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Methane enters a 3 -cm ID pipe at \(30^{\circ} \mathrm{C}\) and 10 bar with an average velocity of \(5.00 \mathrm{m} / \mathrm{s}\) and emerges at a point 200 m lower than the inlet at \(30^{\circ} \mathrm{C}\) and 9 bar. (a) Without doing any calculations, predict the signs ( \(+\) or \(-\) ) of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}},\) where \(\Delta\) signifies (outlet - inlet). Briefly explain your reasoning. (b) Calculate \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}(\mathrm{W}),\) assuming that the methane behaves as an ideal gas. (c) If you determine that \(\Delta \dot{E}_{\mathrm{k}} \neq-\Delta \dot{E}_{\mathrm{p}},\) explain how that result is possible.

Short Answer

Expert verified
\(\Delta \dot{E}_{\mathrm{k}} = 0\) and \(\Delta \dot{E}_{\mathrm{p}}\) is negative. If \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\), it can imply that there is some heat transfer and/or work done during the process.

Step by step solution

01

Prediction of signs of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}\)

The velocity is the same at the inlet and outlet, hence there is no change in kinetic energy. Therefore, \(\Delta \dot{E}_{\mathrm{k}} = 0\). Methane emerges at a point 200m lower than the inlet, indicating a decrease in potential energy (as potential energy is proportional to height). Therefore, \(\Delta \dot{E}_{\mathrm{p}}\) is negative.
02

Calculation of \(\Delta \dot{E}_{\mathrm{k}}\) and \(\Delta \dot{E}_{\mathrm{p}}\)

As derived in step 1, \(\Delta \dot{E}_{\mathrm{k}} = 0\). For \(\Delta \dot{E}_{\mathrm{p}}\), use the formula for change in potential energy \(\Delta E_p = m \cdot g \cdot \Delta h\), where m is mass, g is acceleration due to gravity and \(\Delta h\) is change in height. The mass flow rate of methane can be calculated from the given average velocity, diameter of the pipe, and the ideal gas law. After calculating the mass flow rate, it can be substituted in the potential energy formula to find \(\Delta \dot{E}_{\mathrm{p}}\).
03

Explanation for \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\)

The energy conservation equation for a steady-flow process is given by: \(\Delta KE + \Delta PE = Q - W\), where Q represents heat transfer and W is work done. If \(\Delta \dot{E}_{\mathrm{k}} \neq -\Delta \dot{E}_{\mathrm{p}}\), it implies \(Q \neq 0\) and/or \(W \neq 0\), i.e., there is some heat transfer and/or work done during the process apart from changes in kinetic and potential energies. This can occur due to friction (which generates heat) in the fluid or if there is some sort of mechanical or heat interaction (like a pump or a heat exchanger) in the system.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Kinetic Energy in Chemical Processes
Understanding kinetic energy in chemical processes is pivotal because it embodies the energy of motion. As molecules move and react, they carry kinetic energy. In the context of the exercise, the methane gas flowing through a pipe exhibits kinetic energy due to its velocity. Contrary to what might seem intuitive, the exercise shows that kinetic energy, denoted by \(\Delta \dot{E}_{\mathrm{k}}\), does not always change as the gas flows through the system.

It's important to clarify why \(\Delta \dot{E}_{\mathrm{k}} = 0\) in this scenario. This occurs because the velocity, and consequently the kinetic energy of the gas, remains constant from the inlet to the outlet of the pipe; this suggests that other forms of energy or work might be involved in the system. This delineates a fundamental principle: kinetic energy change within a chemical process is not solely reliant on the distances travelled by the molecules, but rather on changes in their velocities.
Potential Energy in Chemical Systems
Potential energy in chemical systems is closely associated with the position or configuration of the system. In the case of gases, such as methane in our exercise, potential energy can be tied to the elevation of the gas due to gravitational forces. As per the given problem, methane is released 200 meters lower than where it was introduced, leading to a loss in potential energy, signified by a negative \(\Delta \dot{E}_{\mathrm{p}}\).

Using the equation \(\Delta E_p = m \cdot g \cdot \Delta h\), where \(m\) is mass, \(g\) is the gravitational acceleration, and \(\Delta h\) is the change in height, we see that as the distance \(\Delta h\) decreases, so does the potential energy. This relationship demonstrates that within chemical systems, potential energy variably depends on the position within a gravitational field and is crucial for understanding the energetics in processes like fluid flow in pipes.
Steady-Flow Energy Equation
The steady-flow energy equation is a vital concept in thermodynamics that describes the conservation of energy in fluid flow through a control volume. As per the step 3 of the solution, the equation \(\Delta KE + \Delta PE = Q - W\) relates changes in kinetic \(\Delta KE\) and potential \(\Delta PE\) energies to heat transfer \(Q\) and work done \(W\).

This equation can be misleading if examined superficially, as one might expect changes in kinetic and potential energies to be equal and opposite, which is not always the case. The exercise shows that \(\Delta \dot{E}_{\mathrm{k}} eq -\Delta \dot{E}_{\mathrm{p}}\), indicating that there is either heat transfer or work done or both within the system. For instance, friction could convert mechanical energy into thermal energy, or a pump might add work to the system, thus altering the straightforward exchange between kinetic and potential energies. This expounds on the complexity of real-world chemical processes, where multiple energy transformations occur simultaneously.

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Most popular questions from this chapter

A steam trap is a device to purge steam condensate from a system without venting uncondensed steam. In one of the crudest trap types, the condensate collects and raises a float attached to a drain plug. When the float reaches a certain level, it "pulls the plug," opening the drain valve and allowing the liquid to discharge. The float then drops down to its original position and the valve closes, preventing uncondensed steam from escaping. (a) Suppose saturated steam at 25 bar is used to heat \(100 \mathrm{kg} / \mathrm{min}\) of an oil from \(135^{\circ} \mathrm{C}\) to \(185^{\circ} \mathrm{C}\). Heat must be transferred to the oil at a rate of \(1.00 \times 10^{4} \mathrm{kJ} / \mathrm{min}\) to accomplish this task. The steam condenses on the exterior of a bundle of tubes through which the oil is flowing. Condensate collects in the bottom of the exchanger and exits through a steam trap set to discharge when 1200 g of liquid is collected. How often does the trap discharge? (b) Especially when periodic maintenance checks are not performed, steam traps often fail to close completely and so leak steam continuously. Suppose a process plant contains 1000 leaking traps (not an unrealistic supposition for some plants) operating at the condition of Part (a), and that on the average 10\% additional steam must be fed to the condensers to compensate for the uncondensed steam venting through the leaks. Further suppose that the cost of generating the additional steam is \$7.50 per million Btu, where the denominator refers to the enthalpy of the leaking steam relative to liquid water at \(20^{\circ} \mathrm{C}\). Estimate the yearly cost of the leaks based on \(24 \mathrm{h} /\) day, 360 day/yr operation.

Energy may be produced from solid waste in two ways: (1) generate methane from anaerobic decomposition of the waste and burn it (landfill-gas-to-energy, or LFGTE) or(2) burn the waste directly (waste-to-energy, or WTE). The heat generated by either method can be used to produce steam, which impinges on a turbine rotor connected to a generator to produce electricity. LFGTE produces about 215 k Wh electricity/ton of waste, and WTE produces roughly 600 kWh/ton of waste. The average output of a large power plant is 1 GW, which is enough to supply the annual residential energy consumption of a city of roughly 800,000 people. (a) The current rate of municipal solid-waste generation in the United States is approximately 413 million tons per year. If all of it were used for energy recovery, how many \(1 \mathrm{GW}\) power plants could LFGTE supply? How many if WTE is used? A useful source of information regarding LFGTE is the U.S. EPA Landfill Methane Outreach Program, http://www.epa.gov//mop/; the Waste-to-Energy Research and Technology Council at Columbia University provides useful information on WTE, http://www.seas.columbia.edu/earth/wtert/; and information on natural gas can be obtained from the U.S. Energy Information Administration, http:// www.eia.doe.gov/oil_gas/natural_gas/info_glance/natural_gas.html.

Water from a reservoir passes over a dam through a turbine and discharges from a \(70-\mathrm{cm}\) ID pipe at a point 55 m below the reservoir surface. The turbine delivers 0.80 MW. Calculate the required flow rate of water in \(\left.\mathrm{m}^{3} / \mathrm{min} \text { if friction is neglected. (See Example } 7.7-3 .\right)\) If friction were included, would a higher or lower flow rate be required? (Note: The equation you will solve in this problem has multiple roots. Find a solution less than \(2 \mathrm{m}^{3} / \mathrm{s}\).)

The specific enthalpy of liquid \(n\) -hexane at 1 atm varies linearly with temperature and equals \(25.8 \mathrm{kJ} / \mathrm{kg}\) at \(30^{\circ} \mathrm{C}\) and \(129.8 \mathrm{kJ} / \mathrm{kg}\) at \(50^{\circ} \mathrm{C}\) (a) Determine the equation that relates \(\hat{H}(\mathrm{kJ} / \mathrm{kg})\) to \(T\left(^{\circ} \mathrm{C}\right)\) and calculate the reference temperature on which the given enthalpies are based. Then derive an equation for \(\hat{U}(T)(\mathrm{kJ} / \mathrm{kg})\) at 1 atm. (b) Calculate the heat transfer rate required to cool liquid \(n\) -hexane flowing at a rate of \(20 \mathrm{kg} / \mathrm{min}\) from \(60^{\circ} \mathrm{C}\) to \(25^{\circ} \mathrm{C}\) at a constant pressure of 1 atm. Estimate the change in specific internal energy \((\mathrm{kJ} / \mathrm{kg})\) as the n-hexane is cooled at the given conditions.

One thousand liters of a 95 wt\% glycerol- \(5 \%\) water solution is to be diluted to \(60 \%\) glycerol by adding a \(35 \%\) solution pumped from a large storage tank through a \(5-\mathrm{cm}\) ID pipe at a steady rate. The pipe discharges at a point 23 m higher than the liquid surface in the storage tank. The operation is carried out isothermally and takes 13 min to complete. The friction loss ( \(\hat{F}\) of Equation \(7.7-2\) ) is \(50 \mathrm{J} / \mathrm{kg}\). Calculate the final solution volume and the shaft work in \(\mathrm{kW}\) that the pump must deliver, assuming that the surface of the stored solution and the pipe outlet are both at 1 atm. Data: \(\quad \rho_{\mathrm{H}_{2} \mathrm{O}}=1.00 \mathrm{kg} / \mathrm{L}, \rho_{\mathrm{gly}}=1.26 \mathrm{kg} / \mathrm{L} .\) (Use to estimate solution densities.)

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