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Methane enters a 3 -cm ID pipe at \(30^{\circ} \mathrm{C}\) and 10 bar with an average velocity of \(5.00 \mathrm{m} / \mathrm{s}\) and emerges at a point 200 m lower than the inlet at \(30^{\circ} \mathrm{C}\) and 9 bar. (a) Without doing any calculations, predict the signs ( \(+\) or \(-\) ) of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}},\) where \(\Delta\) signifies (outlet - inlet). Briefly explain your reasoning. (b) Calculate \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}(\mathrm{W}),\) assuming that the methane behaves as an ideal gas. (c) If you determine that \(\Delta \dot{E}_{\mathrm{k}} \neq-\Delta \dot{E}_{\mathrm{p}},\) explain how that result is possible.

Short Answer

Expert verified
\(\Delta \dot{E}_{\mathrm{k}} = 0\) and \(\Delta \dot{E}_{\mathrm{p}}\) is negative. If \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\), it can imply that there is some heat transfer and/or work done during the process.

Step by step solution

01

Prediction of signs of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}\)

The velocity is the same at the inlet and outlet, hence there is no change in kinetic energy. Therefore, \(\Delta \dot{E}_{\mathrm{k}} = 0\). Methane emerges at a point 200m lower than the inlet, indicating a decrease in potential energy (as potential energy is proportional to height). Therefore, \(\Delta \dot{E}_{\mathrm{p}}\) is negative.
02

Calculation of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}\)

As derived in step 1, \(\Delta \dot{E}_{\mathrm{k}} = 0\). For \(\Delta \dot{E}_{\mathrm{p}}\), use the formula for change in potential energy \(\Delta E_p = m \cdot g \cdot \Delta h\), where m is mass, g is acceleration due to gravity and \(\Delta h\) is change in height. The mass flow rate of methane can be calculated from the given average velocity, diameter of the pipe, and the ideal gas law. After calculating the mass flow rate, it can be substituted in the potential energy formula to find \(\Delta \dot{E}_{\mathrm{p}}\).
03

Explanation for \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\)

The energy conservation equation for a steady-flow process is given by: \(\Delta KE + \Delta PE = Q - W\), where Q represents heat transfer and W is work done. If \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\), it implies \(Q \neq 0\) and/or \(W \neq 0\), i.e., there is some heat transfer and/or work done during the process apart from changes in kinetic and potential energies. This can occur due to friction (which generates heat) in the fluid or if there is some sort of mechanical or heat interaction (like a pump or a heat exchanger) in the system.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Kinetic Energy in Chemical Processes
Understanding kinetic energy in chemical processes is pivotal because it embodies the energy of motion. As molecules move and react, they carry kinetic energy. In the context of the exercise, the methane gas flowing through a pipe exhibits kinetic energy due to its velocity. Contrary to what might seem intuitive, the exercise shows that kinetic energy, denoted by \(\Delta \dot{E}_{\mathrm{k}}\), does not always change as the gas flows through the system.

It's important to clarify why \(\Delta \dot{E}_{\mathrm{k}} = 0\) in this scenario. This occurs because the velocity, and consequently the kinetic energy of the gas, remains constant from the inlet to the outlet of the pipe; this suggests that other forms of energy or work might be involved in the system. This delineates a fundamental principle: kinetic energy change within a chemical process is not solely reliant on the distances travelled by the molecules, but rather on changes in their velocities.
Potential Energy in Chemical Systems
Potential energy in chemical systems is closely associated with the position or configuration of the system. In the case of gases, such as methane in our exercise, potential energy can be tied to the elevation of the gas due to gravitational forces. As per the given problem, methane is released 200 meters lower than where it was introduced, leading to a loss in potential energy, signified by a negative \(\Delta \dot{E}_{\mathrm{p}}\).

Using the equation \(\Delta E_p = m \cdot g \cdot \Delta h\), where \(m\) is mass, \(g\) is the gravitational acceleration, and \(\Delta h\) is the change in height, we see that as the distance \(\Delta h\) decreases, so does the potential energy. This relationship demonstrates that within chemical systems, potential energy variably depends on the position within a gravitational field and is crucial for understanding the energetics in processes like fluid flow in pipes.
Steady-Flow Energy Equation
The steady-flow energy equation is a vital concept in thermodynamics that describes the conservation of energy in fluid flow through a control volume. As per the step 3 of the solution, the equation \(\Delta KE + \Delta PE = Q - W\) relates changes in kinetic \(\Delta KE\) and potential \(\Delta PE\) energies to heat transfer \(Q\) and work done \(W\).

This equation can be misleading if examined superficially, as one might expect changes in kinetic and potential energies to be equal and opposite, which is not always the case. The exercise shows that \(\Delta \dot{E}_{\mathrm{k}} eq -\Delta \dot{E}_{\mathrm{p}}\), indicating that there is either heat transfer or work done or both within the system. For instance, friction could convert mechanical energy into thermal energy, or a pump might add work to the system, thus altering the straightforward exchange between kinetic and potential energies. This expounds on the complexity of real-world chemical processes, where multiple energy transformations occur simultaneously.

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Most popular questions from this chapter

The specific enthalpy of liquid \(n\) -hexane at 1 atm varies linearly with temperature and equals \(25.8 \mathrm{kJ} / \mathrm{kg}\) at \(30^{\circ} \mathrm{C}\) and \(129.8 \mathrm{kJ} / \mathrm{kg}\) at \(50^{\circ} \mathrm{C}\) (a) Determine the equation that relates \(\hat{H}(\mathrm{kJ} / \mathrm{kg})\) to \(T\left(^{\circ} \mathrm{C}\right)\) and calculate the reference temperature on which the given enthalpies are based. Then derive an equation for \(\hat{U}(T)(\mathrm{kJ} / \mathrm{kg})\) at 1 atm. (b) Calculate the heat transfer rate required to cool liquid \(n\) -hexane flowing at a rate of \(20 \mathrm{kg} / \mathrm{min}\) from \(60^{\circ} \mathrm{C}\) to \(25^{\circ} \mathrm{C}\) at a constant pressure of 1 atm. Estimate the change in specific internal energy \((\mathrm{kJ} / \mathrm{kg})\) as the n-hexane is cooled at the given conditions.

Air at \(300^{\circ} \mathrm{C}\) and \(130 \mathrm{kPa}\) flows through a horizontal \(7-\mathrm{cm}\) ID pipe at a velocity of \(42.0 \mathrm{m} / \mathrm{s}\). (a) Calculate \(\dot{E}_{\mathrm{k}}(\mathrm{W}),\) assuming ideal-gas behavior. (b) If the air is heated to \(400^{\circ} \mathrm{C}\) at constant pressure, what is \(\Delta \dot{E}_{\mathrm{k}}=\dot{E}_{\mathrm{k}}\left(400^{\circ} \mathrm{C}\right)-\dot{E}_{\mathrm{k}}\left(300^{\circ} \mathrm{C}\right) ?\) (c) Why would it be incorrect to say that the rate of transfer of heat to the gas in Part (b) must equal the rate of change of kinetic energy?

During a period of relative inactivity, the average rate of transport of enthalpy by the metabolic and digestive waste products leaving the body minus the rate of enthalpy transport by the raw materials ingested and breathed into the body is approximately \(\Delta H=-300 \mathrm{kJ} / \mathrm{h}\). Heat is transferred from the body to its surroundings at a rate given by \(Q=h A\left(T_{\mathrm{s}}-T_{0}\right)\) where \(A\) is the body surface area (roughly \(1.8 \mathrm{m}^{2}\) for an adult), \(T_{\mathrm{s}}\) is the skin temperature (normally \(\left.34.2^{\circ} \mathrm{C}\right), T_{0}\) is the temperature of the body surroundings, and \(h\) is a heat transfer coefficient. Typical values of \(h\) for the human body are \(^{5}\) \(h=8 \mathrm{kJ} /\left(\mathrm{m}^{2} \cdot \mathrm{h} \cdot^{\circ} \mathrm{C}\right) \quad\) (fully clothed, slight breeze blowing) \(h=64 \mathrm{kJ} /\left(\mathrm{m}^{2} \cdot \mathrm{h} \cdot^{\circ} \mathrm{C}\right) \quad\) (nude, immersed in water) (a) Consider the human body as a continuous system at steady state. Write an energy balance on the body, making all appropriate simplifications and substitutions. (b) Calculate the surrounding temperature for which the energy balance is satisfied (i.e., at which a person would feel neither hot nor cold) for a clothed person and for a nude person immersed in water. (c) At a family party, an elderly relative calls out to you in a loud voice, "Hey, you're an engineer, so you know everything. Explain why I'm comfortable when the room temperature is seventy degrees, but if I get into seventy-degree water in a bathtub, I'm freezing." He stops with a smug expression on his face and along with everyone else within earshot waits for your response. What would it be?

Steam produced in a boiler is frequently "wet"-that is, it is a mist composed of saturated water vapor and entrained liquid droplets. The quality of a wet steam is defined as the fraction of the mixture by mass that is vapor. A wet steam at a pressure of 5.0 bar with a quality of 0.85 is isothermally "dried" by evaporating the entrained liquid. The flow rate of the dried steam is \(52.5 \mathrm{m}^{3} / \mathrm{h}\). (a) Use the steam tables to determine the temperature at which this operation occurs, the specific enthalpies of the wet and dry steams, and the total mass flow rate of the process stream. (b) Calculate the heat input (kW) required for the evaporation process. (c) Suppose leaks developed in the feed pipe to the dryer and in the dryer exit pipe. Speculate on what you would see at each location.

A Thomas flowmeter is a device in which heat is transferred at a measured rate from an electric coil to a flowing fluid, and the flow rate of the stream is calculated from the measured increase of the fluid temperature. Suppose a device of this sort is inserted in a stream of nitrogen, the current through the heating coil is adjusted until the wattmeter reads \(1.25 \mathrm{kW},\) and the stream temperature goes from \(30^{\circ} \mathrm{C}\) and \(110 \mathrm{kPa}\) before the heater to \(34^{\circ} \mathrm{C}\) and \(110 \mathrm{kPa}\) after the heater. (a) If the specific enthalpy of nitrogen is given by the formula \(\hat{H}(\mathrm{kJ} / \mathrm{kg})=1.04\left[T\left(^{\circ} \mathrm{C}\right)-25\right]\) what is the volumetric flow rate of the gas (L/s) upstream of the heater (i.e., at \(30^{\circ} \mathrm{C}\) and \(110 \mathrm{kPa}\) )? (b) List several assumptions made in the calculation of Part (a) that could lead to errors in the calculated flow rate.

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