, crucial in countless chemical and biological processes.
Solution Chemistry
Solution chemistry is the study of solutes dissolved in solvents creating a homogenous mixture, a solution. It's a central part of chemistry, where solutions can be gases, liquids, or solids.The pH calculation is a straightforward application of solution chemistry principles, connecting solute concentrations with acidity or basicity.Key points to remember include:
  • Solutes (acids/bases) interact to modify \( [\mathrm{H}^+] \) levels.
  • Concentration directly affects a solution's behavior and properties, including pH.
Grasping these fundamentals aids in deeper understanding, allowing you to apply this knowledge to various functions like neutralizing acidic or alkaline episodes in real-world scenarios and experiments.

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Most popular questions from this chapter

The \(\mathrm{pH}\) of the extracellular fluid is buffered by the bicarbonate/ carbonic acid system. Holding your breath can increase the concentration of \(\mathrm{CO}_{2}(\mathrm{g})\) in the blood. What effect might this have on the pH of the extracellular fluid? Explain by showing the relevant equilibrium equation(s) for this buffer system.

An unknown compound, \(\mathrm{X}\), is thought to have a carboxyl group with a \(\mathrm{p} K_{\mathrm{n}}\) of 2.0 and another ionizable group with a \(\mathrm{p} K_{\mathrm{a}}\) between 5 and \(8 .\) When \(75 \mathrm{mL}\) of \(0.1 \mathrm{M} \mathrm{NaOH}\) is added to \(100 \mathrm{mL}\) of a \(0.1 \mathrm{M}\) solution of \(\mathrm{X}\) at \(\mathrm{pH} 2.0\), the \(\mathrm{pH}\) increases to \(6.72 .\) Calculate the \(\mathrm{p} K_{\mathrm{a}}\) of the second ionizable group of \(X\).

A biochemist has \(100 \mathrm{mL}\) of a 0.10 M solution of a weak acid with a \(\mathrm{p} K_{\mathrm{a}}\) of \(6.3 .\) She adds \(6.0 \mathrm{mL}\) of \(1.0 \mathrm{m} \mathrm{HCl}\) which changes the pH to \(5.7 .\) What was the pH of the original solution?

(a) The partial pressure of \(\mathrm{CO}_{2}\) in the lungs can be varied rapidly by the rate and depth of breathing. For example, a common remedy to alleviate hiccups is to increase the concentration of \(\mathrm{CO}_{2}\) in the lungs. This can be achieved by holding one's breath, by very slow and shallow breathing (hypoventilation), or by breathing in and out of a paper bag. Under such conditions, \(\mathrm{pCO}_{2}\) in the air space of the lungs rises above normal. Qualitatively explain the effect of these procedures on the blood pH. (b) A common practice of competitive short-distance runners is to breathe rapidly and deeply (hyperventilate) for about half a minute to remove \(\mathrm{CO}_{2}\) from their lungs just before the race begins. Blood pH may rise to \(7.60 .\) Explain why the blood pH increases. (c) During a short-distance run, the muscles produce a large amount of lactic acid \(\left(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{OH}) \mathrm{COOH} ; K_{\mathrm{a}}=1.38 \times\right.\) \(10^{-4}\) M) from their glucose stores. In view of this fact, why might hyperventilation before a dash be useful?

Calculate the \(\mathrm{pH}\) of a blood plasma sample with a total \(\mathrm{CO}_{2}\) concentration of \(26.9 \mathrm{mM}\) and bicarbonate concentration of \(25.6 \mathrm{mM}\). Recall from page 67 that the relevant \(\mathrm{p} K_{\mathrm{a}}\) of car- bonic acid is 6.1.

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