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A fuel gas containing methane and ethane is burned with air in a furnace, producing a stack gas at \(300^{\circ} \mathrm{C}\) and \(105 \mathrm{kPa}\) (absolute). You analyze the stack gas and find that it contains no unburned hydrocarbons, oxygen, or carbon monoxide. You also determine the dew-point temperature.(a) Estimate the range of possible dew-point temperatures by determining the dew points when the feed is either pure methane or pure ethane. (b) Estimate the fraction of the feed that is methane if the measured dew- point temperature is \(59.5^{\circ} \mathrm{C}\). (c) What range of measured dew point temperatures would lead to calculated methane mole fractions within 5\% of the value determined in Part (b)?

Short Answer

Expert verified
The dew point temperatures for pure methane and pure ethane are given by the calculation in step 1. The mole fraction of methane for a dew point temperature of \(59.5^{\circ} \mathrm{C}\) is given by the calculation in step 2. The range of dew point temperatures that give a methane molar fraction within 5% of the value determined in step 2 are given by the calculation procedure described in step 3.

Step by step solution

01

Calculate dew point temperature for pure methane and pure ethane

First, consider the case when the feed gas is either pure methane or pure ethane. Using the Antoine equation: \[ P_{\text{sat}} = \text{exp}(A - \frac{B}{T+C}) \] where \(A\), \(B\), and \(C\) are specific constants for each compound, and \(T\) is the temperature in degrees Celsius. Solve for \(T\) to get: \[ T = \frac{B}{A - \text{ln}(P_{\text{sat}})} - C \] Now, choose appropriate Antoine constants for Methane (A=14.8782, B=519.67, C=-53.42) and Ethane (A=15.6856, B=655.78, C=-97.16) and knowing that the saturation pressure is 105 kPa, obtain the temperatures for the case when the feed gas is pure methane and pure ethane.
02

Calculate the mole fraction of methane in the mixture

For part (b), use the measured dew point temperature of \(59.5^{\circ} \mathrm{C}\) to find the mole fraction of methane in the feed. For this, use the Antoine equation to calculate the saturation pressures of methane and ethane at \(59.5^{\circ} \mathrm{C}\), and then use these values and the Dalton's law to write an equation for the total pressure: \[ P_{\text{total}} = y_{\text{CH4}}\cdot P_{\text{sat, CH4}} + y_{\text{C2H6}}\cdot P_{\text{sat, C2H6}} \] Given that \(y_{\text{C2H6}} = 1 - y_{\text{CH4}}\), solve for \(y_{\text{CH4}}\).
03

Calculate the range of dew point temperatures that result in methane molar fraction within 5% of the determined in step 2

For part (c), knowing the percentage tolerance (5%) and the molar fraction of methane determined in step 2, establish a range for permissible molar fractions of methane and then generate a series of equations similar to that in step 2, using a range of temperatures. Use the Antoine equation again to find the saturation pressures at these temperatures and solve each equation until you find two values that yield the upper and lower limits for the molar fraction of methane. The corresponding temperatures will be the limits for the dew point temperature.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Combustion Analysis
Combustion analysis is a fundamental technique in chemical engineering that involves determining the composition of a fuel by burning it and analyzing the products.
This process is critical for understanding the performance of fuel, which includes its energy content and emission characteristics.

In the given exercise, the combustion analysis is performed without the presence of unburned hydrocarbons, oxygen, or carbon monoxide in the stack gas. This indicates complete combustion, which is ideal for maximising energy output and reducing pollutants.

To further explain how combustion analysis is applied in the exercise: we start with knowing the stack gas temperature and pressure, then compute the dew point temperatures for pure hydrocarbons. This information can help in predicting the properties and behavior of a hydrocarbon mixture when burned, and consequently improving furnace efficiency.
Antoine Equation
The Antoine equation is a mathematical model used to describe the relation between the vapor pressure and temperature of pure substances.
It's extensively used in chemical engineering for processes that involve phase changes, such as distillation and evaporation. In our context, it's essential for finding the dew point temperature of hydrocarbons.

The equation is represented as: \[ P_{\text{sat}} = \text{exp}(A - \frac{B}{T+C}) \], where \(P_{\text{sat}}\) is the saturation pressure, \(T\) is the temperature, and \(A, B, \text{and} C\) are substance-specific constants.

In the exercise, we rely on the Antoine equation to find the temperatures at which methane and ethane transition from gas to liquid at a given pressure, thus estimating dew points for each.
Dew Point Calculation
Dew point calculation determines the temperature at which air becomes fully saturated with water vapor and water droplets begin to condense.
For chemical engineers, calculating the dew point of a gas mixture is useful for process control, preventing corrosion, and understanding the behavior of gases under various thermal conditions.

The exercise applies dew point calculation to the hydrocarbon mixture in the stack gas. By examining when methane or ethane would condense, we are effectively determining the dew point for each component, which helps in estimating the quality of the fuel gas and its combustion efficiency.
Hydrocarbon Gas Combustion
The combustion of hydrocarbon gases like methane (\(CH_4\)) and ethane (\(C_2H_6\)) is a key process in many industrial applications, particularly for energy production.
These compounds are important fuel sources, and their combustion yields carbon dioxide (\(CO_2\)) and water (\(H_2O\)), releasing energy.

The exercise involves burning a fuel gas mixture containing methane and ethane, where the challenge is to discern the properties of this mixture based on stack gas analysis. Understanding the fundamentals of hydrocarbon gas combustion allows us to predict the efficiency and outputs of the combustion process, leading to optimized engineering solutions.
Dalton's Law
Dalton's law of partial pressures states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of individual gases.
It is mathematically represented as: \[ P_{\text{total}} = P_1 + P_2 + \ldots + P_n \], where each \(P\) represents the partial pressure of a gas component in the mixture.

In the proposed exercise, Dalton's law is used to calculate the mole fraction of methane by setting up an equation that relates the total pressure of the stack gas to the partial pressures of methane and ethane, thereby assisting us in identifying the composition of the feed gas mixture.
Mole Fraction Estimation
Mole fraction estimation involves determining the proportion of a particular substance within a mixture. It is defined as the ratio of the moles of one component to the total moles of all components in the mixture.
The mole fraction is represented by \(y\), and for a two-component system with components \(A\) and \(B\), it can be calculated as: \[ y_A = \frac{n_A}{n_A + n_B} \] and \[ y_B = \frac{n_B}{n_A + n_B} = 1 - y_A \].

For this exercise, the mole fraction of methane is critical. We use the dew point and saturation pressures to find methane's mole fraction in the fuel gas. Mole fraction estimation is a key step towards understanding the composition of gaseous mixtures and designing suitable processes for their use or management.

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Most popular questions from this chapter

The solubility of sodium bicarbonate in water is \(11.1 \mathrm{g} \mathrm{NaHCO}_{3} / 100 \mathrm{g} \mathrm{H}_{2} \mathrm{O}\) at \(30^{\circ} \mathrm{C}\) and \(16.4 \mathrm{g}\) \(\mathrm{NaHCO}_{3} / 100 \mathrm{g} \mathrm{H}_{2} \mathrm{O}\) at \(60^{\circ} \mathrm{C} .\) If a saturated solution of \(\mathrm{NaHCO}_{3}\) at \(60^{\circ} \mathrm{C}\) is cooled and comes to equilibrium at \(30^{\circ} \mathrm{C},\) what percentage of the dissolved salt crystallizes?

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